A structure-reactivity correlation with three slopes in the elimination kinetics of 2-substituted ethyl N,N-dimethyl-carbamates in the gas phase

Journal of Physical Organic Chemistry

Volumn 14, Issue 3, 2001, Pages 146-158

  Chuchani, Gabriel ^a   Nunñez, Oswaldo ^b   Marcano, Norka ^b   Napolitano, Suvighey ^b   Rodriguez, Henry ^b   Dominguez, Marianella ^b   Ascanio, Judany ^b   Rotinov, Alexandra ^a   Domínguez, Rosa M ^a   Herize, Armando ^a  

^a INSTITUTO VENEZOLANO DE INVESTIGACIONES CIENTÍFICAS   (Venezuela)

^b UNIVERSIDAD SIMÓN BOLÍVAR   (Venezuela)

Author keywords

2 substituted ethyl N, N dimethylcarbamates; Gas phase elimination kinetics; Structure reactivity correlation

Indexed keywords

EID: 18044404734     PISSN: 08943230     EISSN: None     Source Type: Journal    
DOI: 10.1002/poc.341     Document Type: Article

References (20)

1. Daly NJ, Ziolkowski F. Aust. J. Chem. 1971; 24: 2451.
2. Smith GG, Voorkees KI, Kelly FM. J. Chem. Soc. Chem. Commun. 1971; 789
3. Gordon AS, Norris WP. J. Pys. Chem. 1965; 69: 3013.
4. Kwart H, Slutsky J. J. Chem. Soc. Chem. Commun. 1972, 552.
5. Daly NJ, Ziolkowski F. Aust. J. Chem. 1972, 25, 1453.
6. Kwart H, Slutsky J. J. Chem. Soc. Chem. Commun. 1972, 1182.
7. Herize A, Dominguez RM, Rotinov A, Nuñez O, Chuchani G. J. Phys. Org. Chem. 1999, 12, 1.
8. Chuchani G, Mishima M, Notario R, Abboud JL. In Advances in Quantitative Structure-Property Relationship. Structural Effect on Gas Phase Reactivities. Charton MCharton B (eds), VoL. 2. JAI Press: Stamford, CT, 1999; 83, and references cited therein.
9. Hansch C, Leo A. J. Substituent Constants for Correlation Analysis in Chemistry and Biology. Wiley, New York 1979;
10. Hansch C, Leo A, Taft R. Chem. Rev. 1991, 91, 165;
11. Benson SW, O'Neal HE. Kinetic Data on Gas Phase Unimolecular Reactions National Standard Reference Data Series, National Bureau of Standards: Gaithersburg, MD, 21, 1970
12. Hernandez J.A., Chuchani G. Int. J. Chem. Kinet., 1978, 10 923
13. Chuchani G, Domínguez RM, Rotinov A, Alvarez J. J. Phys. Chem. 1990 94, 3341,
14. Rogan JB, J. Org. Chem. 1962, 27, 3910.
15. Chuchani G, Hernandez JA, Martin I, Int. J. Chem. Kinet. 1979, 11, 1279.
16. Chuchani G, Martin I, Alonso ME, Jaino P. Int. J. Chem. Kinet. 1981, 13, 1.
17. Lustig E, Benson W, Day N. J. Org. Chem., 1967, 32, 851.
18. Joullie MM, Day AR, J. Am. Chem. Soc., 1954, 76, 2990.
19. Maccoll A. J. Chem. Soc., 1955, 965.
20. Swinbourne ES. Aust. J. Chem., 1958, 11, 314.