Platination of [3-X-7,8-Ph2-7,8-nido-C2 B9H8]2- (X=Et, F)Synthesis and characterisation of slipped and 1,2→1,7 isomerised products

Journal of Organometallic Chemistry

Volumn 680, Issue 1-2, 2003, Pages 286-293

  Robertson, Susan ^a   Ellis, David ^a   Rosair, Georgina M ^a   Welch, Alan J ^a  

^a HERIOT WATT UNIVERSITY   (United Kingdom)

Author keywords

Carborane; Crystallographic study; Isomerisation; Metallacarborane; Spectroscopy; Synthesis; Vertex labelling

Indexed keywords

ALKYL GROUP; CARBORANE DERIVATIVE; FLUORINE; LIGAND; PLATINUM;

ADDITION REACTION; ARTICLE; ATOM; CHEMICAL ANALYSIS; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; CONTROLLED STUDY; CRYSTALLOGRAPHY; ISOMER; ISOMERISM; ROOM TEMPERATURE; SPECTROSCOPY; SYNTHESIS;

EID: 0041888211     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(03)00406-6     Document Type: Article

References (35)

1. Grafstein D. Dvorak J. Inorg. Chem. 2 1963 1128
2. L.I. Zakharkin, V.N. Kalinin, Izv. Akad. Nauk SSSR, Ser. Khim. (1969) 607.
3. Hawthorne M.F. Young D.C. Wegner P.A. J. Am. Chem. Soc. 87 1965 1818
4. Hoffmann R. Angew. Chem. Int. Ed. 21 1982 711
5. Baghurst D.R. Copley R.C.B. Fleischer H. Mingos D.M.P. Kyd G.O. Yellowlees L.J. Welch A.J. Spalding T.R. O'Connell D. J. Organometal. Chem. 447 1993 C14
6. Welch A.J. Steric effects in metallacarboranes in: Braunstein P. Oro L.A. Raithby P.R. (Eds.), Metal Clusters in Chemistry 1999 69 Wiley/VCH New York/Weinheim
7. Barberà G. Dunn S. Fox M.A. Garrioch R.M. Hodson B.E. Low K.S. Rosair G.M. Teixidor F. Viñas C. Welch A.J. Weller A.S. Towards experimental mapping of the mechanism of heteroborane isomerisation in: Davidson M.G. Hughes A.K. Marder T.B. Wade K. (Eds.), Contemporary Boron Chemistry 2000 329 Royal Society of Chemistry
8. Lipscomb W.N. Science 153 1966 373
9. Kaeze H.D. Bau R. Beal H.A. Lipscomb W.N. J. Am. Chem. Soc. 86 1967 4218
10. Zakharkin L.I. Kalinin V.N. Dokl. Akad. Nauk SSSR 169 1966 590
11. Wu S.-H. Jones M. J. Am. Chem. Soc. 111 1989 5373
12. Wong H.S. Lipscomb W.N. Inorg. Chem. 14 1975 1350
13. Edvenson G.M. Gaines D.F. Inorg. Chem. 29 1990 1210
14. Wales D.J. J. Am. Chem. Soc. 115 1993 1557
15. Robertson S. Ellis D. McGrath T.D. Rosair G.M. Welch A.J. Polyhedron 22 2003 1293
16. Robertson S. Ellis D. Rosair G.M. Welch A.J. Appl. Organometal. Chem. 17 2003 516
17. Garrioch R.M. Kuballa P. Low K.S. Rosair G.M. Welch A.J. J. Organometal. Chem. 575 1999 57
18. J.M. Jenkins, B.L. Shaw, J. Chem. Soc. A (1966) 770.
19. Siemens Analytical Instruments, Inc., Madison, WI, 1996.
20. G.M. Sheldrick, shelxtl Version 5.1, Bruker AXS, Inc., Madison, WI, 1999.
21. A.S. Weller, A.J. Welch, J. Chem. Soc. Dalton Trans. (1997) 1205.
22. D.M.P. Mingos, M.I. Forsyth, A.J. Welch, J. Chem. Soc. Dalton Trans. (1978) 1363.
23. 9 [Δ 0.52 Å; G.O. Kyd, L.J. Yellowlees, A.J. Welch, J. Chem. Soc. Dalton Trans. (1994) 3129].
24. Cowie J. Reid B.D. Watmough J.M.S. Welch A.J. J. Organometal. Chem. 481 1994 283
25. Lewis Z.G. Welch A.J. J. Organometal. Chem. 430 1992 C45
26. P.T. Brain, M. Bühl, J. Cowie, Z.G. Lewis, A.J. Welch, J. Chem. Soc. Dalton Trans. (1996) 231
27. U. Grädler, A.S. Weller, A.J. Welch, D. Reed, J. Chem. Soc. Dalton Trans. (1996) 335
28. Welch A.J. Weller A.S. Inorg. Chem. 35 1996 4548
29. Rosair G.M. Welch A.J. Weller A.S. Organometallics 17 1998 3227
30. McWhannell M.A. Rosair G.M. Welch A.J. Teixidor F. Viñas C. J. Organometal. Chem. 573 1999 165
31. Reed D. Welch A.J. Cowie J. Donohoe D.J. Parkinson J.A. Inorg. Chim. Acta 289 1999 125
32. Cowie J. Donohoe D.J. Douek N.L. Welch A.J. Acta Crystallogr. C 49 1993 710
33. Lewis Z.G. Welch A.J. Acta Crystallogr. C 49 1993 705
34. G.O. Kyd, Ph.D. Thesis, University of Edinburgh, 1996.
35. T.L. Sadler, D. Ellis, R.M. Garrioch, G.M. Rosair, A.J. Welch, in preparation.