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Volumn 44, Issue 37, 2005, Pages 6033-6038

Transition-state effects of ionic liquids in substitution reactions of PtII complexes

Author keywords

Density functional calculations; Ionic liquids; Kinetics; Platinum; Reaction mechanisms

Indexed keywords

COMPLEXATION; ELECTRON TRANSITIONS; IONIC CONDUCTION; METHANOL; PROBABILITY DENSITY FUNCTION; REACTION KINETICS; SUBSTITUTION REACTIONS; WATER;

EID: 25144466108     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200501329     Document Type: Article
Times cited : (61)

References (44)
  • 24
    • 33845470176 scopus 로고
    • It has been pointed out that corrections made to second-order rate constants to compensate for changes in solvent density are incorrect as all kinetic parameters are defined in terms of concentration units under ambient conditions, that is, the conditions under which all solutions were prepared, see: S. D. Hamann, W. J. le Noble, J. Chem. Educ. 1984, 61, 658.
    • (1984) J. Chem. Educ. , vol.61 , pp. 658
    • Hamann, S.D.1    Le Noble, W.J.2
  • 25
    • 0037173667 scopus 로고    scopus 로고
    • No corrections were made to compensate for the temperature and pressure dependence of the solvent viscosity as the investigated bimolecular reaction is slow and far away from a diffusion-controlled chemical process for which viscosity dependence is to be expected. It has been demonstrated elsewhere that slow bimolecular reactions in general do not exhibit meaningful viscosity dependence, see: C. F. Weber, R. van Eldik, J. Phys. Chem. A 2002, 106, 6904.
    • (2002) J. Phys. Chem. A , vol.106 , pp. 6904
    • Weber, C.F.1    Van Eldik, R.2
  • 41
    • 25144519651 scopus 로고    scopus 로고
    • Reference [22], p. 417
    • Reference [22], p. 417.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.