Spectroscopic studies of enantiomeric discrimination in jet-cooled chiral complexes

Chirality

Volumn 13, Issue 10, 2001, Pages 715-721

  Barbu, K L E ^a   Zehnacker, A ^a   Lahmani, F ^a   Mons, M ^b   Piuzzi, F ^b   Dimicoli, I ^b  

^a UNIVERSITÉ PARIS SACLAY   (France)

^b CEA SACLAY   (France)

Author keywords

Binding energy; Jet cooled diastereoisomers; Spectral discrimination

Indexed keywords

1 PHENYLETHANOL; 2 BUTANOL; 2 NAPTHYL 1 ETHANOL; ALCOHOL DERIVATIVE; AROMATIC COMPOUND; SOLVENT; UNCLASSIFIED DRUG;

CHIRALITY; CHROMATOPHORE; COMPLEX FORMATION; CONFERENCE PAPER; CONFORMATION; COOLING; DIASTEREOISOMER; ENANTIOMER; ENERGY; GAS; ISOMER; MOLECULAR INTERACTION; MOLECULAR STABILITY; PRIORITY JOURNAL; SPECTROSCOPY;

EID: 20644449679     PISSN: 08990042     EISSN: None     Source Type: Journal    
DOI: 10.1002/chir.10016     Document Type: Conference Paper

References (19)

1. Al-Rabaa AR, Bréhéret E, Lahmani F, Zehnacker A. Enantiodifferentiation in jet-cooled van der Waals complexes of chiral molecules. Chem Phys Lett 1995;237:480-484.
2. Al Rabaa AR, Le Barbu K, Lahmani F, Zehnacker-Rentien A. van der Waals complexes between chiral molecules in a supersonic jet: a new spectroscopic method for enantiomeric discrimination. J Phys Chem 1997;101:3273-3278.
3. Le Barbu K, Brenner V, Millié P, Lahmani F, Zehnacker-Rentien A. An experimental and theoretical study of jet-cooled complexes of chiral molecules: the role of dispersive forces in chiral discrimination. J Phys Chem A 1998;102:128-137.
4. Latini A, Toja D, Giardini-Guidoni A, Piccirillo S, Speranza M. Energetics of molecular complexes in a supersonic beam: a novel spectroscopic tool for enantiomeric discrimination. Angew Chemie Int Ed 1999;38:815-817.
5. Latini A, Toja D, Giardini-Guidoni A, Piccirillo S, Speranza M. Short range interaction within molecular complexes formed in supersonic beams: structural effects and chiral discrimination. Chem Eur J 2000; 6:1042-1049.
6. Mons M, Piuzzi F, Dimicoli I, Zehnacker A, Lahmani F. Binding energy of hydrogen-bonded complexes of the chiral 1-phenylethanol molecule by 2C-R2PI: comparison between diastereoisomeric complexes with butan-2-ol and the singly hydrated complex. Phys Chem Chem Phys 2000;2:5065-5070.
7. Giardini-Guidoni A, Piccirillo S, Scuderi D, Satta M, Di Palma TM, Speranza M. Chirality and molecular forces: studies using R2PI experiments in supersonic beams. Phys Chem Chem Phys 2000;2:4139-4142.
8. 3). J Phys Chem A 1998;102:4890-4898.
9. Lippert RJ, Colson SD. Persistent spectral hole burning of molecular clusters in a supersonic jet. J Phys Chem 1989;93:2093-2096.
10. Ballard RE, Jones J, Sutherland E, Read D, Inchley A. The He(I) photoelectron spectrum of benzyl alcohol-liquid surface and gas phase. Chem Phys Lett 1986;126:311-313.
11. Guchhait N, EbataT, Mikami N. Structure of hydrogen-bonded clusters of benzyl alcohol with water investigated by infrared-ultraviolet double resonance spectroscopy in supersonic jet. J Chem Phys 1999; 111:8438-8447.
12. Mons M, Robertson E, Simons JP. Intra and intermolecular π-type hydrogen bonding in aryl alcohols: UV and IR ion-dip spectroscopy. J Phys Chem A 2000;104:420-425.
13. Weinkauf R, Lehrer F, Schlag EW, Metsala A. Investigation of charge localization and charge delocalization in model molecules by multiphoton ionization photoelectron spectroscopy and DFT calculations. Faraday Disc 2000;115:363-381.
14. Dessent CEH, Geppert WD, Ullrich S, Müller-Dethlefs K. Ionisationinduced conformational changes: REMPI and ZEKE spectroscopy of salicyl and benzyl alcohol. Chem Phys Lett 2000;319:375-384.
15. 2O complexes: experiments and theory. J Phys Chem A 1998;102:6590-6600.
16. Li S, Bernstein ER. Benzyl alcohol-water and benzyl alcohol-ammonia clusters/ion fragmentation and chemistry. J Chem Phys 1992;97:7383-7391.
17. Gord JA, Garett AW, Bandy RE, Zwier TS. REMPI fragmentation as a probe of hydrogen bonding in aromatic -X clusters. Chem Phys Lett 1990;171:443-450.
18. NIST Chemistry webbook (http://webbook.nist.gov/chemistry).
19. Hagemann H, Mareda J, Chiancone C, Bill H. Conformational studies of butan-2-ol using temperature-dependent Raman measurements and MM3 calculations. J Mol Struct 1997;410-411:357-360.