Diastereoselective epoxidation of allylic diols derived from Baylis-Hillman adducts

Synthesis

Volumn , Issue 14, 2005, Pages 2297-2306

  Porto, Ricardo S ^a   Vasconcellos, Mario L A A ^b   Ventura, Elizete ^b   Coelho, Fernando ^a  

^a UNIVERSITY OF CAMPINAS   (Brazil)

^b FEDERAL UNIVERSITY OF PARAÍBA   (Brazil)

Author keywords

Allylic alcohol; Baylis Hillman reaction; Diastereoselectivity; Epoxidation; Silicon

Indexed keywords

HYDROGEN BONDS; MOLECULAR STRUCTURE; OXIDATION; REACTION KINETICS;

ALLYLIC ALCOHOL; BAYLIS-HILLMAN REACTION; DIASTEREOSELECTIVITY; EPOXIDATION;

ALCOHOLS;

ACRYLIC ACID DERIVATIVE; METHYL 2 (1 TERT BUTYLDIMETHYLSILYLOXYBUTYL 3 METHYL)ACRYLATE; METHYL 2 (1 TERT BUTYLDIMETHYLSILYLOXYPROPYL)ACRYLATE; METHYL 2 [(2 BROMOPHENYL)(TERT BUTYLDIMETHYLSILYLOXY)METHYL]ACRYLATE; METHYL 2 [(4 BROMOPHENYL)(TERT BUTYLDIMETHYLSILYLOXY)METHYL]ACRYLATE; METHYL 2 [(6 BROMO 1,3 BENZODIOXOL 5 YL)(TERT BUTYLDIMETHYLSILYLOXY)METHYL]ACRYLATE; METHYL 2 [(TERT BUTYLDIMETHYLSILYLOXY)(4 METHOXYPHENYL)METHYL]ACRYLATE; METHYL 2 [(TERT BUTYLDIMETHYLSILYLOXY)(PHENYL)METHYL]ACRYLATE; UNCLASSIFIED DRUG;

ARTICLE; BAYLIS HILLMAN REACTION; EPOXIDATION; HYDROGEN BOND; STEREOCHEMISTRY;

EID: 24944546079     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2005-872091     Document Type: Article

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