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Volumn 118, Issue 40, 1996, Pages 9788-9789

Solvent reorganization as a governing factor in the kinetics of intramolecular dissociative electron transfers. Cleavage of anion radicals of α-substituted acetophenones

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EID: 0000444683     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9622564     Document Type: Article
Times cited : (38)

References (45)
  • 9
    • 0002010399 scopus 로고
    • Intramolecular Photochemical Electron Transfer (PET) - Induced Bond Cleavage Reactions in some Sulfonium Salts Derivatives
    • Mariano, P. S., Ed.; JAI Press: New York
    • (b) Saeva, F. D. Intramolecular Photochemical Electron Transfer (PET) - Induced Bond Cleavage Reactions in some Sulfonium Salts Derivatives. In Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: New York, 1994; Vol. 4, pp 1-25.
    • (1994) Advances in Electron Transfer Chemistry , vol.4 , pp. 1-25
    • Saeva, F.D.1
  • 16
    • 77956772881 scopus 로고
    • Single Electron Transfer and Nucleophilic Substitution
    • Bethel, D., Ed.; Academic Press: New York
    • (a) Savéant, J.-M. Single Electron Transfer and Nucleophilic Substitution. In Advances in Physical Organic Chemistry; Bethel, D., Ed.; Academic Press: New York, 1990; Vol. 26, pp 1-130.
    • (1990) Advances in Physical Organic Chemistry , vol.26 , pp. 1-130
    • Savéant, J.-M.1
  • 18
    • 0001887557 scopus 로고
    • Dissociative Electron Transfer
    • Mariano, P. S., Ed.; JAI Press: New York
    • (c) Savéant, J.-M. Dissociative Electron Transfer. In Advances in Electron Transfer Chemistry; Mariano, P. S., Ed.; JAI Press: New York, 1994; Vol. 4, pp 53-116.
    • (1994) Advances in Electron Transfer Chemistry , vol.4 , pp. 53-116
    • Savéant, J.-M.1
  • 20
    • 85033042196 scopus 로고    scopus 로고
    • note
    • 7b The solvent reorganization energy is also expected to be small since the charge stays on the same portion of the molecule during bond cleavage.
  • 27
    • 85033070062 scopus 로고    scopus 로고
    • 10b
    • 10b
  • 29
    • 85033066400 scopus 로고    scopus 로고
    • note
    • -1), pointing to a strong localization of the negative charge on the carbonyl oxygen of the anion radical in both cases, albeit somewhat less with 2b than with acetophenone.
  • 32
    • 85033047302 scopus 로고    scopus 로고
    • 4c for an extended series of a-phenoxyacetophenones bearing various substituents on the phenoxy ring, although not a 3-methyl group as in 3a
    • 4c for an extended series of a-phenoxyacetophenones bearing various substituents on the phenoxy ring, although not a 3-methyl group as in 3a.
  • 38
    • 85033071322 scopus 로고    scopus 로고
    • note
    • RX/R*-+H*. are about the same in both cases.
  • 43
    • 85033056552 scopus 로고    scopus 로고
    • note
    • 18b.c


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.