APSe6 (A = K, Rb, and Cs): Polymeric Selenophosphates with Reversible Phase-Change Properties

Inorganic Chemistry

Volumn 43, Issue 9, 2004, Pages 2762-2764

  Chung, In ^a   Do, Junghwan ^a   Canlas, Christian G ^a   Weliky, David P ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CESIUM; POLYMER; POTASSIUM; RUBIDIUM; SELENIUM DERIVATIVE; SELENOPHOSPHATE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; PHASE TRANSITION; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 2142767362     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic035448q     Document Type: Article

References (29)

1. Kanatzidis, M. G. Curr. Opin. Solid State Mater. Sci. 1997, 2, 139.
2. (a) Mercier, R.; Malugani, J.-P.; Fahys, B.; Robert, G. Acta Crystallogr., Sect. B 1982, 38, 1887.
3. (b) Schäfer, H.; Schäfer, G.; Weiss, A. Z. Naturforsch., B: Anorg. Chem. Org. Chem. 1965, 20, 811.
4. (c) Jansen, M.; Henseler, U. J. Solid State Chem. 1992, 99, 110.
5. Dickerson, C. A.; Fisher, M. J.; Sykora, R. E.; Albrecht-Schmitt, T. E.; Cody, J. A. Inorg. Chem. 2002, 41, 640.
6. Brockner, W.; Becker, R.; Eisenmann, B.; Schäfer, H. Z. Anorg. Allg. Chem. 1985, 520, 51.
7. Mercier, R.; Malugani, J.-P.; Fahys, B.; Douglade, J.; Robert, G. J. Solid State. Chem. 1982, 43, 151.
8. Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1995, 34, 5401.
9. Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1998, 37, 2582.
10. Aitken, J. A.; Canlas, C.; Weliky, D. P.; Kanatzidis, M. G. Inorg. Chem. 2001, 40, 6496.
11. Canlas, C. G.; Kanatzidis, M. G.; Weliky, D. P. Inorg. Chem. 2003, 42, 3399.
12. 2O but relatively stable under acetonitrile.
13. 2 = 4.99% for 1 > 2σ(I). An empirical absorption correction was done using SADABS, and all atoms were refined anisotropically. Structure solution and refinement were performed with SHELXTL.
14. Hordvik, A. Acta Chem. Scand. 1966, 20, 1885.
15. Brese, N. E.; Randall, C. R.; Ibers, J. A. Inorg. Chem. 1988, 27, 940.
16. Bond, A. J. Phys. Chem. 1964, 68, 441.
17. (a) Electronic Properties of Inorganic Quasi-One-Dimensional Compounds, Part II: Monceau, P., Ed.; D. Reidel Publishing Company: Dordrecht, 1985.
18. (b) Canadell, E.; Rachidi, E.-I.; Pouget, J. P.; Gressier, P.; Meerschaut, A.; Rouxel, J.; Jung, D.; Evain, M.; Whangbo, M.-H. Inorg. Chem. 1990, 29, 1401.
19. Mueller, V.; Frenzen, G.; Dehnicke, K.; Fenske, D. Z. Naturforsch., B: Chem. Sci. 1992, 47, 205.
20. 33) = (0.0559, 0.0489, 0.0211). Cs(2), however, still exhibited disorder near its refined position leading to relatively high standard deviation of bond lengths between Cs(2) and P and Se atoms. An empirical absorption correction was done using SADABS, and all atoms were refined anisotropically.
21. Chondroudis, K.; Kanatzidis, M. G. Angew. Chem., Int. Ed. Engl. 1997, 36, 1324.
22. 10.
23. 6.
24. The powder X-ray diffraction (XRD) patterns after each DTA cycle showed that amorphous glasses had formed.
25. Dhingra, S.; Kanatzidis, M. G. Science 1992, 258, 1769.
26. (a) Feinlieb, J.; deNeufville, J. P.; Moss, S. C.; Ovshinsky, S. R. Appl. Phys. Lett. 1971, 18, 254.
27. (b) Maeda, Y.; Andoh, H.; Ikuta, I.; Minemura, H. J. Appl, Phys. 1988, 64, 1715.
28. Wachhold, M.; Kanatzidis, M. G. J. Am. Chem. Soc. 1999, 121, 1, 4189.
29. Chondroudis, K.; Kanatzidis, M. G. Chem. Commun. 1996, 1371.