Identification of metallic-smelling 1-octen-3-one and 1-nonen-3-one from solutions of ferrous sulfate

Journal of Agricultural and Food Chemistry

Volumn 53, Issue 21, 2005, Pages 8325-8327

  Lubran, Meryl B ^a   Lawless, Harry T ^a   Lavin, Edward ^b   Acree, Terry E ^b  

^a Department of Obstetrics Gynecology   (United States)

^b New York State Agricultural Experiment Station   (United States)

Author keywords

Ferrous sulfate; Lipid oxidation; Metallic taste

Indexed keywords

1 OCTEN 3 ONE; 1-OCTEN-3-ONE; FERROUS ION; FERROUS SULFATE; KETONE;

ARTICLE; CHEMISTRY; GAS CHROMATOGRAPHY; HUMAN; ODOR; SOLUTION AND SOLUBILITY;

CHROMATOGRAPHY, GAS; FERROUS COMPOUNDS; HUMANS; KETONES; ODORS; SMELL; SOLUTIONS;

EID: 27644443728     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf0511594     Document Type: Article

References (15)

1. Hettinger, T. P.; Meyers, W. E.; Frank, M. E. Role of olfaction in perception of non-traditional 'taste' stimuli. Chem. Senses 1990, 15, 755-760.
2. Lawless, H. T.; Schlake, S.; Smythe, J.; Lim, J.; Yang, H.; Chapman, K.; Bolton, B. Metallic taste and retronasal smell. Chem. Senses 2004, 29, 25-33.
3. Yang, H. H.; Lawless, H. T. Descriptive analysis of divalent salts. J. Sensory Stud. 2005, 20, 97-113.
4. Tordoff, M. G. Some basic psychophysics of calcium salt solutions. Chem. Senses 1996, 21, 417-424.
5. Civille, G. V.; Lyon, B. G. Aroma and flavor lexicon for sensory evaluation: Terms, definitions, references, and examples. In ASTM DS 66; American Society for Testing and Materials: West Conshohoken, PA, 1996.
6. Kovats, E. Gas chromatographic characterization of organic substances in the retention index system. Adv. Chromatogr. 1965, 1, 229-247.
7. Marin, A. B.; Acree, T. E.; Barnard, J. Variation in odor detection thresholds determined by charm analysis. Chem. Senses 1988, 13, 435-444.
8. Guth, H.; Grosch, W. Comparison of stored soya-bean and rapeseed oils by aroma extract dilution analysis. Lebensm.-Wiss. -Technol. 1990, 23, 59-65.
9. Bravo, A.; Hotchkiss, J. H.; Acree, T. E. Identification of odor-active compounds resulting from thermal oxidation of polyethylene. J. Agric. Food Chem. 1992, 40, 1881-1885.
10. Swoboda, P. A. T.; Peers, K. E. Metallic odour caused by vinyl ketones formed in the oxidation of butterfat. The identification of octa-1,cis-5-dien-3- one. J. Sci. Food Agric. 1977, 28, 1019-1024.
11. Corey, E. J.; Suggs, W. Pyridinium chlorochromate. An efficient reagent for oxidation of primary and secondary alcohols to carbonyl compounds. Tetrahedron Lett. 1975, 31, 2647-2650.
12. Menashe, I.; Man, O.; Lancet, D.; Gilad, Y. Different noses for different people. Nat. Genet. 2003, 34 (2), 143-144.
13. Cullere, L.; Escudero, A.; Cacho, J.; Ferreira, V. Gas chromatography-olfactometry and chemical quantitative study of the aroma of six premium quality Spanish aged red wines. J. Agric. Food Chem. 2004, 52, 1653-1660.
14. Roberts, D. D.; Acree, T. E. Effects of heating and cream addition on fresh raspberry aroma using a retronasal aroma simulator and gas chromatography olfactometry. J. Agric. Food Chem. 1996, 44, 3919-3925.
15. Ott, A.; Chaintreau, L.; Fay, L. B. Use of 1-nonen-3-one for aroma/flavor enhancement. U.S. Patent 6,296,889 B1, Oct 2, 2001.