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Volumn , Issue 22, 2005, Pages 2840-2842

Photomodulation of Lewis basicity in a pyridine-functionalized 1,2-dithienylcyclopentene

Author keywords

[No Author keywords available]

Indexed keywords

1,2 DITHIENYLCYCLOPENTENE; CYCLOPENTENE DERIVATIVE; LEWIS BASE; LIGAND; PORPHYRIN; PYRIDINE DERIVATIVE; RUTHENIUM; UNCLASSIFIED DRUG;

EID: 21344437508     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b501779c     Document Type: Article
Times cited : (54)

References (23)
  • 4
    • 0348080703 scopus 로고    scopus 로고
    • (b) M. Irie, Chem. Rev., 2000, 100, 1685;
    • (2000) Chem. Rev. , vol.100 , pp. 1685
    • Irie, M.1
  • 5
    • 0002963533 scopus 로고    scopus 로고
    • ed. B. L. Feringa, Wiley-VCH, Weinheim, Germany
    • (c) M. Irie, in Molecular Switches, ed. B. L. Feringa, Wiley-VCH, Weinheim, Germany, 2001, p. 37.
    • (2001) Molecular Switches , pp. 37
    • Irie, M.1
  • 7
    • 0032853749 scopus 로고    scopus 로고
    • (a) For an example where the acidity of a phenol -OH increases due to the creation of linear π-conjugation between the phenol and a pyridinium across a DTE backbone, see: S. H. Kawai, S. L. Gilat and J.-M. Lehn, Eur. J. Org. Chem., 1999, 2359;
    • (1999) Eur. J. Org. Chem. , pp. 2359
    • Kawai, S.H.1    Gilat, S.L.2    Lehn, J.-M.3
  • 8
    • 1642568094 scopus 로고    scopus 로고
    • (b) For an example where the coordination geometry around a copper(II) ion is photoregulated using the bis(pyridine) version of the DTE, see: K. Matsuda, K. Takayama and M. Irie, Inorg. Chem., 2004, 43, 482. Although this study demonstrates that there is a difference in the π-acceptor character of the pyridyl ligand in the two forms of the DTE, the authors only suggest it is due to variations in electronics in the pyridine of the closed form and do not attribute it to electronic communication between the free pyridine and the one that is electron poor owing to the coordination. In fact they later state that the distance between the two metal centres is too far for them to be effectively coupled.
    • (2004) Inorg. Chem. , vol.43 , pp. 482
    • Matsuda, K.1    Takayama, K.2    Irie, M.3
  • 13
  • 21
    • 0030887405 scopus 로고    scopus 로고
    • For an example where photochemical fragmentation of a malachite green dye leads to complete decomplexation of a cation/aza-crown ether, see: K. Kimura, R. Mizutani, M. Yokoyama, M. Okamoto and H. Doe, J. Am. Chem. Soc., 1997, 119, 2062.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 2062
    • Kimura, K.1    Mizutani, R.2    Yokoyama, M.3    Okamoto, M.4    Doe, H.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.