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Volumn 42, Issue 19, 2003, Pages 5801-5803

Triangular, ferromagnetically-coupled CuII 3-pyrazolato complexes as possible models of particulate methane monooxygenase (pMMO)

Author keywords

[No Author keywords available]

Indexed keywords

BROMINE; CHLORINE; COPPER; COPPER COMPLEX; FERROMAGNETIC MATERIAL; IRON; METHANE MONOOXYGENASE; ORGANOMETALLIC COMPOUND; OXYGENASE; PYRAZOLE DERIVATIVE;

EID: 0141591745     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0344416     Document Type: Article
Times cited : (94)

References (26)
  • 12
    • 0141590702 scopus 로고    scopus 로고
    • note
    • 2. The crystal structure of 1a shows one pyrazole partially brominated (40%) at the 4-position; similar unexpected chlorination of a pyrazole ligand under mild conditions has been observed elsewhere.
  • 14
    • 0141479175 scopus 로고    scopus 로고
    • note
    • max = 46.56°, 13162 reflections measured (8478 independent, R(int) = 0.0434), R1 = 0.0559 and wR2 = 0.0960 for 3923 reflections with I > 2σ(I) (0.1493 and 0.1192 for all data) and 603 parameters.
  • 15
    • 0141590703 scopus 로고    scopus 로고
    • note
    • 2.
  • 16
    • 0141479174 scopus 로고    scopus 로고
    • note
    • Modified Varian E4 spectrometer, 9.23 GHz for 1b, 9.10 GHz for 2.
  • 17
    • 0141590701 scopus 로고    scopus 로고
    • note
    • The discrepancy between g-values determined by EPR or magnetic susceptibility for 1b is attributed to the different nature of those measurements; all populated states contribute to bulk magnetic susceptibility, while fast-relaxing states are not observable by EPR.
  • 21
    • 0141813832 scopus 로고    scopus 로고
    • note
    • 3 framework remains invariant in those complexes, the weaker contribution of the μ-pz* ligands is considered constant and ignored in the present discussion.
  • 23
    • 0141479173 scopus 로고    scopus 로고
    • note
    • 1′, respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.