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Volumn , Issue 19, 2005, Pages 3155-3160

Can weak interactions modify the binding properties of a strong nitrogen donor? Unusual N-coordination of a phosphoranylidene-substituted pyrazolone unit towards palladium(II) centres: An experimental and theoretical study

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION PLANE; OUT-OF-PLANE DISTORTION; PHENYL GROUP; PYRAZOLE RINGS;

EID: 26844576235     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b506352n     Document Type: Article
Times cited : (9)

References (39)
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    • note
    • aromatic⋯ Cl(l) interactions similar to those observed in 4.
  • 19
    • 26844512636 scopus 로고    scopus 로고
    • note
    • aromatic interaction is still present (the d(C12-HPh) distance changed from 3.246 Å to an even smaller value, 3.054 A, see entry 10, Table 1). Moreover, there are some other attractive interactions that result from the out-of-plane Pd distortion: these involve (i) the Pd atom, which interacts with two hydrogen atoms, one originating from the tert-butyl group and sitting apically above the metal (Pd ⋯ H 2.539 Å), the other one belonging to the C(3)-methyl group (Pd ⋯ H 2.729 Å); (ii) the C11 atom, which interacts with H atoms of the same alkyl groups (Cl(1) ⋯ H distances: 3.043 and 2.905 A, respectively).
  • 24
    • 26844511859 scopus 로고    scopus 로고
    • Nonius B V
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  • 39
    • 26844469492 scopus 로고    scopus 로고
    • Hypercube, Inc., 1115 NW 4th Street, Gainesville, FL 32601, USA
    • Hyperchem™ release 7.51. Hypercube, Inc., 1115 NW 4th Street, Gainesville, FL 32601, USA.
    • Hyperchem™ Release 7.51


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.