Effect of temperature on structure and performance of in-house cobalt-tungsten carbide catalyst for dry reforming of methane

Industrial and Engineering Chemistry Research

Volumn 44, Issue 14, 2005, Pages 4914-4921

  Shao, Huifang ^a   Kugler, Edwin L ^a   Ma, Wenping ^a   Dadyburjor, Dady B ^a  

^a West Virginia University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIMETALLIC CARBIDE CATALYSTS; DRY REFORMING; REACTANTS; SYNTHESIS GAS PRODUCTION;

CARBIDES; CARBON; COBALT; METHANE; REFORMING REACTIONS; SYNTHESIS GAS; THERMAL EFFECTS;

CATALYSTS;

TEMPERATURE EFFECT;

EID: 22944459560     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie049186r     Document Type: Article

References (24)

1. Ross, J. R. H.; van Keulen, A. N. J.; Hegarty, M. E. S.; Seshan, K. The Catalytic Conversion of Natural Gas to Useful Products. Catal. Today 1996, 30, 193.
2. 3 Catalysts: Effect of Ni Content. Bull. Korean Chem. Soc. 2002, 23 (8), 1166.
3. Wang S. B.; Lu, G. Q. Carbon Dioxide Reforming of Methane to Produce Synthesis Gas over Metal-Supported Catalysts: State of the Art. Energy Fuels 1996, 10, 896.
4. Liang, C.; Ma, W.; Feng, Z.; Li, C. Activated Carbon Supported Bimetallic CoMo Carbides Synthesized by Carbothermal Hydrogen Reduction. Carbon 2003, 41, 1833.
5. Claridge, J. B.; York, A. P. E.; Brungs, A. J.; Marquez-Alvarez, C.; Sloan, J.; Tsang S. C.; Green, M. L. H. New Catalysts for the Conversion of Methane to Synthesis Gas: Molybdenum and Tungsten Carbide. J. Catal. 1998, 180, 85.
6. Chen, Y.-G.; Tomishige, K.; Yokoyama, K.; Fujimoto, K. Catalytic Performance and Catalyst Structure of Nickel-Magnesia Catalysts for CO2 Reforming of Methane. J. Catal. 1999, 184, 479.
7. Zhang, Z. L.; Tsipouriari, V. A.; Efstanthion, A. M.; Verykios, X. E. Reforming of Methane with Carbon Dioxide to Synthesis Gas over Supported Rhodium Catalysts I: Effects of Support and Metal Crystallite Size on Reaction Activity and Deactivation Characteristics. J. Catal. 1996, 158, 51.
8. 4 Catal. Rev.-Sci. Eng. 1999, 41 (1), 1.
9. 3-Supported Ni Catalysts. Catal. Lett. 2003, 89 (1-2), 121.
10. 4 over Supported Pt Catalysts. J. Catal. 1998, 173, 157.
11. Lercher, J. A; Bitter, J. H.; Hally, W.; Niessen, W.; Seshan, K. Design of Stable Catalysts for Methane-Carbon Dioxide Reforming. Stud. Surf. Sci. Catal. 1996, 101, 463.
12. Bradford, M. C. J.; Vannice, M. A. Catalytic Reforming of Methane with Carbon Dioxide over Nickel Catalysts I. Catalyst Characterization and Activity. Appl. Catal., A 1996, 142, 73.
13. 3 Catalysts. J. Catal. 2001, 204, 89.
14. 2-Reforming of Methane over Transition Metals. J. Catal. 1993, 144, 38.
15. Rostrup-Nielsen, J. R. Sulfur-Passivated Nickel Catalysts for Carbon-Free Steam Reforming. J. Catal. 1984, 85, 31.
16. Babilius, A. Influence of Temperature on the Phases Changes of HVOF Sprayed Tungsten Carbide Coatings. Mater. Sci. 2003, 9 (3), 183.
17. Lee, J. S.; Oyama, S. T.; Boudart, M. Molybdenum Carbide Catalysts I. Synthesis of Unsupported Powders. J Catal. 1987, 106, 125.
18. 2 Mixtures Leading to Bulk Tungsten Carbide Powder Catalysts. J. Catal. 2000, 189, 170.
19. Shamsi, A.; Lyons, D. Methane Dry Reforming over Carbide, Ni-based and Noble Metal Catalysts. Prepr. -Am. Chem. Soc., Div. Pet. Chem. 2000, 45 (1), 132.
20. Iyer, M. V.; Norcio, L. P.; Punnoose, A.; Kugler, E. L.; Seehra, M. S.; Dadyburjor, D. B. Catalysis for Synthesis Gas Formation from Reforming of Methane. Top. Catal. 2004, 29 (3-4), 197.
21. Iyer, M. V.; Norcio, L. P.; Kugler, E. L.; Dadyburjor, D. B. Kinetic Modeling for Methane Reforming with Carbon Dioxide over a Mixed-Metal Carbide Catalyst. Ind. Eng. Chem. Res. 2003, 42 (12), 2712.
22. Kugler, E. L.; McCandlish, L. E.; Jacobson, A. J.; Chianelli, R. R. Eta Phase Materials, Methods of Producing the Same, and Use Thereof as Catalysts for Alcohol Synthesis, Hydrocarbon Synthesis, Hydrocarbon Hydrogenation and Hydrocarbon conversion Reactions. U.S. Patent 5,138,111, Aug 11, 1992.
23. Polizzotti, R. S.; McCandlish, L. E.; Kugler, E. L. Multiphase Composite Particle Containing a Distribution of Nonmetallic Compound Particles. U.S. Patent 5,338,330, Aug 16, 1994.
24. Shao, H.; Kugler, E. L.; Dadyburjor, D. B. Catalysts for Hydrogen Production from Methane. Prepr.-Am. Chem. Soc., Div. Fuel Chem. 2004, 49 (2), 702.