Variable temperature 1H NMR and X-ray diffraction characterisation of [H5Os10(CO)24]- obtained in reproducible and high yields by hydrogenation of silica-supported [Os(CO)3(OH)2]n

Inorganica Chimica Acta

Volumn 354, Issue , 2003, Pages 79-89

  Beringhelli, Tiziana ^a   Cariati, Elena ^a   Dragonetti, Claudia ^a   Galli, Simona ^b   Lucenti, Elena ^c   Roberto, Dominique ^a   Sironi, Angelo ^a,d   Ugo, Renato ^a  

^a UNIVERSITY OF MILAN   (Italy)

^b UNIVERSITY OF INSUBRIA   (Italy)

^c CNR Consiglio Nazionale delle Ricerche   (Italy)

^d Istituto Nazionale per la Fisica della Materia Milan   (Italy)

Author keywords

1H NMR spectroscopy; Hydrides; Osmium carbonyl clusters; Silica mediated synthesis; X ray structure solution

Indexed keywords

HYDROGENATION; NEUTRON DIFFRACTION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POTENTIAL ENERGY; SILICA; TEMPERATURE; X RAY DIFFRACTION;

1H NMR INVESTIGATION; 1H NMR SPECTROSCOPY; CARBONYL CLUSTERS; ENERGY CONSIDERATIONS; OSMIUM CARBONYL CLUSTERS; SILICA-MEDIATED SYNTHESIS; VARIABLE TEMPERATURE; X-RAY STRUCTURE;

HYDRIDES;

CARBONYL DERIVATIVE; HYDROXYL GROUP; SILICON DIOXIDE;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL STRUCTURE; ELECTRON DIFFRACTION; ENERGY; HYDROGENATION; LOW TEMPERATURE; NEUTRON; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE; X RAY DIFFRACTION;

EID: 0142155250     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(03)00477-8     Document Type: Article

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