Mechanisms of concurrent hydride migration processes in a triruthenium cluster capped by a phenylphosphinidene (PPh) ligand

European Journal of Inorganic Chemistry

Volumn , Issue 21, 2005, Pages 4352-4360

  Deeming, Antony J ^a   Forth, Caroline S ^a   Hyder, Md Iqbal ^b   Kabir, Shariff E ^b   Nordlander, Ebbe ^c   Rodgers, Fiona ^a   Ullmann, Bettina ^c  

^a UNIVERSITY COLLEGE LONDON   (United Kingdom)

^b JAHANGIRNAGAR UNIVERSITY   (Bangladesh)

^c CHEMICAL CENTER   (Sweden)

Author keywords

Clusters; Dynamic mobility; Hydrides; Kinetics; Ruthenium

Indexed keywords

BINARY ALLOYS; LIGANDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM; RUTHENIUM ALLOYS; RUTHENIUM COMPOUNDS; SINGLE CRYSTALS;

CLUSTER; DYNAMIC MOBILITY; HYDRIDE LIGANDS; HYDRIDE MIGRATION; MIGRATION PROCESS; PHENYLPHOSPHINIDENE; REFLUXING; SINGLE CRYSTAL X-RAY STRUCTURES; SPECTRA'S; TRIRUTHENIUM CLUSTERS;

HYDRIDES;

EID: 27744437034     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200400892     Document Type: Article

References (24)

1. a) Some recent examples: S. P. Tunik, T. S. Pilyugina, I. O. Koskevoy, S. I. Selivanov, M. Haukka, T. A. Pakkanen, Organometallics 2004, 23, 568;
2. b) M. G. Ballinas-López, E. V. García-Báez, M. J. Rosales-Hoz, Polyhedron 2003, 22, 3403;
3. c) T. Beringhelli, E. Cariati, C. Dragonetti, S. Galli, E. Lucenti, D. Roberto, A. Sironi, R. Ugo, Inorg. Chim. Acta 2003, 354, 79;
4. d) G. Süss-Fink, L. Plasseraud, A. Maisse-François, H. Stoeckli-Evans, H. Berken, T. Fox, R. Gautier, J.-Y. Saillard, J. Organomet. Chem. 2000, 609, 196;
5. e) M. P. Cifuentes, M. G. Humphrey, B. W. Skelton, A. H. White, J. Organomet. Chem. 1996, 507, 163;
6. f) J. B. Keister, U. Frey, D. Zbinden, A. E. Merbach, Organometallics 1991, 10, 1497;
7. g) L. R. Nevinger, J. B. Keister, Organometallics 1990, 9, 2313;
8. h) P. Ewing, L. J. Farrugia, D. S. Rycroft, Organometallics 1988, 7, 859.
9. F. Iwasaki, M. J. Mays, P. R. Raithby, P. L. Taylor, P. J. Wheatley, J. Organomet. Chem. 1981, 213, 185.
10. S. P. Rowley, P. S. White, C. K. Schaver, Inorg. Chem. 1992, 31, 3158.
11. E. Ngai-Man Ho, W.-T. Wong, J. Chem. Soc., Dalton Trans. 1998, 51.
12. a) A. Forster, B. F. G. Johnson, J. Lewis, T. W. Matheson, J. Organomet. Chem. 1976, 104, 225;
13. b) J. Bracker-Novak, S. Hajela, M. Lord, M. Zhang, E. Rosenberg, R. Gobetto, L. Milone, D. Osella, Organometallics 1990, 9, 1379.
14. M. I. Bruce, B. K. Nicholson, M. L. Williams, Inorg. Synth. 1989, 26, 276;
15. M. I. Bruce, B. K. Nicholson, M. L. Williams, Inorg. Synth. 1990, 28, 225.
16. A. J. Deeming, C. S. Forth, F. Rodgers, unpublished results.
17. M. I. Bruce, O. Bin Shawkataly, M. L. Williams, J. Organomet. Chem. 1985, 287, 127.
18. a) J. A. Clucas, M. M. Harding, A. K. Smith, J. Chem. Soc., Chem. Commun. 1985, 1280;
19. b) M. I. Bruce, E. Horn, O. Bin Shawkataly, M. R. Snow, E. Tiekink, M. L. Williams, J. Organomet. Chem. 1986, 316, 187;
20. c) M. J. Stchedroff, S. Aime, R. Gobetto, L. Salassa, E. Nordlander, Magnet. Reson. Chem. 2002, 40, 107.
21. gNMR, Ver. 4.1, Cherwell Scientific Ltd., Oxford, U. K., 1995.
22. SMART and SAINT software for CCD diffractometers, version 6.1, Bruker AXS, Madison, WI, 2000.
23. G. M. Sheldrick, SADABS software for empirical absorption correction, University of Göttingen, Germany, 2000.
24. G. M. Sheldrick, SHELXTL PLUS, version 6.1, Bruker AXS Inc., Madison, WI, 2000.