Reaction of the stable silylene Si[(NCH2But) 2C6H4-1,2] with lithium amides

Dalton Transactions

Volumn , Issue 16, 2005, Pages 2720-2725

  Gehrhus, Barbara ^a   Hitchcock, Peter B ^a   Parruci, Massimo ^a  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

LITHIUM AMIDES; SILYLENE; X-RAY STRUCTURES;

AMINES; LITHIUM COMPOUNDS; OXIDATION; REACTION KINETICS; THERMOANALYSIS; THERMODYNAMIC STABILITY;

SILICON COMPOUNDS;

AMIDE; LITHIUM; ORGANOSILICON DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SENSITIVITY AND SPECIFICITY; STEREOISOMERISM; SYNTHESIS;

AMIDES; LITHIUM; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOSILICON COMPOUNDS; SENSITIVITY AND SPECIFICITY; STEREOISOMERISM;

EID: 24144441699     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b506610g     Document Type: Article

References (21)

1. M. Denk, R. Lennon, R. Hayashi, R. West, A. V. Belyakov, H. P. Verne, A. Haaland, M. Wagner and N. Metzler, J. Am. Chem. Soc., 1994, 116, 2691.
2. B. Gehrhus, M. F. Lappert, J. Heinicke, R. Boese and D. Bläser, J. Chem. Soc., Chem. Commun., 1995, 1931.
3. B. Gehrhus and M. F. Lappert, J. Organomet. Chem., 2001, 617, 209.
4. M. Haaf, T. A. Schmedake and R. West, Acc. Chem. Res., 2000, 33, 704.
5. N. J. Hill and R. West, J. Organomet. Chem., 2004, 689, 4165.
6. B. Gehrhus, P. B. Hitchcock, M. F. Lappert and J. C. Slootweg, Chem. Commun., 2000, 1427.
7. X. Cai, B. Gehrhus, P. B. Hitchcock, M. F. Lappert and J. C. Slootweg, J. Organomet. Chem., 2002, 651, 150.
8. F. Antolini, B. Gehrhus, P. B. Hitchcock, M. F. Lappert and J. C. Slootweg, Dalton Trans., 2004, 3288.
9. For reviews on structurally characterised lithium amides see: K. Gregory, P. v. R. Schleyer and R. Snaith, Adv. Inorg. Chem., 1991, 37, 47;
10. R. E. Mulvey, Chem. Soc. Rev., 1991, 20, 167.
11. K. Tamao, A. Kawachi and Y. Ito, J. Am. Chem. Soc., 1992, 114, 3989.
12. A. Kawachi and K. Tamao, Bull. Chem. Soc. Jpn., 1997, 70, 945.
13. K. Tamao, A. Kawachi, Y. Tanaka, H. Ohtani and Y. Ito, Tetrahedron, 1996, 52, 5765.
14. K. Tamao, A. Kawachi, M. Asahara and A. Toshimitsu, Pure Appl. Chem., 1999, 71, 393.
15. A. Kawachi and K. Tamao, J. Am. Chem. Soc., 2000, 122, 1919.
16. A. Kawachi, H. Maeda and K. Tamao, Organometallics, 2002, 21, 1319.
17. M. Kaftory, M. Kapon and M. Botoshansky, The Chemistry of Organosilicon Compounds, ed. R. Rappoport and Y. Apeloig, Wiley, Chichester, 1998.
18. C. Strohmann, O. Ulbrich and D. Auer, Eur. J. Inorg. Chem., 2001, 1013.
19. J. E. Huheey, E. A. Keiter and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, Harper-Collins College Publishers, New York, 1993.
20. B. Gehrhus, P. B. Hitchcock, M. F. Lappert, J. Heinicke, R. Boese and D. Bläser, J. Organomet. Chem., 1996, 521, 211.
21. G. M. Sheldrick, SHELXL 97, Program for Crystal Structure Refinement, University of Göttingen, Germany, 1997.