Exploratory synthesis in molten salts: Role of flux basicity in the stabilization of the complex thiogermanates Cs 4Pb 4Ge 5S 16, K 2PbGe 2S 6, and K 4Sn 3Ge 3S 14

Inorganic Chemistry

Volumn 44, Issue 12, 2005, Pages 4151-4153

  Palchik, Oleg ^a   Marking, Gregory M ^a   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20744447321     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic050087v     Document Type: Article

References (37)

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31. 16.7, which is close to the chemical formula determined by single-crystal X-ray diffraction analysis.
32. 5.5".
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36. Single-crystal visible spectroscopy: Optical transmission measurements were made at room temperature on single crystals with a Hitachi U-6000 spectrophotometer equipped with an Olympus BH-2 microscope. The crystals were placed on the glass slide and covered with mineral oil. Measurements were done for at least four crystals from each batch.
37. 16 showed luminescence.