31P MAS NMR: A useful tool for the evaluation of VX natural weathering in various urban matrixes

Environmental Science and Technology

Volumn 39, Issue 22, 2005, Pages 8931-8935

  Mizrahi, Dana M ^a   Columbus, Ishay ^a  

^a ISRAEL INSTITUTE FOR BIOLOGICAL RESEARCH   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

BITUMINOUS MATERIALS; BUILDINGS; CHEMICAL WARFARE; DEGRADATION; EVAPORATION; PAVEMENTS; TOXICITY;

BITUMEN SHEET; DESERT SAND; MAS NMR;

NUCLEAR MAGNETIC RESONANCE;

ASPHALT; METHYLPHOSPHONOTHIOIC ACID S (2 DIISOPROPYLAMINOETHYL) O ETHYL ESTER; HYDROCARBON; PHOSPHOROTHIOIC ACID DERIVATIVE; PHOSPHORUS; SILICON DIOXIDE;

CHEMICAL WEATHERING;

ARTICLE; BUILDING; CHEMICAL INTERACTION; CHEMICAL WARFARE; DEGRADATION; EVAPORATION; MASS; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SAND; SOLID STATE; TOXICITY; URBAN AREA; WEATHERING; COMPARATIVE STUDY; ENVIRONMENTAL EXPOSURE; MASS SPECTROMETRY; METABOLISM; METHODOLOGY;

ENVIRONMENTAL EXPOSURE; HYDROCARBONS; ORGANOTHIOPHOSPHORUS COMPOUNDS; PHOSPHORUS; SILICON DIOXIDE; SPECTROMETRY, MASS, SECONDARY ION;

EID: 27744443302     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es050311f     Document Type: Article

References (10)

1. Kingery, A. F.; Allen, H. E. The Environmental Fate of Organophosphorus Nerve Agents: A Review. Toxicol. Environ. Chem. 1995, 47, 155-184.
2. (a) Groenewold, G. S.; Appelhans, A. D.; Gresham, G. L.; Olson, J. E.; Jeffery, M.; Weibel, M. Characterization of VX on Concrete Using Ion Trap Secondary lonization Mass Spectrometry. J. Am. Soc. Mass Spectrom. 2000, 11, 69-77.
3. (b) Wagner, G. W.; O'Connor, R. J.; Procell, L. R. Preliminary Study on the Fate of VX in Concrete. Langmuir 2001, 17, 4336-41.
4. (c) Groenewold, G. S.; Williams, J. M.; Appelhans, A. D.; Gresham, G. L.; Olson, J. E.; Jeffery, M. T.; Rowland, B. Hydrolysis of VX on Concrete: Rate of Degradation by Direct Surface Interrogation Using an Ion Trap Secondary Ion Mass Spectrometer. Environ. Sci. Technol. 2002, 36, 4790-4.
5. Wagner, G. W.; O'Connor, R. J.; Edwards, J. L.; Brevett, C. A. S. Effect of Drop Size on the Degradation of VX in Concrete. Langmuir 2004, 20, 7146-50.
6. (a) Wagner, G. W.; Bartram, P. W.; Koper, O.; Klabunde, K. J. Reactions of VX, GD and HD with Nanosize MgO. J. Phys. Chem. B 1999, 103, 3225-8.
7. (b) Wagner, G. W.; Bartram, P. W. Reactions of VX, HD and Their Simulants with NaY and AgY Zeolites. Desulfurization of VX and AgY. Langmuir 1999, 15, 8113-8.
8. Shaw, J. A.; Harris, R. K.; Norman, P. R. Magic-Angle Spinning NMR Study of the Competitive Adsorption of an organophosphate and an Organophosphonate on Activated Carbon. Langmuir 1998, 14, 6716-21.
9. 3. Formation of Aluminophosphates. J. Am. Chem. Soc. 2001, 123, 1636-44.
10. Yang, Y.-C.; Szafraniec, L. L.; Beaudry, W. T.; Rohrbaugh, D. K.; Procell, L. R.; Samuel, J. B. Autocatalytic Hydrolysis of V-Type Nerve Agents. J. Org. Chem. 1996, 61, 8407-13.