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Volumn 127, Issue 25, 2005, Pages 8958-8959

Fluorous bulk membranes for potentiometric sensors with wide selectivity ranges: Observation of exceptionally strong ion pair formation

Author keywords

[No Author keywords available]

Indexed keywords

BORIC ACID; LIPID; PERFLUOROPHENANTHRENE; POLITEF; TETRAHENYLBORATE; UNCLASSIFIED DRUG;

EID: 21244470611     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja052403a     Document Type: Article
Times cited : (84)

References (41)
  • 23
    • 0009060010 scopus 로고
    • Stearic acid, e.g., has a solubility of 430 mM in hexane and 0.026 mM in the fluorous solvent trans-1,2-bis(perfluorohexyl)ethylene, as reported in Grec, J. J.; Riess, J. G. Nouv. J. Chim. 1985, 9, 109.
    • (1985) Nouv. J. Chim. , vol.9 , pp. 109
    • Grec, J.J.1    Riess, J.G.2
  • 27
    • 0012219553 scopus 로고    scopus 로고
    • Chemistry in fluorous biphasic systems
    • Clark, J., Macquarrie, D., Eds.; Blackwell Science: Oxford
    • Rabai, J.; Szlavik, Z.; Horvath, I. T. Chemistry in Fluorous Biphasic Systems. In Handbook of Green Chemistry and Technology; Clark, J., Macquarrie, D., Eds.; Blackwell Science: Oxford, 2002.
    • (2002) Handbook of Green Chemistry and Technology
    • Rabai, J.1    Szlavik, Z.2    Horvath, I.T.3
  • 29
    • 21244485503 scopus 로고    scopus 로고
    • note
    • Note that perfluoropolymers with highly polar functional groups, such as Nafion and Tosflex, are not fluorous as they readily mix with water.
  • 32
    • 21244491624 scopus 로고    scopus 로고
    • note
    • Porosity 68%, average pore size 10 μm, thickness 125 μm.
  • 33
    • 21244464799 scopus 로고    scopus 로고
    • note
    • This polymer is easier to machine than Teflon and does not swell when exposed to fluorous solvents.
  • 39
    • 21244470378 scopus 로고    scopus 로고
    • note
    • Control experiments with membranes containing poly(vinyl chloride), chloroparaffin, and 2 are not feasible due to precipitation of 2.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.