Low-temperature "1,2 →1,7" isomerization of sterically crowded icosahedral closo-((2,3,8-η3):(5,6-η2)- norbornadien-2-yl)rhodacarborane via the formation of a pseudocloso intermediate.

Organometallics

Volumn 24, Issue 12, 2005, Pages 2964-2970

  Safronov, Alexander V ^a   Dolgushin, Fedor M ^a   Petrovskii, Pavel V ^a   Chizhevsky, Igor T ^a  

^a A N NESMEYANOV INSTITUTE OF ORGANOELEMENT COMPOUNDS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTALLOGRAPHY; ISOMERIZATION; LOW TEMPERATURE EFFECTS; NEGATIVE IONS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POTASSIUM; THERMAL EFFECTS;

CARBORANE; DIASTEREOMERS; ISOMERIZATION REACTION; METALATION REACTION;

ORGANIC COMPOUNDS;

EID: 21344432336     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om050125i     Document Type: Article

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