The solubility of phenanthrene in toluene: Insitu ATR-FTIR, experimental measurement, and thermodynamic modelling

Canadian Journal of Chemical Engineering

Volumn 83, Issue 2, 2005, Pages 267-273

  Bakhbakhi, Yousef ^a   Charpentier, Paul ^a   Rohani, Sohrab ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

Author keywords

Concentration; Crystallization; FTIR spectroscopy; Solubility prediction; Thermodynamic modelling

Indexed keywords

CRYSTALLIZATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GRAVIMETRIC ANALYSIS; ORGANIC SOLVENTS; SOLUBILITY; SUPERCRITICAL FLUIDS;

CRYSTALLIZATION PROCESS; FLORY-HUGGINS CORRECTION; PHENANTHRENE; REGULAR SOLUTION THEORY;

TOLUENE;

SOLUBILITY;

EID: 22144468020     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.5450830212     Document Type: Article

References (23)

1. Burshtein, A.I. and S.I.Temkin, (1994). "Spectroscopy of Molecular Rotation in Gases and Liquids". Cambridge Press.
2. Borissova, A., Dashova Z., Lai X., Roberts K.J. (2004). Examination of the Semi-Batch Crystallization of Benzophenone from Saturated Methanol Solution via Aqueous Antisolvent Drowning-Out as Monitored In-Process Using ATR FTIR Spectroscopy. J. of Crystal Growth & Design, 4,5, 1053-1060.
3. Dixon, D.J., Johnston, K.P. (1991). Molecular Thermodynamics of Solubilities in Gas Antisolvent Crystallization. AIChE J., 37 1441-1449.
4. Dunuwila, D.D., Caroll and L.B., Berglund, K.A. (1994). An Investigation of The Applicability of Attenuated Total Reflection Infrared Spectroscopy for Measurement of Solubility and Supersaturation of Aqueous Citric Acid Solutions. J. of Crystal Growth, 137, 561-568.
5. Dunuwila, D., Berglund, K.A. (1997). ATR FTIR Spectroscopy for in situ measurement of supersaturation. J. of Crystal Growth, 179, 185-193.
6. Feng, L., Berglund, K. A. (2002). ATR FTIR for determination optimal cooling curves for batch crystallization of succinic acid. J. of Crystal Growth& Design, 2, 5, 449-452.
7. Groen, H., Roberts, K.J. (2001). Nucleation, growth and pseudo-polymorphic behavior of citric acid as monitored in situ by attenuated total reflection Fourier transform infrared Spectroscopy. J. Phys. Chem. B, 105, 43, 10723-10730
8. Groen, H., Borissova, A., Roberts, K.J. (2003). In-Process ATR-FTIR Spectroscopy for Closed-Loop Supersaturation Control of a Batch Crystallizer Producing Monosodium Glutamate Crystals of Defined Size. Ind. Eng. Chem. Res., 42, 198-206.
9. Groen, H., Mougin P., Thomas A., White G., Wilkinson D. (2003). Dynamic In-Process Examination of Particle Size and Crystallographic Form under Defined Conditions of Reactant Supersaturation as Associated with the Batch Crystallization of Monosodium Glutamate from Aqueous Solution. Ind. Eng. Chem. Res., 42, 4888-4898.
10. Groen, H., Roberts, K.J. (2004). An Examination of the Crystallization of Urea from Supersaturated Aqueous and Aqueous-Methanol Solutions as Monitored In-Process Using ATR FTIR Spectroscopy. J. of Crystal Growth& Design, 4,5, 929-936.
11. Harrick, N. J. (1967). Internal reflection Spectroscopy. John Wiley & Sons, Inc.
12. Harris A., Daniel C. (1999). Quantitative Chemical Analysis. NH Freeman, New York, 5th edition.
13. Hildebrand, J.H., Prausnitz, J.M., Scott, R.L. (1970). Regular and Related solutions, Van Nostrand Reinhold, New York.
14. Lewiner F., Fevotte G., Klein, J.P., Puel F. (2001). On line ATR FTIR measurement of supersaturation during solution crystallization process. Calibration and applications on three solute/solvent systems. Chem. Eng. Sci., 56, 2069-2084.
15. Lewiner, F., F' evotte, G., Klein, J. P, Puel, F. (2001). Improving Batch Cooling Seeded Crystallization of an Organic Weed-Killer Using On-Line ATR FTIR Measurement of Supersaturation. J. of Crystal Growth, 226, 348-362.
16. Prausnitz, J. M., Edmister, W.C., Chao, K.C. (1960). Hydrocarbon Vapor-Liquid Equilibria and solubility Parameter. AIChE J., 6, 214-219.
17. Prausnitz, J. M., Lichtenthaler, R. N., Gomes de Azevedo, E. (1999). Molecular Thermodynamics of Fluid-Phase Equilibria. Prentice Hall, Inc.
18. Rouessac F., Rouessac A. (2000). Chemical Analysis: Modern Instrumental Methods and Techniques. Wiley, New York, 1st edition.
19. Smith, B.C. (1996). Fundamentals of Fourier Transform Infrared Spectroscopy. CRC press.
20. Stephen, H., Stephen, (1963). Solubilities of Inorganic and Organic Compounds: Binary Systems. Pergamon Press, New York.
21. Stuart, B. (1996). Modern Infrared Spectroscopy. John Wiley & Sons, Inc.
22. Togkalidou, T., Fujiwara, M., Patel, S., Braatz, R. D. A. (2001). Solute concentration prediction using chemometrics and ATR-FTIR Spectroscopy. J. of Crystal Growth, 231, 534-543.
23. Yaws C. L. (1999). Chemical properties handbook: physical, thermodynamic, environmental, transport, safety, and health related properties for organic and inorganic chemicals. McGraw-Hill, New York.