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27744537027
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note
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PM3 modelling of the Cu+-bound monomer 1 and MMFF94 modelling of its octamer are included in the supporting information section.
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27
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27744561520
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note
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Electrochemical experiments were performed in 0.1 M tetrabutylammonium perchlorate in a 1:1 mixture of acetonitrile and water. This optimized electrolyte system affords the most stable and reproducible CVs and prevents the oxidized species from dissolving from the electrode surface.
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0038384670
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27744548520
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note
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Due to the unexpected solubility of Poly(1, Cu) in CH3CN, the polymer dissolves into the solution at longer dipping times.
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