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Volumn 7, Issue 16, 2005, Pages 3453-3455

Synthesis of vinylogous carbamates by rhodium(II)-catalyzed olefination of tertiary formamides with a silylated diazoester

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EID: 23944527322     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol0510872     Document Type: Article
Times cited : (17)

References (38)
  • 22
    • 0000801863 scopus 로고
    • Formamides were used as received from commercial sources or prepared by reaction of the corresponding secondary amines with ethyl formate; see: Moffat, J.; Newton, M. V.; Papenmeier, G. J. J. Org. Chem. 1962, 27, 4058.
    • (1962) J. Org. Chem. , vol.27 , pp. 4058
    • Moffat, J.1    Newton, M.V.2    Papenmeier, G.J.3
  • 23
    • 33645380208 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum of the crude reaction mixture.
  • 31
    • 0001291323 scopus 로고
    • It should be noted that in the absence of a nucleophilic substrate, "carbene dimerization" of silylated diazoesters is observed; see: Maas, G.; Gimmy, M.; Alt, M. Organometallics 1992, 11, 3813.
    • (1992) Organometallics , vol.11 , pp. 3813
    • Maas, G.1    Gimmy, M.2    Alt, M.3
  • 34
    • 0002043286 scopus 로고
    • For previously reported applications of α-alkoxy-β- aminoacrylates, see: (a) Schmidt, R. R.; Betz, R. Synthesis 1982, 748.
    • (1982) Synthesis , pp. 748
    • Schmidt, R.R.1    Betz, R.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.