Kinetic modeling for methane reforming with carbon dioxide over a mixed-metal carbide catalyst

Industrial and Engineering Chemistry Research

Volumn 42, Issue 12, 2003, Pages 2712-2721

  Iyer, Mahesh V ^a,b   Norcio, Lawrence P ^a   Kugler, Edwin L ^a   Dadyburjor, Dady B ^a  

^a West Virginia University   (United States)

^b The Ohio State University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CARBIDES; CARBON DIOXIDE; CATALYSTS; DEPOSITION; METHANE; REACTION KINETICS; SYNTHESIS GAS;

KINETIC MODELS;

REFORMING REACTIONS;

CARBON; CARBON DIOXIDE; COBALT; METAL DERIVATIVE; METHANE; TUNGSTEN;

KINETIC THEORY;

ARTICLE; CATALYST; CHEMICAL REACTION KINETICS; GAS; MODEL; QUANTITATIVE ANALYSIS; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE;

EID: 0037872048     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020677q     Document Type: Article

References (46)

1. Otsuka, K.; Ushiyama, T.; Yamanaka, I. Partial Oxidation of Methane by Redox Reaction with Cerium Oxide. Chem. Lett. 1993, 9, 1517.
2. 2. Stud. Surf. Sci. Catal. 1994, 81, 285.
3. Ross, J. R. H.; van Keulen, A. N. J.; Hegarty, M. E. S.; Seshan, K. The Catalytic Conversion of Natural Gas to Useful Products. Catal. Today 1996, 30, 193.
4. Wang, S.; Lu, G. Q.; Millar, G. J. Carbon Dioxide Reforming of Methane to Produce Synthesis Gas over Metal-Supported Catalysts: State of the Art. Energy Fuels 1996, 10, 896.
5. Claridge, J. B.; York, A. P. E.; Brungs, A. J.; Marquez-Alvarez, C.; Sloan, J.; Tsang, S. C.; Green, M. L. H. New Catalysts for the Conversion of Methane to Synthesis Gas: Molybdenum and Tungsten Carbide. J. Catal. 1998, 180, 85.
6. 2-Reforming of Methane over Transition Metals J. Catal. 1993, 144, 38.
7. 4, Catal. Rev. Sci. Eng. 1999, 41 (1), 1.
8. Rostrup-Neilsen, J. R. Syngas in Perspective. Catal. Today 2002, 71, 243.
9. York, A. P. E. Magic Catalysts. Chem. Br. 1999, 35 (8), 25.
10. Brungs, A. J.; York, A. P. E.; Green, M. L. H. Comparison of the Group V and VI Transition Metal Carbides for Methane Dry Reforming and Thermodynamic Prediction of their Relative Stabilities. Catal. Lett. 1999, 57, 65.
11. Brungs, A. J.; York, A. P. E.; Claridge, J. B.; Marquez- Alvarez, C.; Green, M. L. H. Dry Reforming of Methane to Synthesis Gas over Supported Molybdenum Carbide Catalysts. Catal. Lett. 2000, 70, 117.
12. 2. Chem. Lett. 2000, 9, 1086.
13. Shamsi, A.; Lyons, D. Methane Dry Reforming over Carbide, Ni-Based, and Noble Metal Catalysts. Prepr. - Am. Chem. Soc., Div. Pet. Chem. 2000, 45 (1), 132.
14. Iyer, M. V.; Norcio, L. P.; Punnoose, A.; Kugler, E. L.; Seehra, M. S.; Dadyburjor, D. B. Catalysis for Synthesis Gas Formation from Reforming of Methane. Top. Catal. 2003, submitted for publication.
15. Sakai, Y.; Saito, H.; Sodesawa, T.; Nozaki, F. Catalytic Reactions of Hydrocarbon with Carbon Dioxide over Metallic Catalysts. React. Kinet. Catal. Lett. 1984, 24, 253.
16. Tokunaga, O.; Ogasawara, S. Reduction of Carbon Dioxide with Methane over Ni-Catalyst. React. Kinet. Catal. Lett. 1989, 39 (1), 69.
17. Richardson, J. T.; Paripatyadar, S. A. Carbon Dioxide Reforming of Methane with Supported Rhodium. Appl. Catal. 1990, 61 (2), 293.
18. Erdohelyi, A.; Cserenyi, J.; Papp, E.; Solymosi, F. Catalytic Reaction of Methane with Carbon Dioxide over Supported Palladium. Appl. Catal. A 1994, 108 (2), 205.
19. Takano, A.; Tagawa, T.; Goto, S. Carbon Dioxide Reforming of Methane on Supported Nickel Catalysts. J. Chem Eng. Jpn. 1994, 27 (6), 727.
20. Bodrov, I. M.; Apel'baum, L. O. Reaction Kinetics of Methane and Carbon Dioxide on a Nickel Surface. Kinet. Catal. 1967, 8 (2), 379.
21. 2 over supported Rh Catalysts. J. Catal. 1993, 141, 287.
22. 2 over Rh Catalysts. Catal. Lett. 1994, 25, 265.
23. 2 Reforming of Methane on Metal Sulfide Catalysts. Catal. Lett. 1995, 35, 39.
24. Efstathiou, A. M.; Kladi, A.; Tsipouriari, V. A.; Verykios, X. E. Reforming of Methane with Carbon Dioxide to Synthesis Gas over Supported Rhodium Catalysts. J. Catal. 1996, 158, 64.
25. 2-Reforming of Methane on Supported Rh and Ir Catalysts. J. Catal. 1996, 164, 122.
26. 2 Catalyst. II. A Mechanistic Study. J. Catal. 1997, 164, 387.
27. 4 over supported Pt Catalysts. J. Catal. 1998, 173, 157.
28. Bradford, M. C. J.; Vannice, M. A. Catalytic Reforming of Methane with Carbon Dioxide over Nickel Catalysts. II. Reaction Kinetics. Appl. Catal. A 1996, 142, 97.
29. 2-Reforming of Methane over Supported Ni Catalyst. J. Catal. 1998, 180, 106.
30. Ferreira-Aparicio, P.; Marquez-Alvarez, C.; Rodriguez-Ramos, I.; Schuurman, Y.; Guerrero-Ruiz, A.; Mirodatos, C. A Transient Kinetic Study of the Carbon Dioxide Reforming of Methane over Supported Ru Catalysts. J. Catal. 1999, 184, 202.
31. Lu, G. Q.; Wang, S. Ni-based Catalysts for Carbon Dioxide Reforming of Methane. CHEMTECH 1999, 29 (1), 37.
32. 3/5A: An Investigation on Carbon Deposition and Reaction Steps. J. Catal. 2000, 194, 198.
33. 2 Reforming of Methane. Chem. Eng. Technol. 1997, 20, 361.
34. Lewis, W. K.; Gilliland, E. R.; Reed, W. A. Reaction of Methane with Copper Oxide in a Fluidized Bed. Ind. Eng. Chem. 1949, 41, 1227.
35. Zhang, Z.; Verykios, X. E. Mechanistic Aspects of Carbon Dioxide Reforming of Methane to Synthesis Gas over Ni Catalysts. Catal. Today 1994, 21, 589.
36. 3 Catalyst. Ind. Eng. Chem. Res. 1997, 36, 5180.
37. Osaki, T.; Horiuchi, T.; Suzuki, K.; Mori, T. Appl. Catal. A 1997, 155, 229.
38. 2 Catalysts Based on a Stepwise Mechanistic Model. Stud. Surf. Sci. Catal. 1998, 119, 753.
39. 2 Reforming of Methane. React, Eng. Pollut. Prev. 2000, 75.
40. Iyer, M. V. New Catalysts for Syngas Production from Carbon Dioxide and Methane. M.S.Ch.E. Thesis, West Virginia University, Morgantown, WV, 2001.
41. Liu, Z.; Li, X.; Close, M. R.; Kugler, E. L.; Peterson, J. L.; Dadyburjor, D. B. Screening of Alkali-Promoted Vapor-Phase-Synthesized Molybdenum Sulfide Catalysts for the Production of Alcohols from Synthesis Gas. Ind. Eng. Chem. Res. 1997, 36 (8), 3085.
42. 4 over Supported Molybdenum Carbide Catalysts. Catal. Lett. 2000, 69, 195.
43. Wang, S.; Lu, G. Q. Effects of Acidic Treatments on the Pore and Surface Properties of Ni Catalyst Supported on Activated Carbon. Carbon 1998, 35, 283.
44. Sandler, S. I. Chemical Engineering Thermodynamics, 2nd ed.; John Wiley & Sons: New York, 1989.
45. Vannice, M. A.; Hyun, S. H.; Kalpakci, B.; Liauh, W. C. Entropies of Adsorption in Heterogeneous Catalytic Reactions. J. Catal. 1979, 56, 358.
46. Lee, H. H. Heterogeneous Reactor Design; Butterworth Publishers: Stoneham, MA, 1985.