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33646650665
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note
-
2O (6 ml) at 140°C for 72 h yielded deep red platelet crystals with ca. 70% yield (based on Co). Phase purity of the polymer is sustained by its powder diffraction pattern, which is consistent with the simulated one from the X-ray single crystal diffraction data (Fig. S1). Analysis found: C, 48.44; H, 2.09; N, 11.79. Calc.: C, 49.01; H, 2.15; N, 12.04%.
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-
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41
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33646670334
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2 by full-matrix least squares using SHELXTL97 [42]. No adsorption correction was applied. The hydrogen atoms were placed geometrically and refined using a riding model. All non-hydrogen atoms were refined anisotropically. Crystallographic data for 1 have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication No. CCDC-268205. Copies of this data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk or www: http://www.ccdc.cam.ac.uk ).
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