Mechanistic insights into the phosphine-free RuCp*-diamine-catalyzed hydrogenation of aryl ketones: Experimental and theoretical evidence for an alcohol-mediated dihydrogen activation

Journal of the American Chemical Society

Volumn 127, Issue 43, 2005, Pages 15083-15090

  Hedberg, Christian ^a   Källström, Klas ^a   Arvidsson, Per I ^a   Brandt, Peter ^b   Andersson, Pher G ^a  

^a UPPSALA UNIVERSITY   (Sweden)

^b Biovitrum AB ^*  (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOLS; AMINES; CATALYSTS; COMPUTATIONAL METHODS; HYDROGEN; MOLECULAR ORIENTATION; RUTHENIUM; STEREOCHEMISTRY;

DIAMINE; ENANTIOMERS; QUINCORINE-AMINE; STEREOSELECTIVITY;

KETONES;

ALCOHOL; ALIPHATIC KETONE; AMINE; AROMATIC COMPOUND; DIAMINE; HYDROGEN; KETONE; PHOSPHINE; PHOSPHINE DERIVATIVE; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE; QUINCORIDINE AMINE; QUINCORINE AMINE; QUININE; QUINUCLIDINE; RUTHENIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; CHIRALITY; ENANTIOMER; ENANTIOSELECTIVITY; EXPERIMENT; HYDROGENATION; REACTION ANALYSIS; STEREOCHEMISTRY; THEORY;

EID: 27544505151     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja051920q     Document Type: Article

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