A 4-acyl-5-pyrazolone ligand (HQ) in N-unidentate coordination mode in a Rh(CO)2Cl(HQ)-type complex

Inorganic Chemistry Communications

Volumn 7, Issue 2, 2004, Pages 235-237

  Cingolani, Augusto ^a   Marchetti, Fabio ^a   Pettinari, Claudio ^a   Pettinari, Riccardo ^a   Skelton, Brian W ^b   White, Allan H ^b  

^a UNIVERSITY OF CAMERINO   (Italy)

^b UNIVERSITY OF WESTERN AUSTRALIA   (Australia)

Author keywords

Carbonyl complexes; Rhodium; Tautomerism; X ray; Diketonate

Indexed keywords

CARBON; CHLORINE; HYDROGEN; LIGAND; PYRAZOLONE DERIVATIVE; RHODIUM;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; SYNTHESIS;

EID: 0442326286     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2003.11.009     Document Type: Article

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14. Fur), 162.62 (s, C5), 180.14 (CO).
15. Fur), 148.65 (s, C3), 162.60 (s, C5), CO not observed.
16. 3 Å. Figures show 50% probability amplitude displacement ellipsoids for the non-hydrogen atoms, hydrogen atoms (where shown) having arbitrary radii of 0.1 Å. CCDC 222559.
17. H refined. T ca. 153 K. CCDC 222651.
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