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Volumn 7, Issue 6, 2005, Pages 468-474

The influence of room-temperature ionic liquids on the stereoselectivity and kinetics of the electrochemical pinacol coupling of acetophenone

Author keywords

[No Author keywords available]

Indexed keywords

ACETOPHENONE; IMIDE;

EID: 21144453578     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/b500839e     Document Type: Article
Times cited : (61)

References (56)
  • 2
    • 49249124954 scopus 로고    scopus 로고
    • Ionic liquids as Green Solvents: Progress and Prospects
    • American Chemical Society, Washington, DC
    • The literature dealing with ionic liquids is rapidly growing. For a general overview, see: (a) Ionic liquids as Green Solvents: Progress and Prospects, ed. R. D. Rogers and K. R. Seddon, ACS Symposium series 856, American Chemical Society, Washington, DC, 2003;
    • (2003) ACS Symposium Series 856
    • Rogers, R.D.1    Seddon, K.R.2
  • 11
    • 21144440384 scopus 로고    scopus 로고
    • note
    • As the physical properties of ionic liquids such as density, melting point, viscosity, and hydrophobicity can be tuned through variation of anion or cation to tailor particular ionic liquids for a given use, they can be specifically designed to facilitate product recovery (from extraction, distillation or steam-stripping) and solvent recycling after the electrolysis hes been completed.
  • 35
    • 21144448302 scopus 로고    scopus 로고
    • See Experimental section
    • The ferrocene/ferrocenium couple is used as an internal reference for potential standardisation. See Experimental section.
  • 36
    • 21144446389 scopus 로고    scopus 로고
    • note
    • Actually, the electrolysis were run at 0.1 V-more anodic potentials than the corresponding peak potentiel of the reduction of acetophenone.
  • 39
    • 21144443614 scopus 로고    scopus 로고
    • note
    • The amount of residual water in the three ionic liquids was measured at 600-700 ppm using Karl-Fisher titration.
  • 46
    • 21144436060 scopus 로고    scopus 로고
    • See ref. 9(b)
    • +. See ref. 9(b).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.