Bis(triazacyclohexane) sandwich complexes of (Cui)2, CuII and ZnII: Complexes with cuprophilic attraction between two cationic copper(I) leading to unusual reactivity with dioxygen

Dalton Transactions

Volumn , Issue 16, 2005, Pages 2793-2797

  Köhn, Randolf D ^a   Pan, Zhida ^a   Haufe, Matthias ^a   Kociok Köhn, Gabriele ^a  

^a University of Bath Claverton Down   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

AIR OXIDATION; METAL COMPLEXES; PROTONOLYSIS; SANDWICH COMPLEXES;

COPPER COMPOUNDS; OXIDATION; REACTION KINETICS; TRANSITION METALS;

COMPLEXATION;

CATION; COPPER; LIGAND; ORGANOMETALLIC COMPOUND; OXYGEN; ZINC;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

CATIONS; COPPER; CRYSTALLOGRAPHY, X-RAY; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXYGEN; STEREOISOMERISM; ZINC;

EID: 24144438183     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b501705j     Document Type: Article

References (19)

1. R. D. Köhn, G. Seifert, Z. Pan, M. F. Mahon and G. Kociok-Köhn, Angew. Chem., Int. Ed., 2003, 42, 793, and references therein.
2. R. D. Köhn, G. Seifert and G. Kociok-Köhn, Chem. Ber., 1996, 129, 1327;
3. R. D. Köhn, Z. Pan, M. F. Mahon and G. Kociok-Köhn, Chem. Commun., 2003, 1272.
4. J. Strähle and J. Beck, Angew. Chem., 1985, 97, 419;
5. J. Strähle and J. Beck, Angew. Chem., Int. Ed., 1985, 24, 409;
6. M. Munakata, M. Maekawa, S. Kitagawa, M. Adachi and H. Masuda, Inorg. Chim. Acta, 1990, 167, 181;
7. A. Al-Obaidi, G. Baranovic, J. Coyle, C. G. Coates, J. J. McGarvey, V. McKee and J. Nelson, Inorg. Chem., 1998, 37, 3567.
8. R. Fuchs and P. Klüfers, J. Organomet. Chem., 1992, 424, 353.
9. G. Kickelbick and T. Gallauner, Acta Crystallogr., Sect. E, 2002, 58, m102.
10. E. A. Lewis and W. B. Tolman, Chem. Rev., 2004, 104, 1047, and references therein.
11. e.g.: F. H. Fry, P. Jensen, C. M. Kepert and L. Spiccia, Inorg. Chem., 2003, 18, 5637, and references therein.
12. P. V. Bernhardt, J. M. Harrowfield, D. C. R. Hockless and A. M. Sargeson, Inorg. Chem., 1994, 33, 5659.
13. M. Haufe, R. D. Köhn, R. Weimann, G. Seifert and D. Zeigan, J. Organomet. Chem., 1996, 520, 121.
14. M. G. Davidson, P. R. Raithby, A. L. Johnson and P. D. Bolton, Eur. J. Inorg. Chem., 2003, 3445, and references therein.
15. R. D. Köhn, P. Kampe and G. Kociok-Köhn, Eur. J. Inorg. Chem., 2005, DOI: 10.1002/ejic.200500122.
16. L. Henry, Bull. Acad. Belg., 1895, 29, 23.
17. Stoe & Cie, (1997). IPDS-2.87, Darmstadt, Germany.
18. B. A. Frenz, Enraf-Nonius, SDP-Structure Determination Package 3.0, Enraf-Nonius, Delft, 1985.
19. L. J. Farrugia, J. Appl. Crystallogr., 1999, 32, 837-838.