Rovibrational transitions and nuclear spin conversion of methane in parahydrogen crystals

Low Temperature Physics

Volumn 26, Issue 9-10, 2000, Pages 661-668

  Miki, M ^a   Momose, T ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CRYSTAL STRUCTURE; CRYSTALS; DECAY (ORGANIC); LIGHT ABSORPTION; MOLECULES; SPECTRAL RESOLUTION;

HIGH SPECTRAL RESOLUTION; MAGNETIC FIELD GRADIENT; MATRIX ISOLATION SPECTROSCOPY; NUCLEAR-SPIN CONVERSION; PARAHYDROGEN CRYSTAL; ROTATIONAL RELAXATIONS; ROVIBRATIONAL TRANSITIONS; VIBRATION ROTATIONS;

SPIN DYNAMICS;

EID: 23044524718     PISSN: 1063777X     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1312392     Document Type: Article

References (53)

1. M. E. Jacox, J. Phys. Chem. Ref. Data 27, 115 (1998).
2. V. E. Bondybey and V. A. Apkarian, Chem. Phys. 189, 137 (1994).
3. G. N. Lewis, D. Lipkin, and T. T. Magel, J. Am. Ceram. Soc. 63, 3005 (1941).
4. E. Whittle, D. A. Dows, and G. C. Pimentel, J. Chem. Phys. 22, 1943 (1954).
5. M. Okumura, M.-C. Chan, and T. Oka, Phys. Rev. Lett. 62, 32 (1989).
6. T. Momose, D. P. Weliky, and T. Oka, J. Mol. Spectrosc. 153, 760 (1992).
7. T. Oka, Annu. Rev. Phys. Chem. 44, 299 (1993).
8. D. P. Weliky, K. E. Kerr, T. J. Byers, Y. Zhang, T. Momose, and T. Oka, J. Chem. Phys. 105, 4461 (1996).
9. Y. Zhang, T. J. Byers, M.-C. Chan, T. Momose, K. E. Kerr, D. P. Weliky, and T. Oka, Phys. Rev. B 68, 218 (1998).
10. M.-C. Chan, Ph.D. Thesis, The University of Chicago (1991).
11. T. Momose and T. Shida, Bull. Chem. Soc. Jpn. 71, 1 (1998).
12. M. E. Fajardo and S. Tam, J. Chem. Phys. 108, 4237 (1998).
13. S. Tam and M. E. Fajardo, Rev. Sci. Instrum. 70, 1926 (1999).
14. H. Katsuki and T. Momose, Phys. Rev. Lett. 84, 3286 (2000).
15. T. Momose, J. Chem. Phys. 107, 7695 (1997).
16. T. Momose, M. Miki, T. Wakabayashi, T. Shida, M.-C. Chan, S. S. Lee, and T. Oka, J. Chem. Phys. 107, 7707 (1997).
17. T. Momose, H. Katsuki, H. Hoshina, N. Sogoshi, T. Wakabayashi, and T. Shida, J. Chem. Phys. 107, 7717 (1997).
18. H. Hoshina, T. Wakabayashi, T. Momose, and T. Shida, J. Chem. Phys. 110, 5728 (1999).
19. S. Tam and M. E. Fajardo, H. Katsuki, H. Hoshina, T. Wakabayashi, and T. Memose, J. Chem. Phys. 111, 4191 (1999).
20. E. B. Wilson Jr., J. Chem. Phys. 3, 276 (1935).
21. A. W. Maue, Ann. Phys. (Leipzig) 20, 555 (1937).
22. M. Hepp, G. Winnewisser, and K. M. T. Yamada, J. Mol. Spectrosc. 164, 311 (1994).
23. R. F. Curl Jr., J. V. V. Kasper, and K. S. Pitzer, J. Chem. Phys. 46, 3220 (1966).
24. P.-N. Yi, I. Ozier, and C. H. Anderson, Phys. Rev. 165, 92 (1968).
25. I. Ozier, P.-N. Yi, A. Khosla, and N. F. Ramsay, Phys. Rev. Lett. 24, 642 (1970).
26. R. P. Wolf and W. M. Whitney, Low Temperature Physics, J. G. Daunt et al. (Eds.) (Plenum Press, Inc., New York, 1965).
27. H. P. Hopkins Jr., P. L. Donoho, and K. S. Pitzer, J. Chem. Phys. 47, 864 (1967).
28. K. P. Wong, J. D. Noble, M. Bloom, and S. Alexander, J. Magn. Reson. 1, 55 (1969).
29. P. van Hecke and L. van Gerven, Physica (Amsterdam) 68, 359 (1973).
30. G. J. Vogt and K. S. Pitzer, J. Chem. Thermodyn. 8, 1011 (1976).
31. J. E. Piott and W. D. McCormick, Can. J. Phys. 54, 1784 (1976);
32. J. E. Piott and W. D. McCormick, Can. J. Phys. ibid. 54, 1799 (1976).
33. K. J. Lushington and J. A. Morrison, Can. J. Phys. 55, 1580 (1977).
34. J. Higinbotham, B. M. Wood, and R. F. Code, Phys. Lett. A 66, 237 (1978).
35. S. Buchman, D. Candela, W. T. Vetterling, and R. V. Pound, Phys. Rev. B 26, 1459 (1982).
36. F. H. Frayer and G. E. Ewing, J. Chem. Phys. 46, 1994 (1967).
37. F. H. Frayer and G. E. Ewing, J. Chem. Phys. 48, 781 (1968).
38. G. Herzberg, Molecular Spectra and Molecular Structure, Vol. I, Spectra of Diatomic Molecules, Krieger Publishing Co., Malabar, Florida (1989).
39. 2 (Plenum Press, Inc., New York, 1983).
40. T. Miyazaki, K. Yamamoto, and J. Arai, Chem. Phys. Lett. 219, 405 (1994).
41. M. E. Fajardo, S. Tam, T. L. Thompson, and M. E. Cordonnier, Chem. Phys. 189, 351 (1994).
42. P. C. Souers, Hydrogen Properties for Fusion Energy, University of California Press, Berkeley (1986).
43. L. Pauling, Phys. Rev. 36, 430 (1930).
44. E. P. Wigner, Group Theory, Academic Press, New York (1959).
45. J. T. Hougen, International Review of Science Physical Chemistry, Vol. 3, Ser. 2, Spectroscopy, p. 75, D. A. Ramsay (Ed.), Butterworths, London (1976).
46. R. E. Miller and J. C. Decius, J. Chem. Phys. 59, 4871 (1973).
47. R. L. Redington and D. E. Milligan, J. Chem. Phys. 37, 2162 (1962).
48. R. L. Redington and D. E. Milligan, J. Chem. Phys. 39, 1276 (1963).
49. T. Momose and T. Oka (in preparation).
50. Since the interaction between orthohydrogen and methane is much stronger than that between parahydrogen and methane, molecular parameters of methane with orthohydrogen next to it could be different from those of methane surrounded by only parahydrogen molecules. Therefore, the equilibrium value c(∞) is not necessarily be equal to 0.89 for higher orthohydrogen concentration. The c(∞) values determined by the least-squares fitting were 0.85 (10%), 0.82 (20%), 0.81 (30%), and 0.80 (75%).
51. E. Wigner, Z. Phys. Chem. Abt. B 23, 28 (1933).
52. K. Motizuki and T. Nagamiya, J. Phys. Soc. Jpn. 11, 93 (1956).
53. A. J. Nijman and A. J. Berlinsky, Can. J. Phys. 58, 1049 (1980).