Luminescence from the trans-dioxotechnetium(V) chromophore

Journal of the American Chemical Society

Volumn 127, Issue 43, 2005, Pages 14978-14979

  Del Negro, Andrew S ^a   Wang, Zheming ^a   Seliskar, Carl J ^b   Heineman, William R ^b   Sullivan, B Patrick ^c   Hightower, Sean E ^c   Hubler, Timothy L ^a   Bryan, Samuel A ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF CINCINNATI   (United States)

^c UNIVERSITY OF WYOMING   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DIOXOTECHNETIUM; TECHNETIUM; UNCLASSIFIED DRUG;

ARTICLE; CHROMATOPHORE; COMPLEX FORMATION; CRYSTALLIZATION; LIGHT EMITTING DIODE; LUMINESCENCE; MOLECULAR DYNAMICS; SPECTROSCOPY; STEADY STATE;

EID: 27544495490     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja054906m     Document Type: Article

References (30)

1. Winkler, J. R.; Gray, H. B. Inorg. Chem. 1985, 24, 346-355.
2. (a) Cheng, J. Y. K.; Cheung, K. K.; Che, C. M.; Lau, T. C. J. Chem. Soc., Chem. Commun. 1997, 15, 1443-1444.
3. (b) Grey, J. K.; Butler, I. S.; Reber, C. Inorg. Chem. 2004, 43, 5103-5111.
4. (c) Schindler, S.; Castner, E. W.; Creutz, C.; Sutin, N. Inorg. Chem. 1993, 32, 4200-4208.
5. (d) Yam, V. W. W.; Che, C. M. Coord. Chem. Rev. 1990, 97, 93-104.
6. Savoie, C.; Reber, C. J. Am. Chem. Soc. 2000, 122, 844-852.
7. (a) Isovitsch, R. A.; Beadle, A. S.; Fronczek, F. R.; Maverick, A. W. Inorg. Chem. 1998, 37, 4258-4264.
8. (b) Isovitsch, R. A.; May, J. G.; Fronczek, F. R.; Maverick, A. W. Polyhedron 2000, 19, 1437-1446.
9. (c) Mohammed, A. K.; Maverick, A. W. Inorg. Chem. 1992, 31, 4441-4443.
10. (d) Da Re, R. E.; Hopkins, M. D. Inorg. Chem. 2002, 41, 6973-6985.
11. (a) Savoie, C.; Reber, C. Coord. Chem. Rev. 1998, 171, 387-398.
12. (b) Savoie, C.; Reber, C.; Belanger, S.; Beauchamp, A. L. Inorg. Chem. 1995, 34, 3851-3852.
13. Grey, J. K.; Butler, I. S.; Reber, C. J. Am. Chem. Soc. 2002, 124, 11699-11708.
14. Grey, J. K.; Butler, I. S.; Reber, C. Can. J. Chem. 2004, 82, 1083-1091.
15. Schwochau, K. Technetium: Chemistry und Radiopharmaceutical Applications; Wiley-VCH: New York, 2000 and references therein.
16. (a) Flint, C. D.; Lang, P. J. Lumin. 1981, 24-25, 301-304.
17. (b) Flint, C. D.; Lang, P. F. J. Chem. Soc., Faraday Trans. 2 1986, 82, 465-472.
18. (c) Flint, C. D.; Lang, P. F. J. Chem. Soc., Dalton Trans. 1986, 5, 921-923.
19. (d) Wendt, A.; Preetz, W. Z. Naturforsch., A 1992, 47, 882-886.
20. - salts.
21. Trop, H. S.; Jones, A. G.; Davison, A. Inorg. Chem. 1980, 19, 1993-1997.
22. (a) Beard, J. H.; Casey, J.; Murmann, R. K. Inorg. Chem. 1965, 4, 797.
23. (b) Sullivan, B. P.; Brewer, J. C.; Gray, H. B. Inorg. Synth. 1992, 29, 146-150.
24. Instrumentation for luminescence measurements is described in Wang, Z.; Zachara, J. M.; Yantasee, W.; Gassman, P. L.; Liu, C. X.; Joly, A. G. Environ. Sci. Technol. 2004, 38, 5591-5597.
25. Frisch, M. J. et al. Gaussian 03, revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.
26. Electronic ground state and geometry optimizations were carried out using the B3LYP approximation, followed by TDDFT calculation of the lowest excited states employing the same functional. Calculations utilized the 6-31G* basis set for the ligands and the LANL2 relativistic effective core potential (RECP) for the transition metal.
27. Tutt, L.; Tannor, D.; Heller, E. J.; Zink, J. I. Inorg. Chem. 1982, 21, 3859-3860.
28. Stephenson, K. A. et al. J. Am. Chem. Soc. 2004, 126, 8598-8599.
29. (a) Stegemiller, M. L.; Heineman, W. R.; Seliskar, C. J.; Ridgway, T. H.; Bryan, S. A.; Hubler, T. L.; Sell, R. L. Environ. Sci. Technol. 2003, 37, 123-130.
30. (b) Kaval, N.; Seliskar, C. J.; Heineman, W. R. Anal. Chem. 2003, 75, 6334-6340.