Deep desulfurization of gasoline by selective adsorption over nickel-based adsorbent for fuel cell applications

Industrial and Engineering Chemistry Research

Volumn 44, Issue 15, 2005, Pages 5768-5775

  Ma, Xiaoliang ^a   Sprague, Michael ^a   Song, Chunshan ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT PRESSURE; BENZOTHIOPHENE; ETHYLBENZEN; GASOLINE FUELS;

BENZENE; DESULFURIZATION; GASOLINE; NICKEL COMPOUNDS; OLEFINS; SULFUR COMPOUNDS;

FUEL CELLS;

ADSORPTION; DESULFURIZATION; GAS SEPARATION;

EID: 22944438051     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0492810     Document Type: Article

References (39)

1. Song, C. S. An Overview of New Approaches to Deep Desulfurization for Ultra-Clean Gasoline, Diesel Fuel and Jet Fuel. Catal. Today 2003, 86, 211-263.
2. Babich, J. A.; Moulijn, J. A. Science and Technology of Novel Processes for Deep desulfurization of Oil Refinery Streams: A Review. Fuel 2003, 82, 607-631.
3. Song, C. S.; Ma, X. New Design Approaches to Ultra-clean Diesel Fuels by Deep Desulfurization and Deep Dearomatization. Appl. Catal. B 2003, 41, 207-238.
4. Song, C. S. Fuel Processing for Low-temperature and High-temperature Fuel Cells-Challenges, and Opportunities for Sustainable Development in the 21st Century. Catal. Today 2002, 77, 17-50.
5. 3 Catalysts During Steam Reforming of Jet Fuels. Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2003, 48 (2), 750-753.
6. Novochinskii, I. I.; Song, C. S.; Ma, X.; Liu, X. S.; Shore, L.; Lampert, J.; Farrauto, R. J. Low-temperature H2S Removal from Steam-containing Gas Mixtures with ZnO for Fuel Cell Application. 1. ZnO Particles and Extrudates. Energy Fuels 2004, 18, 576-583.
7. Gislason, J. Phillips sulfur-removal process nears commercialization. Oil Gas J. 2002, 99, 74. http://www.fuelstechnology.com/szorbgasoline.htm.
8. Turk, B. S.; Gupta, R. P. RTI's TReND Process for Deep Desulfurization of Naphtha. Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2001, 46 (2), 392-393.
9. Tawara, K.; Nishimura, T.; Hikoichi, I.; Nishimoto, T.; Hasuike, T. New Hydrodesulfurization Catalyst for PetroleumFed Fuel Cell Vehicles and Cogenerations. Ind. Eng. Chem. Res. 2001, 40, 2367-2370.
10. Yang, R. T.; Hernandez-Maldonado, A. J.; Yang, F. H. Desulfurization of Transportation /fuels with Zeolites Under Ambient Conditions. Science 301, 79-81.
11. Hernandez-Maldonado, A. J.; Yang, R. T. Desulfurization of Commercial Liquid Fuels by Selective Adsorption via π-Complexation with Cu(I)-Y Zeolite. Ind. Eng. Chem. Res. 2003, 42, 3103-3110.
12. Hernandez-Maldonado, A. J.; Stamatis, S. D.; Yang, R. T.; He, A. Z.; Cannella, W. New Sorbents for Desulfurization of Diesel Fuels via π-Complexation: Layered Beds and Regeneration. Ind. Eng. Chem. Res. 2004, 43, 769-776.
13. Ma, X.; Sun, L.; Song, C. A New Approach to Deep Desulfurization of Gasoline, diesel fuel and Jet Fuel by Selective Adsorption for Ultra-Clean Fuels and Fuel Cell Applications. Catal. Today 2002, 77, 107-116.
14. Ma, X.; Sprague, M.; Sun, L.; Song, C. Deep Desulfurization of Gasoline by SARS Process Using Adsorbent for Fuel Cells. Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2002, 47, 452-453;
15. World Patent WO03068892A2, 2003.
16. Ma, X.; Velu, S.; Sun, L.; Song, C.; Mehdi, N.; Siva, S. Adsorptive Desulfurization of JP-8 Jet Fuel and Its Light Fraction over Nickel-Based Adsorbents for Fuel Cell Applications. Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2003, 48 (2), 688-689.
17. Ma, X.; Sun, L.; Song, C. Adsorptive Desulfurization of Diesel Fuel over a Metal Sulfide-based Adsorbent. Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2003, 48 (2), 522-523.
18. Velu, S.; Ma, X.; Song, C. Selective Adsorption for Removing Sulfur from Jet Fuel over Zeolite-Based Adsorbents. Ind. Eng. Chem. Res. 2003, 42, 5293-5304.
19. Velu, S.; Watanabe, S.; Ma, X.; Sun, L.; Song, C. Development of Selective Adsorbents for Removing Sulfur from Gasoline for Fuel Cell Applications. Prepr.-Am. Chem. Soc., Div. Pet. Cheml. 2003, 48 (1), 56-57.
20. Velu, S.; Ma, X.; Song, C. Mechanistic Investigations on the Adsorption of organic sulfur Compounds over Solid Adsorbents in the Adsorptive Desulfurization of Transportation Fuels. Prepr. Symp.-Am. Chem. Soc., Div. Fuel Chem. 2003, 48 (2), 693-694.
21. Bougault, J.; Cattelain, E.; Chabrier, P. New Method for Obtaining Benzene and Toluene Free of Thiophene and Methylthiophene. Bull. Soc. Chim. Fr. 1940, 7, 781-781.
22. Bonner, W. A.; Grimm, P. A. In The Chemistry of Organic Sulfur Compounds; Kharasch, N.; Neyers, G. Y., Eds.; Pergamon Press: New York, 1966; p 35.
23. Meyers, A. I. Heterocycles in Organic Synthesis; Wiley-Interscience: New York, 1974; pp 15, 228, 243, and 266.
24. Sammes, P. G., Ed. Comprehensive Organic Chemistry, Vol. 4, Heterocyclic Compounds; Pergamon Press: Oxford, U.K., 1985.
25. Startsev, A. The Mechanism of HDS Catalysis. Catal. Rev.-Sci. Eng. 1995, 37, 352-423.
26. Bailey, G. W.; Swan, G. A. U.S. Patent 4,634,515, 1987.
27. Bonvillr, L. J.; DeGeorge, C. L.; Foley, P. F.; Garow, J.; Lesieur, R. R.; Perston, J. L.; Szydlowski, D. F. U.S. Patent 6,156,084, 2000.
28. Bonvillr, L. J.; DeGeorge, C. L.; Foley, P. F.; Garow, J.; Lesieur, R. R.; Perston, J. L.; Szydlowski, D. F. U.S. Patent 6,159,256, 2000.
29. Lesieur, R. R.; Teeling, C.; Sangiovanni, J. J.; Boedeker, L. R.; Dardas, Z. A.; Huang, H.; Sun, J.; Tang, X.; Spadaccini, L. J. U.S. Patent, 6,454,935, 2002.
30. Lesieur, R. R.; Cocolicchio, B. A.; Vincitore, A. M. U.S. Patent, 6,726,836, 2004.
31. Fukunaga, T.; Katsuno, H.; Matsumoto, H.; Takahashi, O.; Akai, Y. Development of Kerosene Fuel Processing System for PEFC Catal. Today 2003, 84, 197-200.
32. Stewart, J. J. P. Optimization of Parameters for Semiempirical Methods. 1. Methodology. J. Comput. Chem. 1989, 10, 209-220.
33. Stewart, J. J. P. Optimization of Parameters for Semiempirical Methods. 2. Applications. J. Comput. Chem. 1989, 10, 221-264.
34. Ma, X.; Sakanishi, K.; Isoda, T.; Mochida, I. Quantum Chemical Calculation on the Desulfurization Reactivities of Heterocyclic Sulfur Compounds. Energy Fuels 1995, 9, 33-37.
35. Ma, X.; Schobert, H. H. Estimating Heats of Formation of Hydrocarbon Radicals by a Combination of Semiempirical Calculation and Family Correlation with Experimental Values. J. Phys. Chem. 2000, 104, 1064-1074.
36. Ma, X.; Kim, J. H.; Song, C. Nonlinear Response and Quenching Effect in GC-FPD and GC-PFPD for Quantitative Sulfur Analysis of Low-Sulfur Hydrocarbon- Fuels. Prepr.-Am. Chem. Soc., Div. Pet. Chem. 2004, 49 (1), 9-12.
37. Ma, X.; Velu, S.; Kim, J. H.; Song, C. Deep Desulfurization of Gasoline by Selective Adsorption over Solid Adsorbents and Impact of Analytical Methods on ppm-Level Sulfur Quantification for Fuel Cell Applications. Appl. Catal. B 2005, 56 (1-2), 137-147.
38. Bartholomew, C. H.; Agrawal, P. K.; Katzer, J. R. Sulfur Poisoning of Metals. Adv. Catal. 1982, 31, 135-242.
39. Perdereau, M.; Oudar, J. Surf. Sci. 1970, 20, 80.