An η2-aryl-metal interaction turns a chiral monodentate phosphoramidite into a chelating ligand in (Sa,SRu,R C,RC)-[RuCl(η6-p-cymene) (O,O′-(1,1′-dinaphthyl-2,2′-diyl)-N-(1-(1,2-η-1-naphthyl) ethyl)-N-(1-(1-naphthyl)ethyl)phosphoramidite-κP)]PF6

Organometallics

Volumn 24, Issue 22, 2005, Pages 5221-5223

  Huber, Dominik ^a   Kumar, P G Anil ^a   Pregosin, Paul S ^a   Mezzetti, Antonio ^a  

^a ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

METAL ANALYSIS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SUBSTITUTION REACTIONS;

CHIRALS; CHLORIDE ABSTRACTION; X-RAY STUDIES;

COMPLEXATION;

EID: 27544490197     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050686+     Document Type: Article

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37. 2 (1 mL) was added over 6 h by syringe pump. The solution, which was protected from light, was stirred for an additional 14 h at 23°C and then analyzed by GC. The total reaction time was 20 h at 23°C. Each experiment was at least reproduced once. A control reaction without the catalyst indicated that there is no formation of the cyclopropane derivatives under the conditions used.