Synthesis of enantioenriched and diastereomerically pure cis-fused bicyclic α-oxy-substituted γ-lactones via epoxidation of optically active homoaldol products

Synthesis

Volumn , Issue 15, 2005, Pages 2507-2520

  Ünaldi, Seda ^a   Fröhlich, Roland ^a   Hoppe, Dieter ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Aldol reactions; Bicyclic compounds; Carbamates; Diastereoselectivity; Epoxides; Lactones; Sparteine

Indexed keywords

ALDEHYDES; GAMMA RAYS; LITHIUM COMPOUNDS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL); TITANIUM COMPOUNDS;

ALDOL REACTIONS; BICYCLIC COMPOUNDS; CARBAMATES; DISTEREOSELECTIVITY; EPOXIDES; LACTONES; SPARTEINE;

ALCOHOLS;

1 O (2 CYCLO 1 ENYL)METHYL N,N DIISOPROPYLCARBAMATE DERIVATIVE; ALDEHYDE DERIVATIVE; ALKYL GROUP; CARBAMIC ACID DERIVATIVE; ETHYLENE OXIDE DERIVATIVE; GAMMA HYDROXYALDEHYDE DERIVATIVE; GAMMA LACTONE DERIVATIVE; HYDROXYL GROUP; LITHIUM; METHYL GROUP; N,N DIISOPROPYLCARBAMOYLOXY DERIVATIVE; PROPANE; SPARTEINE; TITANIUM; UNCLASSIFIED DRUG;

ADDITION REACTION; ALDOL REACTION; ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CRYSTAL STRUCTURE; CYCLIZATION; DIASTEREOISOMER; ENANTIOMER; EPOXIDATION; MASS SPECTROMETRY; OPTICAL ROTATION; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; SILYLATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 26844545409     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-872080     Document Type: Article

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