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Volumn 44, Issue 21, 2005, Pages 7277-7279

Reversible penta- and hexacoordination motifs in [Co(TMPP)] resulting in interchange of 1D and 2D supramolecular designs

Author keywords

[No Author keywords available]

Indexed keywords

COBALT; DICHLOROMETHANE; METALLOPORPHYRIN; PORPHYRIN; SOLVENT; TETRA(4 N METHYLPYRIDYL)PORPHINE; TETRA(4-N-METHYLPYRIDYL)PORPHINE; TETRAKIS(3,4,5 TRIMETHOXYPHENYL)COBALT(II) PORPHYRIN; TETRAKIS(3,4,5-TRIMETHOXYPHENYL)COBALT(II) PORPHYRIN;

EID: 27544510729     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050900m     Document Type: Article
Times cited : (9)

References (25)
  • 15
    • 27544508718 scopus 로고    scopus 로고
    • note
    • An equimolar amount of substituted benzaldehyde and pyrrole with cobalt chloride under reflux in DMF containing a catalytic amount of concentrated HCl led to the formation of a cobalt-containing porphyrin. For detailed synthesis and characterization, see the Supporting Information.
  • 16
    • 27544505027 scopus 로고    scopus 로고
    • note
    • 2. Final R1 [I > 2σ(I)] = 0.050 and wR2 = 0.109 (all data); GOF = 0.875. Data were collected on a Bruker-AXS Smart APEX CCD diffractometer.
  • 18
    • 27544481513 scopus 로고    scopus 로고
    • To be published
    • To be published.
  • 21
    • 27544490096 scopus 로고    scopus 로고
    • note
    • The recrystallized products were identified by measuring the cell parameters by X-ray diffraction and by measuring EPR parameters.
  • 24
    • 27544444504 scopus 로고    scopus 로고
    • note
    • DFT calculation has been carried out by employing a B3LYP hybrid functional using the Gaussian 03 program. Molecular orbitals were visualized using G View. The 6-31G** basis set was used for C, N, O, and H atoms, and the effective core potential basis set LanL2DZ was used for the Co atom. Geometry was taken from the crystal structure (see the Supporting Information).
  • 25
    • 0141704726 scopus 로고    scopus 로고
    • Gaussian, Inc.: Pittsburgh, PA, see the Supporting Information
    • Pople, J. A.; et al. Gaussian 03, revision B.04; Gaussian, Inc.: Pittsburgh, PA, 2003 (see the Supporting Information).
    • (2003) Gaussian 03, Revision B.04
    • Pople, J.A.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.