Selective ring-opening of nonactivated amino aziridines by thiols and unusual nucleophilic substitution of a dibenzylamino group

Journal of Organic Chemistry

Volumn 70, Issue 23, 2005, Pages 9411-9416

  Concellón, José M ^a   Bernad, Pablo L ^a   Suárez, José Ramón ^a   García Granda, Santiago ^a   Díaz, M Rosario ^a  

^a UNIVERSITY OF OVIEDO   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; RING OPENING POLYMERIZATION; STRUCTURE (COMPOSITION); SUBSTITUTION REACTIONS; X RAY ANALYSIS;

NONACTIVATED AMINO AZIRIDINES; SELECTIVE RING OPENING; STEREOSELECTIVITY; THIOLS;

AROMATIC COMPOUNDS;

AMINOAZIRIDINE; AZIRIDINE DERIVATIVE; BORON TRIFLUORIDE; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; RACEMIZATION; REACTION ANALYSIS; RING OPENING; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; X RAY ANALYSIS;

AMINES; AZIRIDINES; CRYSTALLOGRAPHY, X-RAY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; STEREOISOMERISM; SULFHYDRYL COMPOUNDS;

EID: 27744475785     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0515069     Document Type: Article

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33. The oxygen atom acts as a separator, which distances the benzyl group from the aziridine ring.