Electrochemical olefin epoxidation employing an iron(IV)porphyrin/ trisbipyridineruthenium(III) polymer catalyst

Langmuir

Volumn 21, Issue 19, 2005, Pages 8605-8608

  Elliott, C Michael ^a   Dunkle, J R ^a   Paulson, S C ^a,b  

^a Department of Environmental and Radiological Health Sciences   (United States)

^b UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

BIPYRIDINE; CYCLOHEXENE; EPOXIDATION; LIGANDS;

CATALYST ACTIVITY; CATALYSTS; COMPLEXATION; COORDINATION REACTIONS; DEPOSITION; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; ETHYLENE; OXIDATION; PLASTIC FILMS; PORPHYRINS; PROPYLENE; REDUCTION; RUTHENIUM COMPOUNDS;

OLEFINS;

CYCLOHEXENE; CYCLOHEXENE DERIVATIVE; EPOXIDE; IRON; LIGAND; ORGANOMETALLIC COMPOUND; POLYMER; PORPHYRIN; PYRIDINE DERIVATIVE; RUTHENIUM;

ARTICLE; ARTIFICIAL MEMBRANE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; ELECTRODE; OXIDATION REDUCTION REACTION; SURFACE PROPERTY; SYNTHESIS;

CATALYSIS; CYCLOHEXENES; ELECTROCHEMISTRY; ELECTRODES; EPOXY COMPOUNDS; IRON; LIGANDS; MEMBRANES, ARTIFICIAL; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION; POLYMERS; PORPHYRINS; PYRIDINES; RUTHENIUM; SURFACE PROPERTIES;

EID: 25844443770     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la051092e     Document Type: Article

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84. One reviewer pointed out that the anodic voltammetric peak in Figure 2b occurs at more positive potentials than the peak in Figure 2a. Careful examination of these two voltammograms shows that, at the negative edge of the polymer oxidation, there is essentially no catalysis (i.e., curves a and b overlap exactly). One conclusion that might be drawn from this observation is that, prior to ca. 1.1V, the Fe has not yet undergone significant oxidation. The fact that the peak in the catalytic voltammogram is shifted by ca. 80 mV thus could be the result of slow kinetics or the fact that the Fe(III/IV) process occurs at a slightly more positive potential than the dominant Ru(II/III) processes under which it is buried.