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-1 is responsible for the C-H stretching mode of the methylene group in TEA, and the band is under the influence of hyperconjugation between σ* of the C-H bond and the lone pair electron on the N-atom (see ref 25). In the presence of CP, since TEA and CP produces a hydrogen bond in the droplet, this will cause the changes in the Raman shift and scattering intensity of the C-H band.
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As one of the reviewers has pointed out, when we use a solute with a refractive index smaller than that of TEA, concentration effects of the solute to a TEA droplet will not be observed. Such an experiment will prove a role of radiation pressure in the extraction/concentration phenomena observed in the present study. Experiments are now in progress, and the results will be reported in a separate publication.
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74
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24944438099
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note
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b = 1.489) as predicted from eqs 2 and 3.
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