Hexafluoroantimony(v) salts of the cationic Ti(iv) fluoride non metallocene complexes [TiF3(MeCN)3]+ and [TiF2L]2+ (L = 15-Crown-5 and 18-Crown-6). Preparation, characterization and thermodynamic stability

Dalton Transactions

Volumn , Issue 18, 2005, Pages 3039-3050

  Decken, Andreas ^a   Ilyin, Evgeny G ^b   Jenkins, H Donald Brooke ^c   Nikiforov, Grigori B ^a   Passmore, Jack ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

^b KURNAKOV INSTITUTE OF GENERAL AND INORGANIC CHEMISTRY   (Russian Federation)

^c UNIVERSITY OF WARWICK   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

CHARACTERIZATION; NUCLEAR MAGNETIC RESONANCE; SALTS; SPECTROSCOPY; THERMODYNAMIC STABILITY; X RAY ANALYSIS;

BOND ENERGY; MASS SPECTROSCOPY; OXOFLUORIDE;

TITANIUM COMPOUNDS;

EID: 25144476080     PISSN: 14779226     EISSN: None     Source Type: Journal    
DOI: 10.1039/b500993f     Document Type: Article

References (156)

1. -;
2. (b) D. A. McCaulay, W. S. Higley and A. P. Lien, J. Am. Chem. Soc., 1956, 78, 309;
3. (c) J. C. Haartz and D. H. McDaniel, J. Am. Chem. Soc., 1973, 95, 8562.
4. (a) E. L. Muetterties, J. Am. Chem. Soc., 1960, 82, 1082;
5. (b) S. A. A. Zaidi, T. A. Khan and B. S. Neelam, J. Inorg. Nucl. Chem., 1980, 42, 1525;
6. (c) R. G. H. Clark and W. Errington, J. Chem. Soc. (A), 1967, 258;
7. (d) D. S. Dyer and R. O. Ragsdale, Chem. Commun., 1966, 601;
8. (e) D. S. Dyer and R. O. Ragsdale, Inorg. Chem., 1969, 8,1116;
9. (f) E. Turin, R. M. Nielson and A. E. Merbach, Inorg. Chim. Acta, 1987, 134, 67.
10. (a) P. P. K. Claire, G. R. Willey and M. G. B. Drew, Chem. Commun., 1987, 14, 1100;
11. (b) P. N. Billinger, P. P. K. Claire, H. Collins and G. R. Willey, Inorg. Chim. Acta, 1988, 149, 63;
12. (c) M. Plate, G. Frenzen and K. Dehnicke, Z. Naturforsch., 1993, 48b, 149;
13. (d) K. Berhalter and U. Thewalt, J. Organomet. Chem., 1987, 332, 123.
14. (a) V. K. Bel'skii, B. M. Bulichev and N. R. Strel'tsova, Zh. Neorganicheskoi Khim., 1992, 37, 1531;
15. J. J. Eisch, A. M. Piotrowski, S. K. Brownstein, E. J. Gabe and F. L. Lee, J. Am. Chem. Soc., 1985, 107, 7219;
16. (c) S. K. Brownstein, E. J. Gabe, N. F. Han, F. L. Lee, Y. le Page, A. M. Piotrowski and J. J. Eisch, J. Chem. Res., 1992, 214, 1642.
17. (a) U. Thewalt and H.-P. Klein, J. Organomet. Chem., 1980, 194, 297;
18. (b) H.-P. Klein and U. Thewalt, Z. Anorg. Allg. Chem., 1981, 467, 62;
19. (c) U. Thewalt and K. Berhalter, J. Organomet. Chem., 1986, 302, 193;
20. (d) U. Thewalt, K. Berhalter and E. W. Neuse, Transition Met. Chem., 1985, 10, 393;
21. (e) M. G. Meirim and E. W. Neuse, Transition Met. Chem., 1984, 9, 337.
22. (a) P. Gowik and T. Klapötke, J. Organomet. Chem., 1990, 398, 1;
23. (b) P. Gowik, T. Klapötke and U. Thewalt, J. Organomet. Chem., 1990, 385, 345;
24. (c) T. Klapötke and U. Thewalt, J. Organomet. Chem., 1988, 356, 173.
25. (a) M. Bochmann, L. M. Wilson, M. B. Hursthouse and M. Motevalli, Organometallics, 1988, 7, 1148;
26. (b) P. A. Seewald, G. S. White and D. W. Stephan, Can. J. Chem., 1988, 66, 1147.
27. G. R. Willey, J. Palin and N. W. Alcock, J. Chem. Soc., Dalton Trans., 1992, 1117.
28. (a) G. W. A. Fowles, T. E. Lester and J. S. Wood, J. Inorg. Nucl. Chem., 1969, 31, 657;
29. (b) K. Folting, J. C. Huffman, R. L. Bansemer and K. G. Caulton, Inorg. Chem., 1984, 23, 3289;
30. (c) M. Handlovic and F. Hanic, J. Cryst. Mol. Struct., 1974, 4, 327.
31. (a) V. V. Burlakov, P. Arndt, W. Baumann, A. Spannenberg, U. Rosenthal, A. V. Letov, K. A. Lyssenko, A. A. Korlyukov, L. I. Strunkina, M. Kh. Minacheva and V. B. Shur, Organometallics, 2001, 20, 4072;
32. (b) W. W. Ellis, A. Gavrilova, L. Liable-Sands, A. L. Rheingold and B. Bosnich, Organometallics, 1999, 18, 332;
33. (c) D. G. Sekutowski and G. D. Stucky, Inorg. Chem., 1975, 14, 2192;
34. (d) T. A. Wark and D. W. Stephan, Inorg. Chem., 1987, 26, 363;
35. (e) B. Honold and U. Thewalt, J. Organomet. Chem., 1986, 316, 291;
36. (f) H. Aslan, T. Sielisch and R. D. Fischer, J. Organomet. Chem., 1986, 315, C69;
37. (g) U. Thewalt and B. Honold, J. Organomet. Chem., 1988, 348, 291;
38. (h) M. G. Thorn, Z. C. Etheridge, P. E. Fanwick and I. P. Rothwell, Organometallics, 1998, 17, 3636.
39. (a) A. Kayal, J. Kuncheria and S. C. Lee, Chem. Commun., 2001, 23, 2482;
40. (b) F. Guerin, J. C. Stewart, C. Beddie and D. W. Stephan, Organometallics, 2000, 19, 2994;
41. (c) K. Wieghardt, D. Ventur, Y. H. Tsai and C. Kruger, Inorg. Chim. Acta, 1985, 99, L25;
42. (d) U. Thewalt and K. Berhalter, J. Organomet. Chem., 1986, 302, 193;
43. (e) N. L. S. Yue and D. W. Stephan, Organometallics, 2001, 20, 2303;
44. (f) C.-H. Yang and V. L. Goedken, Inorg. Chim. Acta, 1986, 117, L19.
45. (a) E. G. Il'in, G. B. Nikiforov, G. G. Aleksandrov, V. S. Sergienko and Yu. A. Buslaev, Dokl. Chem., 1999, 367, 772;
46. (b) E. G. Il'in, G. B. Nikiforov, M. E. Ignatov and Yu. A. Buslaev, Dokl Chem., 1999, 369, 770;
47. (c) E. G. Il'in, G. B. Nikiforov and Yu. A. Buslaev, Dokl. Chem., 2000, 375, 242;
48. (d) E. G. Il'in, G. B. Nikiforov and Yu. A. Buslaev, Dokl. Chem., 2001, 376, 8;
49. (e) R. S. Borden and R. N. Hammer, Inorg. Chem., 1970, 9, 2004.
50. A. Bodner, P. Jeske, T. Weyhermiiller, K. Wieghardt, E. Dubler, H. Schmalle and B. Nubert, Inorg. Chem., 1992, 31, 3737.
51. L. Kiriazis and R. Mattes, Z. Anorg. Allg. Chem., 1991, 593, 90.
52. M. W. Bouwkamp, J. de Wolf, I. del H. Morales, J. Gercama, A. Meetsma, S. I. Troyanov, B. Hessen and J. H. Teuben, J. Am. Chem. Soc., 2002, 124, 12956.
53. (a) D. S. Payne, Halides and Oxyhalides of Group V Elements as Solvents, in Nonaqueous Solvent Systems, ed. T. C. Waddington, Academic Press, London, 1965, ch. 8;
54. (b) S. Brownridge, I. Krossing, J. Passmore, H. D. B. Jenkins and H. K. Roobottom, Coord. Chem. Rev., 2000, 197, 397;
55. (c) H. D. B. Jenkins, H. K. Roobottom, J. Passmore and L. Glasser, Inorg. Chem., 1999,38, 3609;
56. (d) R. Mews, E. Lork, P. G. Watson and B. Gortler, Coord. Chem. Rev., 2000, 197, 277.
57. (a) A. Bondi, J. Phys. Chem., 1964, 68, 441;
58. (b) N. L. Allinger, J. A. Hirsch, M. Ann Miller, I. J. Tyminski and F. A. Van Catledge, J. Am. Chem. Soc., 1968, 90, 1199.
59. (a) I. D. Brown, Structure and Bonding in Crystals, ed. M. O'Keefe, A. Navrotsky, Academic Press, London, 1981;
60. (b) I. D. Brown and D. Altermatt, Acta Crystallogr., 1985, B41, 244;
61. (c) N. E. Brese and M. O'Keefe, Acta Crystallogr., 1991, B47, 192;
62. (d) Values used: Ti(+4)-F(-1) R = 1.76, B = 0.37, Ti(+4)-N(-3) R = 1.93, B = 0.37, Ti(+4)-O(-2) R = 1.815, B = 0.37.
63. (a) S. Rabe and U. Müller, Z. Anorg. Allg. Chem., 2001, 627, 201;
64. (b) S. I. Troyanov, G. N. Mazo and M. A. Simonov, Koord. Khim., 1985, 11, 1147.
65. H. Bialowons, M. Müller and B. G. Müller, Z. Anorg. Allg. Chem., 1995, 621, 1227.
66. (a) D. S. Dyer and R. O. Ragsdale, Chem. Commun., 1966, 601;
67. (b) D. S. Dyer and R. O. Ragsdale, Inorg. Chem., 1969, 8, 1116.
68. (a) H. W. Roesky and I. Haiduc, Dalton Trans., 1999, 2249;
69. (b) E. F. Murphy, R. Murugavel and H. W. Roesky, Chem. Rev., 1997, 97, 3425.
70. E. G. Il'in, G. G. Aleksandrov, G. B. Nikiforov and Yu. A. Buslaev, Dokl, Chem., 2004, 396, 111.
71. E. G. Il'in, G. G. Aleksandrov, G. B. Nikiforov and Yu. A. Buslaev, Dokl. Chem., 2001, 376, 25.
72. E. G. Il'in, G. B. Nikiforov, G. G. Aleksandrov, H. W. Roesky and Yu. A. Buslaev, Dokl. Chem., 2001, 376, 58.
73. Z. Tun and I. D. Brown, Acta Crystallogr., 1982, 38B, 1792.
74. M. S. Dadachov, L. Q. Tang and X. D. Zou, Z. Kristallogr., 2000, 215, 605.
75. A. Herzog, F.-Q. Liu, H. W. Roesky, A. Demsar, K. Keller, M. Noltemeyer and F. Pauer, Organometallics, 1994, 13, 1521.
76. R. Beckhaus, J. Sang, J. Oster and T. Wagner, J. Organomet. Chem., 1994, 484, 179.
77. T. S. Cameron, A. Decken, E. G. Ilyin, G. B. Nikiforov and J. Passmore, Eur. J. Inorg. Chem., 2004, 3865.
78. A. Penicaud, P. Batail, K. Bechgaard and J. Sala-Pala, Synth. Met., 1988, 22, 201.
79. A. Vij, W. W. Wilson, V. Vij, F. S. Tham, J. A. Sheehy and K. O. Christe, J. Am. Chem. Soc., 2001, 123, 6308.
80. G. Herzberg, Molecular Spectra and Molecular Structure, 2. Infrared and Raman Spectra of Polyatomic Molecules, D. Van NostrandNew York, Toronto, 2nd edn., 1950, p. 332.
81. D. M. Byler and D. F Shriver, Inorg. Chem., 1973, 12, 1412.
82. 3v, consistent with the crystallographic result;
83. (b) W. Preetz, D. Ruf and D. Tensfeldt, Z. Naturforsch., 1984, 39b, 1100.
84. (a) G. V. D. Tiers, J. Am. Chem. Sue., 1962, 84, 3972;
85. (b) R. K. Harris, J. Mol. Spectrosc., 1963, 10, 309;
86. Hudlicky, Milos, Chemistry of organic fluorine compounds II: a critical review, Washington, DC: American Chemical Society, 1995, p. 1104.
87. 4 and C-Cl.
88. G. B. Nikiforov, S. G. Sakharov, E. G. Il'in and Ju. A. Buslaev, Rus. J. Inorg. Chem., 2001, 46, 1045.
89. (a) S. C. Abrahams and E. Prince, J. Chem. Phys., 1962, 36, 50;
90. (b) S. C. Abrahams, J. Chem. Phys., 1962, 36, 56;
91. (c) W. C. Hamilton, Acta Cryst., 1962, 15, 353.
92. G. Frenzen, W. Massa, T. Ernst and K. Dehnicke, Z. Naturforsch., 1990, 45b, 1393.
93. H. H. Eysel and K. Seppelt, J. Chem. Phys., 1972, 56, 5081.
94. (a) S. Daniele, R. Papiernik, L. G. Hubert-Pfalzgraf, S. Jagner and M. Hikansson, Inorg. Chem., 1995, 34, 628;
95. (b) J. Pauls, E. Iravani, P. Köhl and B. Neumüller, Z. Anorg. Allg. Chem., 2004, 630, 876;
96. (c) I. Baxter, S. R. Drake, M. B. Hursthouse, K. M. A. Malik, D. M. P. Mingos, J. C. Plakatouras and D. J. Otway, Polyhedron, 1998, 17, 625;
97. (d) G. Westin, R. Norrestam, M. Nygren and M. Wijk, J. Solid State Chem., 1998, 135, 149.
98. (a) V. Gutmann, Coordination Chemistry in Non-Aqueous Solutions, Springer-Verlag, Berlin and New York, 1968;
99. (b) V. Gutman and R. Schmid, Coord. Chem. Rev., 1973, 12, 263;
100. (c) Ed. By J. J. Lagowsky, The Chemistry of Nonaqueous Solvents, V. VA, Academic Press. New York. 1978. pp. 63-119;
101. (d) V. Gutman and E. Wychera, Inorg. Nucl. Chem. Lett., 1966, 2, 257.
102. G. B. Nikiforov, Ph. D. Thesis: Institute of General and Inorganic Chemistry RAS, 2001, Moscow.
103. (a) G. Olofsson, Acta Chem. Scand., 1967, 21, 1887;
104. (b) G. Olofsson, Acta Chem. Scand., 1968, 22, 1352.
105. 43,44.
106. 2 (Table 4) and it was assumed that the solvent effect is a small one.
107. 43.
108. 2] = 3;
109. Hf(MeCN, s-s) can however be estimated (see text);
110. (c) Handbook of Chemistry 7 Physics, 79th edn., ed. D. R. Lide, C. R. C. Press, Boca Raton, FL, 1998;
111. (d) H. D. B. Jenkins, D. Tudela and L. Classer, Inorg. Chem, 2002, 41, 2364;
112. (e) L. Glasser and H. D. B. Jenkins, J. Am. Chem. Soc., 2000, 122, 632;
113. (f) H. D. B. Jenkins and L. Glasser, Inorg. Chem, 2002, 41, 4378;
114. (g) T. S. Cameron, R. J. Deeth, I. Dionne, H. Du, H. D. B. Jenkins, I. Krossing, J. Passmore and H. K. Roobottom, Inorg. Chem, 2000, 39, 5614;
115. (h) Y Marcus, H. D. B. Jenkins and L. Glasser, Dalton Trans., 2002, 3795;
116. (i) H. D. B. Jenkins and D. Tudela, J. Chem. Educ., 2003, 80, 1482;
117. 15. Entry 102, ed. K.-H. Hellewege and O. Madelung, Springer-Verlag, Heidelberg, 1979;
118. (K) H. D. B. Jenkins, H. K. Roobottom and J. Passmore, Inorg. Chem., 2003, 42, 2886.
119. H. D. B. Jenkins and L. Glasser, J. Am. Chem. Soc, 2004, 126, 15809.
120. H. D. B. Jenkins, L. Glasser, T. M. Klapotke, M.-J. Crawford, K. K. Bhasin, J. Lee, G. J. Schrobilgen, L. S. Sunderlin and J. F. Liebman, Inorg. Chem., 2004, 43, 6238.
121. -1 (See Appendix 1, ref. [49k].
122. N. Nasu, Bull. Chem. Soc. Jpn., 1933, 8, 195-207.
123. G. S. H. Chen and J. Passmore, Dalton Trans., 1979, 1251.
124. 57.
125. - (g) -259.8 [56f ,i,j];
126. (b) J. Burgess, R. D. Peacock and R. Sherry, J. Fluor. Chem., 1982, 20, 541;
127. (c) R. Bougon, T. Bui Huy, J. Burgess, K. O. Christe and R. D. Peacock, J. Fluorine Chem., 1982, 19, 263;
128. (d) E. Greenberg, J. L. Settle and W. N. Hubbard, J. Phys. Chem., 1962, 66, 1345;
129. (e) L. V. Gurvich, I. V. Veyts, C. B. Alcock, Thermodynamic Properties of Individual Substances; Hemisphere Publishing Corporation, NY, 1989;
130. (f) Thermodynamic Database: http://www.chem.msu.su/cgi-bin/tkv2.pl;
131. (g) K. P. Zmbov and J. L. Margrave, J. Phys. Chem., 1967, 71, 2893;
132. (A) I. N. Bakulina and N. I. Ionov, Rus J. Phys. Chem., 1959, 33, 2063;
133. (i) R. S. Berry and C. W. Reimann, J. Chem. Phys., 1963, 38, 1540;
134. (j) D. Cubicciotti, J. Chem. Phys., 1961, 34, 2189;
135. (k) H. D. B. Jenkins, I. Krossing, J. Passmore and I. Raabe, J. Fluor. Chem., 2004, 125, 1585.
136. H. D. B. Jenkins and L. Glasser, Inorg. Chem., 2003, 42, 8702.
137. H. D. B. Jenkins, H. K. Roobottom and J. Passmore, Inorg. Chem., 2003, 42, 2886.
138. F. Meyer, F. A. Khan and P. B. Armentrout, J. Am. Chem. Soc., 1995, 117, 9740.
139. L. Pauling, The Nature of the Chemical Bond, 3rd edn., Cornell University Press, Ithaca N.Y., 1960, p. 514.
140. M. P. Murchie, J. Passmore, R. Kapoor, G. Schatte and T. Way, Inorg. Synth., 1997, 31, 102.
141. (a) R. G. Kidd and R. W. Matthew, Inorg. Chem., 1972, 11, 1156;
142. (b) D. M. Byler and D. F. Shriver, Inorg. Chem., 1976, 15, 32;
143. (c) J. Bacon, P. A. W. Dean and R. J. Gillespie, Can. J. Chem., 1969, 47, 1655.
144. J. W. Moore, H. W. Baird and H. B. Miller, J. Am. Chem. Soc., 1968, 90, 1358.
145. P. A. W. Dean and R. J. Gillespie, J. Am. Chem. Soc., 1969, 17, 7260.
146. (a) J. Bacon, P. A. W. Dean and R. J. Gillespie, Can. J. Chem., 1970, 48, 3413;
147. (b) R. J. Gillespie and K. C. Moss, J. Chem. Soc. A, 1966, 1170.
148. G. V. D. Tiers, J. Am. Chem. Soc., 1957, 79, 5585.
149. NUTS, NMR data processing program, Acorn NMR 1993, 1994, Assaid, C. Randolf Macon College.
150. (a) P. A. W. Dean, Can. J. Chem., 1973, 51, 4024;
151. (b) J. Pauli, W. Storek and L. Riesel, Z. Chem., 1988, H.6, B.226.
152. (a) R. L. Garrell, J. C. Smyth, F. R. Fronczek and R. D. Gandour, J. Inclusion Phenom. Macrocyclic Chem., 1988,6, 73;
153. (b) F. Weller, H. Borgholte, H. Stenger, S. Vogler and K. Dehnicke, Z. Naturforsch., 1989, 44B, 1524.
154. SAINT 6.02, 1997-1999, Bruker AXS, Inc., Madison, WI, USA.
155. SADABS George Sheldrick, 1999, Bruker AXS, Inc., Madison, WI, USA.
156. SHELXTL 5.1, George Sheldrick, 1997, Bruker AXS, Inc., Madison, WI, USA.