Evaluation of isoprene degradation in the detailed tropospheric chemical mechanism, MCM v3, using environmental chamber data

Atmospheric Environment

Volumn 39, Issue 7, 2005, Pages 1303-1322

  Pinho, P G ^a   Pio, C A ^a   Jenkin, M E ^b  

^a UNIVERSITY OF AVEIRO   (Portugal)

^b IMPERIAL COLLEGE LONDON   (United Kingdom)

Author keywords

Acetaldehyde; Butane; Degradation mechanisms; Environmental chamber data; Formaldehyde; Isoprene; Methacrolein; Methylethyl ketone; Methylvinyl ketone; Ozone modelling; Tropospheric chemistry; VOC oxidation

Indexed keywords

ATMOSPHERIC CHEMISTRY; BUTANE; DEGRADATION; ENVIRONMENTAL CHAMBERS; FORMALDEHYDE; FREE RADICALS; KETONES; OPTIMIZATION; PHOTOOXIDATION; TROPOSPHERE;

ACETALDEHYDE; DEGRADATION CHEMISTRY; ISOPRENE; METHACROLEIN (MACR);

OLEFINS;

2 BUTANONE; ACETALDEHYDE; BUTANE; FORMALDEHYDE; ISOPRENE; KETONE DERIVATIVE; OZONE;

ACETALDEHYDE; ATMOSPHERIC CHEMISTRY; FORMALDEHYDE; ISOPRENE; OZONE; PHOTOCHEMISTRY; TROPOSPHERE;

AIR ANALYSIS; AIR POLLUTION; ARTICLE; DATA ANALYSIS; DEGRADATION; EVALUATION; ORGANIC CHEMISTRY; OXIDATION; PHOTOOXIDATION; PRIORITY JOURNAL; TROPOSPHERE;

EID: 13844299289     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2004.11.014     Document Type: Article

References (35)

1. 3 with methacrolein and methyl vinyl ketone Atmospheric Environment 30 1996 2939 2943
2. R. Atkinson Atmospheric reactions of alkoxy and β-hydroxyalkoxy radicals International Journal of Chemical Kinetics 29 1997 99 111
3. C. Bloss, V. Wagner, A. Bonzanini, M.E. Jenkin, K. Wirtz, M. Martin-Reviejo, and M.J. Pilling Evaluation of detailed aromatic mechanisms (MCM v3 and MCM v3.1) against environmental chamber data Atmospheric Chemistry and Physics Discussions 4 2004 5683 5731
4. C. Bloss, V. Wagner, M.E. Jenkin, R. Volkamer, W.J. Bloss, J.D. Lee, D.E. Heard, K. Wirtz, M. Martin-Reviejo, G. Rea, J.C. Wenger, and M.J. Pilling Development of a detailed chemical mechanism (MCM v3.1) for the atmospheric oxidation of aromatic hydrocarbons Atmospheric Chemistry and Physics Discussions 4 2004 5733 5788
5. A. Borbon, H. Fontaine, M. Veillerot, N. Locoge, J.C. Galloo, and R. Guillermo An investigation into the traffic-related fraction of isoprene at an urban location Atmospheric Environment 35 2001 3749 3760
6. Burgess, R.A., Penkett, S.A., 1993. Ground-based non-methane hydrocarbon measurements in England. Proceedings of the EUROTRAC'92 Symposium, Garmisch-Partenkirchen, March 1992. Academic Publishing, The Hague, The Netherlands, pp. 165-169.
7. J.G. Calvert, R. Atkinson, J.A. Kerr, S. Madronich, G.K. Moortgat, T.J. Wallington, and G. Yarwood The Mechanisms of Atmospheric Oxidation of Alkenes 2000 Oxford University Press New York 0195131770
8. Carter, W.P.L., 2000. Documentation of the SAPRC-99 chemical mechanism for VOC reactivity assessment. Final Report to California Air Resources Board Contract 92-329 and Contract 95-308, Air Pollution Research Center and College of Engineering Center for Environmental Research and Technology University of California Riverside, California.
9. W.P.L. Carter, and F.W. Lurmann Evaluation of a detailed gas-phase atmospheric reaction mechanism using environmental chamber data Atmospheric Environment 25A 1991 2771 2806
10. x International Journal of Chemical Kinetics 28 1996 497 530
11. Carter, W.P.L., Luo, D., Malkina, I.L., Fitz, D., 1995a. The University of California, riverside environmental chamber data base for evaluating oxidant mechanisms: indoor chamber experiments through 1993. EPA/600/SR-96/078, US Environmental Protection Agency, Research Triangle Park, NC.
12. Carter, W.P.L., Luo, D., Malkina, I.L., Pierce, J.A., 1995b. Environmental chamber studies of atmospheric reactivities of volatile organic compounds. Effects of varying chamber and light source. Final report to National Renewable Energy Laboratory, Contract XZ-2-12075, Coordinating Research Council, Inc., Project M-9, California Air Resources Board, Contract A032-0692, and South Coast Air Quality Management District, Contract C91323.
13. x in the UK Atmospheric Environment 35 2001 6391 6405
14. X. Chen, D. Hulbert, and P. Shepson Measurement of the organic nitrate yield from OH reaction with isoprene Journal of Geophysical Research 103 D9 1998 25563 25568
15. R.G. Derwent, D.R. Middleton, R.A. Field, M.E. Goldstone, J.N. Lester, and R. Perry Analysis and interpretation of air quality data from an urban roadside location in central London over the period from July 1991 to July 1992 Atmospheric Environment 29 8 1995 923 946
16. R.G. Derwent, M.E. Jenkin, S.M. Saunders, and M.J. Pilling Photochemical ozone creation potentials for organic compounds in North West Europe calculated with a master chemical mechanism Atmospheric Environment 32 1998 2429 2441
17. M. Duane, B. Poma, D. Rembges, C. Astorga, and B.R. Larsen Isoprene and its degradation products as strong ozone precursors in Insubria, Northern Italy Atmospheric Environment 36 2002 3867 3879
18. T. Gierczak, J.B. Burkholder, R.K. Talukdar, A. Mellouki, S.B. Barone, and A.R. Ravishankara Atmospheric fate of methyl vinyl ketone and methacrolein Journal of Photochemistry and Photobiology A: Chemistry 110 1997 1
19. A.B. Guenther, C.N. Hewitt, D. Erickson, R. Fall, C. Geron, T. Graedel, P. Harley, L. Klinger, M. Lerdau, W.A. McKay, T. Pierce, B. Scholes, R. Steinbrecher, R. Tallamraju, J. Taylor, and P. Zimmerman A global model of natural volatile organic compound emissions Journal of Geophysical Research 100 1995 8873 8892
20. IUPAC Subcommittee on Gas Kinetic Data Evaluation, http://www.iupac- kinetic.ch.cam.ac.uk/
21. M.E. Jenkin, S.M. Saunders, and M.J. Pilling The tropospheric degradation of volatile organic compounds a protocol for mechanism development Atmospheric Environment 31 1997 81 104
22. M.E. Jenkin, A.A. Boyd, and R. Lesclaux Peroxy radical kinetics resulting from the OH-initiated oxidation of 1,3-butadiene, 2,3-dimethyl-1,3-butadiene and isoprene Journal of Atmospheric Chemistry 29 1998 267 298
23. M.E. Jenkin, T.J. Davies, and J.R. Stedman The origin and day-of-week dependence of photochemical episodes in the UK Atmospheric Environment 36 2002 999 1012
24. M.E. Jenkin, S.M. Saunders, V. Wagner, and M.J. Pilling Protocol for the development of the Master Chemical Mechanism, MCM v3, Part B tropospheric degradation of aromatic volatile organic compounds Atmospheric Chemistry and Physics 3 2003 181 193
25. J. Kesselmeier, and M. Staudt Biogenic volatile organic compounds, VOC an overview on emission, physiology and ecology Journal of Atmospheric Chemistry 33 1999 23 88
26. J.P. Killus, and G.Z. Whitten Backgroud reactivity in smog chambers International Journal of Chemical Kinetics 22 1990 547 575
27. R. McLaren, D.L. Singleton, J.Y.K. Lai, B. Khouw, E. Singer, Z. Wu, and H. Niki Analysis of motor vehicle sources and their contribution to ambient hydrocarbon distributions at urban sites in Toronto during the Southern Oxidants Study Atmospheric Environment 30 12 1996 2219 2232
28. R.E. Meller, and G.K. Moortgat Temperature dependence of the absorption cross sections of formaldehyde between 223 and 323 K in the wavelength range 225-375 nm Journal of Geophysical Research 105 2000 7089 7101
29. S.E. Paulson, R.C. Flagan, and J.H. Seinfeld Atmospheric photo-oxidation of isoprene part I. The hydroxyl radical and ground state atomic oxygen reactions International Journal of Chemical Kinetics 24 1992 79 101
30. S.E. Paulson, M. Chung, A.D. Sen, and G. Orzechowska Measurement of OH radical formation from the reaction of ozone with several biogenic alkenes Journal of Geophysical Research 103 1998 25533 25539
31. Raber, W.H., Moortgat, G.K., 1996. In: Barker, J. (Ed.), Progress and Problems in Atmospheric Chemistry. World Scientific Publishing Company, Singapore, pp. 318-373.
32. RADICAL, 2002. Final report on the EU fourth framework project 'evaluation of radical sources in atmospheric chemistry through chamber and laboratory studies, RADICAL'. European Communities Report EUR 20254 EN, G.K. Moortgat (Coordinator), MPI Mainz, Germany.
33. S. Reimann, P. Calanca, and P. Hofer The anthropogenic contribution to isoprene concentrations in a rural atmosphere Atmospheric Environment 34 2000 109 115
34. S.M. Saunders, M.E. Jenkin, R.G. Derwent, and M.J. Pilling Protocol for the development of the Master Chemical Mechanism, MCM v3, Part A tropospheric degradation of non-aromatic volatile organic compounds Atmospheric Chemistry and Physics 3 2003 161 180
35. G.D. Smith, L.T. Molina, and M. Molina Measurement of radical quantum yields from formaldehyde photolysis between 269 and 339 nm Journal of Physical Chemistry A 106 2002 1233 1240