Mn-tourmaline from island of Elba (Italy): Crystal chemistry

American Mineralogist

Volumn 90, Issue 10, 2005, Pages 1661-1668

  Bosi, Ferdinando ^a   Agrosì, Giovanna ^b   Lucchesi, Sergio ^a   Melchiorre, Giovanni ^b   Scandale, Eugenio ^b  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

^b UNIVERSITY OF BARI   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ANALYSIS; LATTICE CONSTANTS; SILICATE MINERALS;

ANALYTICAL APPROACH; CHEMICAL EVOLUTION; CRYSTAL FRAGMENTS; DEHYDROXYLATIONS; GROWTH EVOLUTION; MICROENVIRONMENTS; OCTAHEDRAL SITES; STRUCTURAL TOLERANCES;

CRYSTAL CHEMISTRY;

COLOR; CRYSTAL CHEMISTRY; TOURMALINE; ZONING;

EASTERN HEMISPHERE; ELBA; EURASIA; EUROPE; ITALY; LIVORNO [TUSCANY]; SOUTHERN EUROPE; TUSCANY; WORLD;

EID: 27644533446     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2005.1852     Document Type: Article

References (35)

1. Barton, R. Jr. (1969) Refinement of the crystal structure of buergerite and the absolute orientation of tourmalines. Acta Crystallographica, B25, 1524-1533.
2. Bosi, F. and Lucchesi, S. (2004) Crystal chemistry of the schorl-dravite series. European Journal of Mineralogy, 16, 335-344.
3. Bosi, F., Lucchesi, S., and Reznitskii, L. (2004) Crystal chemistry of the dravite-chromdravite series. European Journal of Mineralogy, 16, 345-352.
4. Bosi, F., Andreozzi, G.B., Federico, M., Graziani, G., and Lucchesi, S. (2005) Crystal chemistry of the elbaite-schorl series. American Mineralogist, 90, in press.
5. Burns, P.C., MacDonald, D.J., and Hawthorne, F.C. (1994) The crystal chemistry of manganese-bearing elbaite. Canadian Mineralogist, 32, 31-41.
6. Cámara, F., Ottolini, L., and Hawthorne, F.C. (2002) Crystal chemistry of three tourmalines by SREF, EMPA, and SIMS. American Mineralogist, 87, 1437-1442.
7. Carobbi, G. and Rodolico, F. (1976) I minerali della Toscana, 280 p. L.S. Olschki, Firenze.
8. Deloule, E., Chaussidon, M., and Allé, P. (1992) Instrumental limitations for isotope ratio measurements with a Cameca IMS 3f ion microprobe: the example of H, B, S, Sr. Chemical Geology, 101, 187-192.
9. Ertl, A., Hughes, J.M., Prowatke, S., Rossman, G.R., London, D., and Fritz, E.A. (2003) Mn-rich tourmaline from Austria: structure, chemistry, optical spectra, and relations to synthetic solid solutions. American Mineralogist, 88, 1369-1376.
10. Ertl, A., Schuster, R., Prowatke, S., Brandstätter, F., Ludwig, T., Bernhardt, H.J., Koller, F., and Hughes, J.M. (2004) Mn-rich tourmaline and fluorapatite in a Variscan pegmatite from Eibenstein an der Thaya, Bohemian massif, Lower Austria. European Journal of Mineralogy, 16, 551-560.
11. Federico, M., Andreozzi, G.B., Lucchesi, S., Graziani, G., and César-Mendes, J. (1998) Crystal chemistry of tourmalines. I. Chemistry, compositional variations and coupled substitutions in the pegmatite dykes of the Cruzeiro mine, Minas Gerais, Brazil. Canadian Mineralogist, 36, 415-431.
12. Foit, F.F. Jr. (1989) Crystal chemistry of alkali-deficient schorl and tourmaline structural relationships. American Mineralogist, 74, 422-431.
13. Graziani, G., Lucchesi, S., and Scandale, E. (1990) General and specific growth marks in pegmatite beryls. Physics and Chemistry of Minerals, 17, 379-384.
14. Grice, J.D. and Ercit, T.S. (1993) Ordering of Fe and Mg in the tourmaline crystal structure: The correct formula. Neues Jahrbuch Mineralogie Abhandlungend, 165, 245-266.
15. Hawthorne, F.C. (1996) Structural mechanisms for light-element variations in tourmaline. Canadian Mineralogist, 34, 123-132.
16. Hawthorne, F.C. and Henry, D. (1999) Classification of the minerals of the tourmaline group. European Journal of Mineralogy, 11, 201-215.
17. [4]B content in zoned Fe-bearing olenite from Koralpe, Austria. American Mineralogist, 49, 447-454.
18. Kahlenberg, V. and Veličkov, B. (2000) Structural investigations on a synthetic alkali-free hydrogen-deficient Fe-tourmaline (foitite). European Journal of Mineralogy, 12, 947-953.
19. Kargaltsev, S.V., Lebedev, A.S., and Fursenko, D.A. (1990) Relationship of intercation distances and unit cell dimension of tourmaline. Soviet Geology and Geophysics, 31, 105-112.
20. Lang, A.R. (1959) The projection topograph: a new method in X-ray diffraction microradiography. Acta Crystallografica, 12, 249-250.
21. MacDonald, D.J. and Hawthorne, F.C. (1995) The crystal chemistry of Si ↔ Al substitution in tourmaline. Canadian Mineralogist, 33, 849-858.
22. Marinelli, G. (1959) Le intrusioni terziarie dell'Isola d'Elba. Atti Società Toscana di Scienze Naturali, Memorie, 66, 50-253.
23. Marschall, H.R., Ertl A., Hughes, J.M., and McCammon, C. (2004) Metamorphic Na- and OH-rich disordered dravite with tetrahedral boron associated with omphacite, from Syros, Greece: chemistry and structure. European Journal of Mineralogy, 16, 817-823.
24. Novàk, M. (2000) Compositional pathways of tourmaline evolution during primary (magmatic) crystallization in complex (Li) pegmatites of the Moldanubicum, Czech Republic. Memorie della Società Italiana di Scienze Naturali e del Museo Civico di Storia naturale di Milano, 30, 45-56.
25. Nuber, B. and Schmetzer, K. (1984) Structural refinement of tsilaisite (manganese tourmaline). Neues Jahrbuch für Mineralogie Monatshefte, 1984, 301-304.
26. Orlandi, P. and Scortecci, P.B. (1985) Minerals of the Elba pegmatites. Mineralogical Record, 16, 353-363.
27. Pieczka, A. (1999) Statistical interpretation of structural parameters of tourmalines: the ordering of ions in the octahedral sites. European Journal of Mineralogy, 11, 243-251.
28. Pieczka, A. (2000) Modelling of some structural parameters of tourmalines on the basis of their chemical composition. I. Ordered structure model. European Journal of Mineralogy, 12, 589-596.
29. Robinson, K., Gibbs, G.V., and Ribbe, P.H. (1971) Quadratic elongation: A quantitative measure of distortion in coordination polyhedra. Science, 172, 567-570.
30. Scandale, E., Lucchesi, S., and Graziani, G. (1990) Growth defects and growth marks in pegmatite beryls. European Journal of Mineralogy, 2, 305-311.
31. Schmetzer, K. and Bank, H. (1984) Crystal chemistry of tsilaisite (manganese tourmaline) from Zambia. Neues Jahrbuch für Mineralogie Monatshefte, 1984, 61-69.
32. Shannon, R.D. (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallographica, A32, 751-767.
33. Shigley, J.E., Kane, R.E., and Manson, D.V. (1986) A notable Mn-rich gem elbaite tourmaline and its relationship to "tsilaisite". American Mineralogist, 71, 1214-1216.
34. 57Fe Mössbauer spectroscopy and resultant oxygen fugacity. Geochimica Cosmochimica Acta, 53, 1277-1291.
35. Wright, S.E., Foley, J.A., and Hughes, J.M. (2000) Optimization of site occupancies in minerals using quadratic programming. American Mineralogist, 85, 524-531.