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47
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33645443268
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note
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2: C 65.82, H 3.79; found: C 65.98, H 3.67; b) the experimental set-up for the photochemical measurements is described in ref. [4d, g].
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b) M. Frigoli, PhD thesis, Marseille, 2000.
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52
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33645423676
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note
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c) note: this is typical for 2H-chromenes and indicates, in principle, the presence of four photoproducts (CTC, TTC, TTT, and CTC). The isomers differ only in the configuration at the double bond attached to the naphthalene ring and at the position of the aryl group at the terminal double bond. The isomers CTC and TTC are thermoreversible whereas the other two are thermally stable and bleach on exposure to visible light. (TTT = trans,transoid, trans, CTT = cis,transoid,trans).
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53
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33645439497
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note
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Note: The thermal stability of CD-ON increased about 28 times relative to OD-ON. This result, together with monoexponential bleaching kinetics, might indicate that TT isomers, whose formation is selectively photoinduced by the extended π conjugation throughout the molecule, are formed preferentially.
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