Reactivity of the unsaturated triosmium cluster Os 3(CO) 8(μ 3-η 2-Ph 2PCH 2P(Ph)C 6H 4)(μ-H) with benzothiophene: Activation of a P-C bond in diphosphine and a C-H bond in benzothiophene

Organometallics

Volumn 24, Issue 13, 2005, Pages 3315-3320

  Kabir, Shariff E ^a   Miah, Md Arzu ^a   Sarker, Nitai C ^a   Hussain, G M Golzar ^b   Hardcastle, Kenneth I ^c   Nordlander, Ebbe ^d   Rosenberg, Edward ^e  

^a JAHANGIRNAGAR UNIVERSITY   (Bangladesh)

^b CARDIFF UNIVERSITY   (United Kingdom)

^c EMORY UNIVERSITY   (United States)

^d LUND UNIVERSITY   (Sweden)

^e UNIVERSITY OF MONTANA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BENZOTHIOPHENE; DIPHOSPHINE; REACTIVITY; THERMOLYSIS;

CHEMICAL ACTIVATION; CHEMICAL BONDS; COORDINATION REACTIONS; HYDROGENATION; MOLECULAR STRUCTURE; NITROGEN COMPOUNDS; OSMIUM COMPOUNDS; PHOSPHORUS COMPOUNDS; SULFUR; SYNTHESIS (CHEMICAL); TOLUENE; X RAY DIFFRACTION ANALYSIS;

REACTION KINETICS;

EID: 23144446370     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050110k     Document Type: Article

References (64)

1. (a) Reynolds, M. A.; Guzei, I. A.; Angelici, R. J. Inorg. Chem. 2003, 42, 2191.
2. (b) Reynolds, M. A.; Guzei, I. A.; Angelici, R. J. J. Chem. Soc., Chem. Commun. 2000, 513.
3. (c) Reynolds, M. A.; Guzei, I. A.; Angelici, R. J. Organometallics 2001, 20, 1071.
4. Chen, J.; Angelici, R. J. Organometallics 1999, 18, 5721.
5. (e) Prins, R.; De Beer, V. H. J.; Somorjai, G. A. Catal. Rev-Sci. Eng. 1989, 31, 1.
6. (f) Topsøe, H.; Clausen, B. S.; Massoth, F. E. In Hydrotreating Catalysis: Science and Technology; Anderson, J. R., Boudart, M., Ed.; Springer-Verlag: Berlin, 1996.
7. (g) Petroleum Chemistry and Refining; Speight, J. G., Ed.; Taylor and Francis: Washington, DC, 1998.
8. (h) Dullaghn, C. A.; Sun, S.; Welden, B.; Sweigart, D. A. Angew. Chem., Int. Ed. Engl. 1996, 35, 212.
9. Angelici, R. J. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed. ; Wiley: New York, 1994; Vol. 3, pp 1433-1443.
10. (a) Shih, S. S.; Mizahi, S.; Green, L. A.; Sarli, M. S. Ind. Eng. Chem. Res. 1992, 31, 1232.
11. (b) Topsøe, H.; Gates, B. C. Polyhedron 1997, 16, 3212.
12. (c) Gates, B. C.; Katzer, J. R.; Schuit, C. A. Chemistry of Catalytic Processes; MacGraw Hill: New York, 1979; pp 1433-1443.
13. (d) Galpern, G. D. In The Chemistry of Heterocyclic Compounds; Gronowitz, S., Ed.; John Wiley and Sons Inc.: New York, 1985; Vol. 44, Part 1, pp 325-351.
14. (e) Kilanowski, D. R.; Gates, B. C. J. Catal. 1980, 62, 70.
15. Bianchini, C.; Herrera, V.; Jimenez, M.; Meli, A.; Sanchez-Delgado, R. A.; Vizza, F. J. Am. Chem. Soc. 1995, 117, 8567.
16. (a) Sanchez-Delgado, R. A.; Gonzalez, E. Polyhedron 1989, 8, 1431.
17. (b) Sanchez-Delgado, R. A.; Herrera, V.; Rincon, L.; Andriollo, A.; Martin, G. Organometallics 1994, 13, 553.
18. Kaesz, H. D.; King, R. B.; Manuel, T. A.; Nichols, L. D.; Stone, F. G. A. J. Am. Chem. Soc. 1960, 82, 4749.
19. (a) King, R. B.; Stone, F. G. A. J. Am. Chem. Soc. 1960, 82, 4557.
20. (b) King, R. B.; Treichel, P. M.; Stone, F. G. A. J Am. Chem. Soc. 1961, 83, 3600.
21. (c) Vicic, D. A.; Jones, W. D. Organometallics 1999, 18, 134.
22. (d) Chehata, A.; Oviedo, A.; Arévalo, A.; Bernès, S.; García, J. J. Organometallics 2003, 22, 1585.
23. (e) Yu, K.; Li, H.; Watson, E. J.; Virkaitis, K. L.; Carpenter, G. B.; Sweigart, D. A. Organometallics 2001, 20, 3550.
24. (f) Sanchez-Delgado, R. A. Organometallic Modeling of the Hydrodesulfurization and Hydrodenitrogenation Reactions; Kluwer Academic: Dordrecht, The Netherlands, 2002.
25. (g) Angelici, R. J. Organometallics 2001, 20, 1259.
26. Ogilvy, A. E.; Draganjac, M.; Rauchfuss, T. B.; Wilson, F. R. Organometallics 1988, 7, 1171.
27. Brorson, M.; King, J. D.; Kiriakidou, K.; Prestopino, F.; Nordlander, E. In Metal Clusters in Chemistry; Braunstein, P., Oro, L. A., Raithby, P. R., Eds.; Wiley-VCH: Weinheim, 1999; Vol. 2, pp 741-781.
28. (a) Arce, A. J.; De Sanctis, Y.; Karam, A.; Deeming, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 1381.
29. (b) Arce, A. J.; Arrojo, P.; De Sanctis, Y.; Karam, A.; Deeming, A. J. J. Chem. Soc., Dalton Trans. 1992, 2423.
30. Arce, A. J.; Karam, A.; De Sanctis, Y.; Capparelli, M. V.; Deeming, A. J. Inorg. Chim. Acta 1999, 285, 277.
31. Adams, R. D.; Pompeo, M. P.; Wu, W.; Yamamoto, J. H. J. Am. Chem. Soc. 1993, 115, 8207.
32. Adams, R. D.; Qu, X. Organometallics 1995, 14, 2238.
33. Abedin, S. M. T.; Azam, K. A.; Hursthouse, M. B.; Kabir, S. E.; Malik, K. M. A.; Mottalib, M. A.; Rosenberg, E. J. Cluster Sci. 2001, 12, 5.
34. Kabir, S. E.; Malik, M. M. A.; Mollah, E.; Mottalib, M. A. J. Organomet. Chem. 2000, 616, 157.
35. Kabir, S. E.; Johns, C. A.; Malik, K. M. A.; Mottalib, M. A.; Rosenberg, E. J. Organomet. Chem. 2001, 625, 112.
36. Kabir, S. E.; Pervin, S.; Barker, N. C.; Yesmin, A.; Sharmin, A.; Siddiquee, T. A.; Haworth, D. T.; Bennett, D. W.; Malik, K. M. A. J. Organomet. Chem. 2003, 681, 237.
37. Abedin, S. M. T.; Hardcastle, K. I.; Kabir, S. E.; Malik, K. M. A.; Mottalib, M. A.; Rosenberg, E.; Abedin, M. J. Organometallics 2000, 19, 5623.
38. Deeming, A. J.; Hassan, Md. M.; Kabir, S. E.; Nordlander, E.; Tocher, D. A. Dalton Trans. 2004, 3079.
39. Kabir, S. E.; Karim, M. M.; Malik, K. M. A.; Siddiquee, T. A. Inorg. Chem. Commun. 1999, 2, 128.
40. (a) Bergounhou, C.; Bonnet, J.-J.; Fompeyrine, P.; Lavigne, G.; Lugan, N.; Mansilla. Organometallics 1986, 5, 60.
41. (b) Lavigne, G.; Bonnet, J.-J. Inorg. Chem. 1981, 20, 2713.
42. Lavigne, G. In The Chemistry of Metal Cluster Complexes; Shriver, D. F., Kaesz, H. D., Adams, R. D., Eds.; VCH: New York, 1990; p 210.
43. King, J. D.; Davies, J. E.; Johansson, M. H.; Johnson, B. F. G.; Nordlander, E. Unpublished results.
44. Goudsmit, R. J.; Johnson, B. F. G.; Lewis, J.; Raithby, P. R.; Rosales, M. J. J. Chem. Soc., Dalton Trans. 1983, 2257.
45. Chen, G.; Deng, M.; Lee, C. K.; Leong, W. K. Organometallics 2000, 21, 1227.
46. (a) Azam, K. A.; Hursthouse, M. B.; Islam, Md. R.; Kabir, S. E.; Malik, K. M. A.; Miah, R.; Sudbrake, C.; Vahrenkamp, H. J. Chem. Soc., Dalton Trans. 1998, 1097.
47. (b) Patel, V. D.; Cherkas, A. A.; Nucciarone, D.; Taylor, N. J.; Carty, A. J. Organometallics 1985, 4, 1792.
48. Mott, G. N.; Carty, A. J. Inorg. Chem. 1983, 22, 2786.
49. Lugan, N.; Bonnet, J. J.; Ibers, J. A. J. Am. Chem. Soc. 1985, 107, 4484.
50. Kabir, S. E.; Karim, M. M.; Malik, K. M. A.; Siddiquee, T. A. Inorg. Chem. Commun. 1999, 2, 128.
51. Beatty, S. T.; Bergman, B.; Rosenberg, E.; Dastru, W.; Gobetto, R.; Milone, L.; Viale, A. J. Organomet. Chem. 2000, 226, 593-594, and references therein.
52. Poe, A. J.; Sekhar, V. C. Inorg. Chem. 1985, 24, 4376.
53. Clucas, J. A.; Foster, D. F.; Harding, M. M.; Smith, A. K. J. Chem. Soc., Chem. Commun. 1984, 949.
54. Hooft, R. COLLECT Data Collection Software; Nonius B.V., Delft: The Netherlands, 1998.
55. Otwinowski, Z.; Minor, W. In Macromolecular Crystallography; Carter, C. W., Sweet, R. M., Jr., Eds.; Academic Press: New York, 1997; pp 307-326.
56. Blessing, R. H. Acta Crystallogr. A 1995, 51, 33.
57. Blessing, R. H. J. Appl. Crystallogr. 1997, 30, 421.
58. Sheldrick, G. M. Acta Crystallogr. A 1990, 46, 467.
59. Sheldrick, G. M. SHELXL-97 Program for Crystal Structure Refinement; University Göttingen: Germany, 1997.
60. SMART Version 5.628; Bruker AXS, Inc.: Madison, WI, 2003.
61. SAINT Version 6.36; Bruker AXS, Inc.: Madison, WI, 2002.
62. Sheldrick, G. SADABS Version 2.10; University of Göttingen, 2003.
63. SHELXTL V6.12; Bruker AXS, Inc.: Madison, WI, 2003.
64. Wilson, A. J. C., Ed. International Tables for X-ray Crystallography, Vol. C; Kynoch, Academic Publishers: Dordrecht, 1992; Tables 6.1.1.4 (pp 500-502) and 4.2.6.8 (pp 219-222).