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4+-mont and HT catalysts showed higher activities than those of other solid acid (see ref 4b) and base catalysts (see Supporting Information), such as zeolites and MgO.
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27
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22144461156
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4+-mont.
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22144480412
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a values (∼31) did not occur under the present conditions.
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31
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22144431674
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note
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The estimated turnover numbers of acid and base sites were calculated to be 25 and 7, respectively; see Supporting Information.
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In the reaction of methyl cyanoacetate with 1, the yields of the first, second, and fifth runs were 95, 95, and 90%. respectively.
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in press
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The Pd/HT has both surface basicity and hydrogenation ability. For details of the bifunctional catalysis of the Pd/HT, see: Motokura, K.; Fujita, N.; Mori, K.; Mizugaki, T.; Ebitani, K.; Kaneda, K. Tetrahedron Lett., in press.
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