Bismuth(III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane

Tetrahedron Letters

Volumn 46, Issue 48, 2005, Pages 8345-8350

  De, Surya K ^a   Gibbs, Richard A ^a  

^a PURDUE UNIVERSITY   (United States)

Author keywords

Alcohols; Allylation; Allyltrimethylsilane; Bismuth(III) chloride

Indexed keywords

ALLYL COMPOUND; ALLYLTRIMETHYLSILANE; BENZYL ALCOHOL DERIVATIVE; BISMUTH CHLORIDE; BISMUTH DERIVATIVE; CHLORIDE; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; CATALYSIS; DEOXYGENATION; METHODOLOGY; SYNTHESIS;

EID: 27644502602     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.09.161     Document Type: Article

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24. 2 at room temperature indicated only the formation of desired alkene, no other side product was observed.
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26. 3 (5 mol %) at reflux temperature. However, other silyl nucleophiles such as phenyltrimethylsilane did not work.