β-diketiminato scandium chemistry: Synthesis, characterization, and thermal behavior of primary amido alkyl derivatives

Organometallics

Volumn 23, Issue 9, 2004, Pages 2087-2094

  Knight, Lisa K ^a   Piers, Warren E ^a   Fleurat Lessard, Paul ^a,c   Parvez, Masood ^a   McDonald, Robert ^b  

^a UNIVERSITY OF CALGARY   (Canada)

^b UNIVERSITY OF ALBERTA   (Canada)

^c UNIVERSITÉ DE LYON   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CRYSTALLOGRAPHY; DECOMPOSITION; DIMERS; NUCLEAR MAGNETIC RESONANCE; POLYMERIZATION; SCANDIUM; SUBSTRATES;

AMIDO ALKYL DERIVATIVES; AMIDO LIGAND; DIASTEREOMER; MONOMERIC COMPOUNDS;

ORGANOMETALLICS;

EID: 2442428420     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034345c     Document Type: Article

References (45)

1. (a) Gade, L. H.; Mountford, P. Coord. Chem. Rev. 2001, 216-217, 65.
2. (b) Duncan, A. P.; Bergmann, R. G. Chem. Rec. 2002, 2, 431.
3. (a) Chan, M. C. W.; Cole, J. M.; Gibson, V. C.; Howard, J. A. K.; Lehmann, C.; Poole, A.; Siemeling, U. J. Chem. Soc., Dalton Trans. 1998, 103.
4. (b) Gibson, V. C.; Redshaw, C.; Clegg, W.; Elsegood, M. R. J.; Siemeling, U.; Türk, T. J. Chem. Soc., Daltion Trans. 1996, 4513.
5. (c) Gibson, V. C. Mod. Coord. Chem. 2002, 140.
6. Walsh, P. J.; Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 8729.
7. (b) Walsh, P. J.; Hollander, F. J.; Bergman, R. G. Organometallics 1993, 12, 3705.
8. (c) Cummins, C. C.; Baxter, S. M.; Wolczanski, P. T. J. Am. Chem. Soc. 1988, 110, 8731.
9. (d) Schaller, C. P.; Cummins, C. C.; Wolczanski, P. T. J. Am. Chem. Soc. 1996, 118, 591.
10. (e) Wolczanski, P. T.; Bennett, J. L. J. Am. Chem. Soc. 1994, 116, 2179.
11. Bytschkov, I.; Doye, S. Eur. J. Org. Chem. 2003, 935.
12. Emslie, D. J. H.; Piers, W. E. Coord. Chem. Rev. 2002, 233-34, 129.
13. Beetstra, D. J.; Meetsma, A.; Hessen, B.; Teuben, J. H. Organometallics 2003, 22, 4372.
14. Other related examples: (a) Gordon, J. C.; Giesbrecht, G. R.; Clark, D. L.; Hay, J.; Keogh, D. W.; Poli, R.; Scott, B. L.; Watkin, J. G.; Organometallics 2002, 21, 4726. (b) Chan, H.-S.; Li, H.-W.; Xie, Z. Chem. Commun. 2002, 652.
15. Other related examples: (a) Gordon, J. C.; Giesbrecht, G. R.; Clark, D. L.; Hay, J.; Keogh, D. W.; Poli, R.; Scott, B. L.; Watkin, J. G.; Organometallics 2002, 21, 4726. (b) Chan, H.-S.; Li, H.-W.; Xie, Z. Chem. Commun. 2002, 652.
16. Hayes, P. G.; Lee, L. W. M.; Knight, L. K.; Piers, W. E.; Parvez, M.; Elsegood, M. R. J.; Clegg, W.; MacDonald, R. Organometallics 2001, 20, 2533.
17. Budzelaar, P. H. M.; van Oort, A. B.; Orpen, A. G. Eur. J. Inorg. Chem. 1998, 1485.
18. Lauterwasser, F.; Hayes, P. G.; Piers, W. E.; Brase, S.; Schafer, L. L. Organometallics 2004, 23, in press.
19. Ryu, J.-S.; Li, G. Y.; Marks, T. J. J. Am. Chem. Soc. 2003, 125, 12584.
20. For a recent paper on mono-ligand bis-amido and alkyl precursors, see: Hong, S.; Tian, S.; Metz, M. V.; Marks, T. J. J. Am. Chem. Soc. 2003, 125, 14768.
21. These bulky β-diketiminato liganda have been used to generate monomeric group 13 imido complexes: (a) Cui, C. M.; Roesky, H. W.; Schmidt, H. G.; Noltemeyer, M. Angew. Chem., Int. Ed. 2000, 39, 4531. (b) Hardman, N. J.; Cui, C. M.; Roesky, H. W.; Fink, W. F.; Power, P. P. Angew. Chem., Int. Ed. 2001, 40, 2172.
22. These bulky β-diketiminato liganda have been used to generate monomeric group 13 imido complexes: (a) Cui, C. M.; Roesky, H. W.; Schmidt, H. G.; Noltemeyer, M. Angew. Chem., Int. Ed. 2000, 39, 4531. (b) Hardman, N. J.; Cui, C. M.; Roesky, H. W.; Fink, W. F.; Power, P. P. Angew. Chem., Int. Ed. 2001, 40, 2172.
23. Hayes, P. G.; Piers, W. E.; Parvez, M, J. Am. Chem. Soc. 2003, 125, 5622.
24. Basuli, F.; Tomaazewski, J.; Huffman, J. C.; Mindiola, D. J. Organometallics 2003, 22, 4705.
25. Hayes, P. G.; Piers, W. E.; McDonald, R. J. Am. Chem. Soc. 2002, 124, 2132.
26. Knight, L. K.; Piers, W. E.; McDonald, R. Chem. Eur. J. 2000, 6, 4322.
27. -1; see ref 10.
28. Hayes, P. G.; Piers, W. E., unpublished results.
29. Fekl, U.; Goldberg, K. I. J. Am. Chem. Soc. 2002, 124, 6804.
30. Pangborn, A. B.; Giardello, M. A.; Grubbs, R. H.; Rosen, R. K.; Timmers, F. J. Organometallics 1998, 15, 1518.
31. Marvich, R. H.; Brintzinger, H. H. J. Am. Chem. Soc. 1971, 93, 2046.
32. Ammann, C.; Meier, P.; Merbach, A. E. J. Magn. Reson. 1982, 46, 319.
33. Manzer, L. Inorg. Synth. 1982, 21, 135.
34. (a) Baerends, E. J. Ph.D. Thesis, Free University, Amsterdam, The Netherlands, 1973.
35. (b) Baerends, E. J.; Ellis, D. E.; Ros, P. Chem. Phys. 1973, 2, 41.
36. Ravenek, W. In Algorithms and Applications on Vector and Parallel Computers; te Riele, H. J. J., Dekker, T. J., van de Horst, H. A., Eds.; Elsevier: Amsterdam, The Netherlands, 1987.
37. Boerrigter, P. M.; te Velde, G.; Baerends, E. J. Int. J. Quantum Chem. 1988, 33, 87.
38. (a) Becke, A. Phys. Rev. A 1988, 38, 3098.
39. (b) Perdew, J. P. Phys. Rev. B 1986, 34, 7406.
40. (c) Perdew, J. P. Phys. Rev. B 1988, 35, 8822.
41. te Velde, G.; Baerends, E. J. Comput. Chem. 1992, 99, 84.
42. Krijn, J.; Baerends, E. J.; Vernoijs, P. At. Nucl. Data Tables 1982, 26, 483.
43. (a) Nalewajski, R. F.; Mrozek, J. Int. J. Quantum Chem. 1994, 51, 187.
44. (b) Nalewajski, R. F.; Mrozek, J.; Mazur, G. Can. J. Chem. 1996, 74, 1121.
45. (c) Mrozek, J.; Nalewajski, R. F.; Michalak, A. Polish J. Chem. 1998, 72, 1779.