Convenient preparation and full characterization of a synthetically useful salt of the dithianitronium cation, SNSSbF6, from readily available starting materials

Inorganic Chemistry

Volumn 44, Issue 19, 2005, Pages 6524-6528

  Cameron, T Stanley ^b   Mailman, Aaron ^a   Passmore, Jack ^a   Shuvaev, Konstantin V ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

^b DALHOUSIE UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 25144511381     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0483139     Document Type: Article

References (68)

1. Parsons, S.; Passmore, J. Acc. Chem. Res. 1994, 27, 101-108.
2. (a) MacLean, G. K.; Passmore, J.; Rao, M. N. S.; Schriver, M. J.; White, P. S.; Bethell, D.; Pilkington, R. S.; Sutcliffe, L. H. J. Chem. Soc., Dalton Trans. 1985, 1405-1416.
3. (b) Parsons, S.; Passmore, J.; Sun, X.; Regitz, M. Can. J. Chem. 1995, 73, 1312-1320 and references therein.
4. (c) Parsons, S.; Passmore, J.; Schriver, M. J.; White, P. J. Chem. Soc., Chem. Commun. 1991, 369-371.
5. (d) Parsons, S.; Passmore, J.; Schriver, M. J.; Sun, X. Inorg. Chem. 1991, 30, 3342-3348.
6. (e) Brooks, W. V. F.; Brownridge, S.; Passmore, J.; Schriver, M. J.; Sun, X. J. Chem. Soc., Dalton Trans. 1996, 1997-2009.
7. (f) Burford, N.; Johnson, J. P.; Passmore, J.; Schriver, M. J.; White, P. J. J. Chem. Soc., Chem. Commun. 1996, 966-968.
8. (g) Passmore, J.; Mailman, A.; Decken, A. Phosphorus, Sulfur, Silicon Relat. Elem. 2004, 179, 977-978.
9. (h) Decken, A.; Mailman, A.; Mattar, S. M.; Passmore, J. J. Chem. Soc. Chem. Commun. 2005, in press.
10. (a) Burford, N.; Passmore, J.; Schriver, M. J. J. Chem. Soc., Chem. Commun. 1986, 140-142.
11. (b) Brooks, W. V. F.; Burford, N.; Passmore, J.; Schriver, M. J.; Sutcliffe, L. H. J. Chem. Soc., Chem. Commun. 1987, 69-71.
12. (c) Brownridge, S.; Du, H.; Fairhurst, S. A.; Haddon, R. C.; Oberhammer, H.; Parsons, S.; Passmore, J.; Schriver, M. J.; Sutcliffe, L. H.; Westwood, N. P. C. J. Chem. Soc., Dalton Trans. 2000, 3365-3382.
13. (d) Awere, E. G.; Burford, N.; Mailer, C.; Passmore, J.; Schriver, M. J.; White, P. S.; Banister, A. J.; Oberhammer, H.; Sutcliffe, L. H. J. Chem. Soc., Chem. Commun. 1987, 66-69.
14. (e) Schriver, M. J., Ph.D. Thesis, University of New Brunswick, 1988.
15. For example see: (a) Du, H.; Haddon, R. C.; Krossing, I.; Rawson, J. M.; Schriver, M. J. J. Chem. Soc., Chem. Commun. 2002, 1836-1837.
16. (b) Fujita, W.; Awaga, K. Science 1999, 286, 261-262.
17. (c) McManus, G. D.; Rawson, J. M.; Feeder, N.; van Duijn, J.; McInnes, E. J. L.; Novoa, J. J.; Burriel, R.; Palacio, F.; Oliete, P. J. Mater. Chem. 2001, 11, 1992-2003.
18. (d) Barclay, T. M.; Cordes, A. W.; George, N. A.; Haddon, R. C.; Itkis, M. E.; Mashuta, M. S.; Oakley, R. T.; Patenaude, G. W.; Reed, R. W.; Richardson, J. F.; Zhang, H. J. Am. Chem. Soc. 1998, 120, 352-360.
19. (e) Fujita, W.; Awaga, K.; Nakazawa, Y.; Saito, K.; Sorai, M. Chem. Phys. Lett. 2002, 352, 348-352.
20. (f) Banister, A. J.; Bricklebank, N.; Lavender, I.; Rawson, J. M.; Gregory, C. I.; Tanner, B. K.; Clegg, W.; Elsegood, M. R. J.; Palacio, F. Angew. Chem., Int. Ed. Engl. 1996, 35, 2533-2534;
21. Angew. Chem. 1996, 108, 2648-2650.
22. Ayres, B.; Banister, A. J.; Coates, P. D.; Hansford, M. I.; Rawson, J. M.; Rickard, C. E. F.; Hursthouse, M. B.; Malik, K. M. A.; Motevalli, M. J. Chem. Soc., Dalton Trans. 1992, 3097-3103.
23. Banister, A. J.; Kendrick, A. G. J. Chem. Soc., Dalton Trans. 1987, 1565-1567.
24. Antorena, G.; Brownridge, S.; Cameron, T. S.; Palacio, F.; Parsons, S.; Passmore, J.; Thompson, L. K.; Zarlaida, F. Can. J. Chem. 2002, 80, 1568-1583 and Supporting Information.
25. (b) Awere, E.; Passmore, J. J. Chem. Soc. Dalton Trans. 1992, 1343-1350 and references therein.
26. (a) Villena-Blanco, M.; Jolly, W. L. Inorg. Synth. 1967, 9, 98-102.
27. (b) Banister, A. J. Inorg. Synth. 1977, 17, 197-198.
28. 6 for 2004: $275/100 g (SynQuest).
29. (a) Jolly, W. L.; Maguire, K. D. Inorg. Synth. 1967, 9, 102-109.
30. (b) Jolly, W. L.; Maguire, K. D. Inorg. Synth. 1967, 9, 109-111.
31. (a) Desjardins, D.; Passmore, J. J. Fluorine Chem. 1975, 6, 379-388.
32. (b) Murchie, M. P.; Kapoor, R. Passmore, J.; Schatte, G. Inorg. Synth. 1996, 31, 102-111.
33. (a) Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Zakrzewski, V. G.; Montgomery, J. A., Jr.; Stratmann, R. E.; Burant, J. C.; Dapprich, S.; Millam, J. M.; Daniels, A. D.; Kudin, K. N.; Strain, M. C.; Farkas, O.; Tomasi, J.; Barone, V.; Cossi, M.; Cammi, R.; Mennucci, B.; Pomelli, C.; Adamo, C.; Clifford, S.; Ochterski, J.; Petersson, G. A.; Ayala, P. Y.; Cui, Q.; Morokuma, K.; Malick, D. K.; Rabuck, A. D.; Raghavachari, K.; Foresman, J. B.; Cioslowski, J.; Ortiz, J. V.; Stefanov, B. B.; Liu, G.; Liashenko, A.; Piskorz, P.; Komaromi, I.; Gomperts, R.; Martin, R. L.; Fox, D. J.; Keith, T.; Al-Laham, M. A.; Peng, C. Y.; Nanayakkara, A.; Gonzalez, C.; Challacombe, M.; Gill, P. M. W.; Johnson, B. G.; Chen, W.; Wong, M. W.; Andres, J. L.; Head-Gordon, M.; Replogle, E. S.; Pople, J. A. Gaussian 98, revision A.3; Gaussian, Inc.: Pittsburgh, PA, 1998.
34. (b) Adamo, C.; Barone, V. J. Chem. Phys. 1998, 108, 664-675.
35. (c) Becke, A. D. Phys. Rev. A 1998, 38, 3098-3100.
36. Gerken, M.; Kolb, P.; Wegner, A.; Mercier, H. P. A.; Borrmann, H.; Dixon, D. A.; Schrobilgen, G. J. Inorg. Chem. 2000, 39, 2813-2824.
37. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed.; John Wiley & Sons: New York, 1986.
38. Sheldrick, G. M. SHELX-97 Programs for Crystal Structure Analysis, Release 97-2; Institut für Anorganische Chemie, Universität Göttingen, 1997.
39. Beursken, P. T.; Admiraal, G.; Beursken, G.; Bosman, W. P.; de Gelder, R.; Israel, R.; Smits, J. M. M. The DIRDIF-94 Program System; Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands, 1994.
40. teXsan for Windows version 1.06: Crystal Structure Analysis Package; Molecular Structure Corporation: The Woodlands, TX, 1997-9.
41. (a) Brooks, W. V. F.; Cameron, T. S.; Grein, F.; Parsons, S.; Pasmore, J.; Schriver, M. J. J. Chem. Soc., Chem. Commun. 1991, 1079-1081.
42. (b) Brooks, W. V. F.; Cameron, T. S.; Parsons, S.; Passmore, J.; Schriver, M. J. Inorg. Chem. 1994, 33, 6230-6241.
43. (a) Kolditz, L. Z. Anorg. Allg. Chem. 1955, 280, 313-320.
44. (b) Murchie, M. P.; Passmore, J.; Sutherland, G. W.; Kapoor, R. J. Chem. Soc., Dalton Trans. 1992, 503-508.
45. Zalkin, A.; Hopkins, T. E.; Templeton, D. H. Inorg. Chem. 1966, 5, 1767-1770.
46. (a) Padma, D. K.; Mews, R. Z. Naturforsch. 1987, 42b, 699-701.
47. (b) Isenberg, W.; Homsy, N. K.; Anhaus, J.; Roesky, H. W.; Sheldrick, G. M. Z. Naturforsch. 1983, 38b, 808-810.
48. 2 in a sealed extractor or thermolysis for high purity (ref 7).
49. Passmore, J.; Schriver, M. J. Inorg. Chem. 1988, 27, 2749-2751.
50. (a) Boyle, P. D.; Cameron, T. S.; Passmore, J.; Schatte, G.; Sutherland, G. W. J. Fluorine Chem. 1995, 71, 217-218.
51. (b) Brownridge, S.; Cameron, T. S.; Passmore, J.; Schatte, G.; Way, T. C. J. Chem. Soc., Dalton Trans. 1996, 2553-2570.
52. (a) Mews, R.; Wagner, D. L.; Glemser, O. Z. Anorg. Allg. Chem. 1975, 412, 148-154.
53. (b) Isenberg, W.; Mews, R. Z. Naturforsch. 1982, 37b, 1388-1392.
54. - = 0.805, and therefore see: Huheey, J. H. In Inorganic Chemistry (Principles of Structure and Reactivity), 2nd ed.; Harper & Row: New York, 1978.
55. (a) Guenther, A. H.; Wiggins, T. A.; Rank, D. H. J. Chem. Phys. 1958, 28, 682-686.
56. (b) The uncorrected values at 0 K were 1.490 (MPW1PW91/6-311G+ (2df)) and 1.505 Å (B3LYP/6-311++G(dp)). These were empirically corrected by multiplying by the ratio of SCS (experimental)/SCS (calculated).
57. Nyburg, S. C.; Faerman, C. H. Acta Crystallogr. 1985, B41, 274-279.
58. o = 1.60 Å. See: (a) Brown, I. D. In Structure and Bonding in Crystals. Vol. 2; O'Keefe, M., Navrotsky, A., Eds.; Academic Press: London, 1981;
59. and (b) Brown, I. D. The Chemical Bond in Inorganic Chemistry (The Bond Valence Model); Oxford University Press: Oxford, 2002.
60. Johnson, J. J.; Passmore, J.; White, P. S.; Banister, A. J.; Kendrick, A. G.; Acta Crystallogr. 1987, C43, 1651-1653.
61. Faggiani, R.; Gillespie, R. J.; Lock, C. J. L.; Tyrer, J. D. Inorg. Chem. 1978, 17, 2975-2978.
62. Thewalt, V. U.; Berhalter, K.; Müller, P. Acta Crystallogr. 1982, B38, 1280-1282.
63. (a) Gimarc, B. M.; Warren, D. S. Inorg. Chem. 1991, 30, 3276-3280.
64. (b) Grein, F. Can. J. Chem. 1993, 71, 335-340.
65. (a) Jenkins, H. D. B.; Roobottom, H. K.; Passmore, J.; Glasser, L. Inorg. Chem. 1999, 38, 3609-3620.
66. O'Hare, P. A. G.; Awere, E. G.; Parsons, S.; Passmore, J. J. Chem. Thermodyn. 1989, 21, 153-158.
67. (a) Jenkins, H. D. B.; Roobottom, H. K.; Passmore, J. Inorg. Chem. 2003, 42, 2886-2893.
68. (b) Jenkins, H. D. B.; Krossing, I.; Passmore, J. J. Fluorine Chem. 2004, 125, 1585-1592.