Evaluation of two MCM v3.1 alkene mechanisms using indoor environmental chamber data

Atmospheric Environment

Volumn 39, Issue 38, 2005, Pages 7251-7262

  Hynes, R G ^a   Angove, D E ^a   Saunders, S M ^b   Haverd, V ^c   Azzi, M ^a  

^a CSIRO   (Australia)

^b UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

^c UNIVERSITY OF WOLLONGONG   (Australia)

Author keywords

Indoor environmental chamber data; Master chemical mechanism; Ozone modelling; Photooxidation; Tropospheric chemistry

Indexed keywords

COMPUTER SIMULATION; ENVIRONMENTAL IMPACT; INDOOR AIR POLLUTION; MATHEMATICAL MODELS; OXIDATION; OZONE; PARAMETER ESTIMATION; PHOTOLYSIS; PHOTOOXIDATION; REACTION KINETICS; SENSITIVITY ANALYSIS;

INDOOR ENVIRONMENTAL CHAMBER DATA; MASTER CHEMICAL MECHANISM; OZONE MODELING; TROPOSPHERIC CHEMISTRY;

OLEFINS;

1 BUTENE NITRIC OXIDE; ALKENE; FORMALDEHYDE; NITRIC OXIDE; PROPENE NITRIC OXIDE; UNCLASSIFIED DRUG; VOLATILE ORGANIC COMPOUND;

ALKENE; ATMOSPHERIC CHEMISTRY; OZONE; PHOTOCHEMISTRY; PHOTOLYSIS; TROPOSPHERE;

AIR ANALYSIS; AIR POLLUTION; AMBIENT AIR; ARTICLE; CHEMICAL MODEL; CHEMICAL PARAMETERS; CHEMICAL REACTION KINETICS; COMPARATIVE STUDY; CONCENTRATION RESPONSE; DATA ANALYSIS; ENVIRONMENT; EVALUATION; MEASUREMENT; PHOTOLYSIS; PHOTOOXIDATION; PRIORITY JOURNAL; SENSITIVITY ANALYSIS; SIMULATION; UNCERTAINTY;

EID: 27544456801     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2005.09.005     Document Type: Article

References (20)

1. R. Atkinson Gas-phase tropospheric chemistry of volatile organic compounds: 1. Alkanes and alkenes Journal of Physical and Chemical Reference Data 26 1997 215 290
2. x species Atmospheric Chemistry and Physics 4 2004 1461 1738
3. C. Bloss, V. Wagner, A. Bonzanini, M.E. Jenkin, K. Wirtz, M. Martin-Reviejo, and M.J. Pilling Evaluation of detailed aromatic mechanisms (MCM v3 and MCM v3.1) against environmental chamber data Atmospheric Chemistry and Physics 5 2005 623 629
4. W.P.L. Carter Computer modelling of environmental chamber measurements of maximum incremental reactivities of volatile organic compounds Atmospheric Environment 29 1995 2513 2527
5. W.P.L. Carter, and F.W. Lurmann Evaluation of a detailed gas-phase atmospheric reaction mechanism using environmental chamber data Atmospheric Environment 25A 1991 2771 2806
6. W.P.L. Carter, R. Atkinson, A.M. Winer, and J.N. Pitts Experimental investigation of chamber-dependent radical sources International Journal of Chemical Kinetics 19 1982 177 216
7. Carter, W.P.L., Luo, D., Malkina, I.L., Fitz., D., 1995. Environmental chamber studies of atmospheric reactivities of volatile organic compounds. Effects of varying chamber and light source. Final report to National Renewable Energy Laboratory, Contract XZ-2-12075, Co-ordinating Research Council, Inc., Project M-9, California Resources Board, Contract A032-0692, and South Coast Air Quality Management District, Contract C91323.
8. D.R. Cocker, R.C. Flagan, and J.H. Seinfeld State-of-the-art chamber facility for studying atmospheric aerosol chemistry Environmental Science and Technology 35 2001 2594 2601
9. 2 in laboratory systems and in outdoor and indoor atmospheres: an integrated mechanism Physical Chemistry Chemical Physics 5 2003 223 242
10. IUPAC Subcommittee on Gas Kinetic Data Evaluation, http://www.iupac- kinetic.ch.cam.ac.uk/
11. Jeffries, H., Fox, D., Kamens, R., 1975. Outdoor smog chamber studies. US Environmental Protection Agency, Report EPA-650/3-75-011.
12. M.E. Jenkin Modelling the formation and composition of secondary organic aerosol from α and β-pinene ozonolysis using MCM v3 Atmospheric Chemistry and Physics 4 2004 1741 1757
13. M.E. Jenkin, S.M. Saunders, and M.J. Pilling The tropospheric degradation of volatile organic compounds: a protocol for mechanism development Atmospheric Environment 31 1997 81 104
14. N.A. Kelly Characterisation of fluorocarbon-film bags as smog chambers Environmental Science and Technology 16 1982 763 770
15. x - air photooxidation of toluene and the cresols" International Journal of Chemical Kinetics 13 1981 1101 1103
16. P.G. Pinho, C.A. Pio, and M.E. Jenkin Evaluation of isoprene degradation in the detailed tropospheric chemical mechanism, MCM v3, using environmental chamber data Atmospheric Environment 39 2005 1303 1322
17. S.M. Saunders, M.E. Jenkin, R.G. Derwent, and M.J. Pilling Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): tropospheric degradation of non-aromatic volatile organic compounds Atmospheric Chemistry and Physics 3 2003 161 180
18. 5 with water vapour Geophysical Research Letters 10 1983 953 956
19. T.J. Wallington, R.Z. Liu, P. Dagaut, and M.J. Kurylo The gas phase reactions of hydroxyl radicals with a series of aliphatic ethers over the temperature range 240-440 K International Journal of Chemical Kinetics 20 1988 41 49
20. T.J. Wallington, P. Dagaut, and M.J. Kurylo Correlation between gas-phase and solution-phase reactivities of hydroxyl radicals toward saturated organic-compounds Journal of Physical Chemistry 92 1988 5024 5028