Short-range interactions within molecular complexes formed in supersonic beams: Structural effects and chiral discrimination

Chemistry - A European Journal

Volumn 6, Issue 6, 2000, Pages 1042-1049

  Latini, Andrea ^a   Satta, Mauro ^a   Giardini Guidoni, Anna ^a   Piccirillo, Susanna ^b   Speranza, Maurizio ^a  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

^b UNIVERSITY OF ROME TOR VERGATA   (Italy)

Author keywords

Chiral recognition; Cluster energetics; Enantiomeric resolution; Mass spectrometry

Indexed keywords

SOLVENT;

ARTICLE; CHEMICAL STRUCTURE; CHIRALITY; COMPLEX FORMATION; DIASTEREOISOMER; ENANTIOMER; ENERGY; MASS SPECTROMETRY;

EID: 0034677681     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3765(20000317)6:6<1042::AID-CHEM1042>3.0.CO;2-W     Document Type: Article

References (32)

1. A. R. Al-Rabaa, E. Bréhéret, F. Lahmani, A. Zehnacker-Rentien, Chem. Phys. Lett. 1995, 237, 480.
2. A. R. Al-Rabaa, K. Le Barbu, F. Lahmani, A. Zehnacker-Rentien, J. Phys. Chem. 1997, 101, 3273.
3. K. Le Barbu, V. Brenner, P. Millié, F. Lahmani, A. Zehnacker-Rentien, J. Phys. Chem. A 1998, 102, 128.
4. S. Piccirillo, C. Bosman, D. Toja, A. Giardini-Guidoni, M. Pierini, A. Troiani, M. Speranza, Angew. Chem. 1997, 109, 1816; Angew. Chem. Int. Ed. Engl. 1997, 36, 1729.
5. S. Piccirillo, C. Bosman, D. Toja, A. Giardini-Guidoni, M. Pierini, A. Troiani, M. Speranza, Angew. Chem. 1997, 109, 1816; Angew. Chem. Int. Ed. Engl. 1997, 36, 1729.
6. A. Giardini Guidoni, S. Piccirillo, Isr. J. Chem. 1997, 37, 439.
7. A. Latini, D. Toja, A. Giardini-Guidoni, A. Palleschi, S. Piccirillo, M. Speranza, Chirality 1999, 11, 376.
8. A. Latini, D. Toja, A. Giardini-Guidoni, S. Piccirillo, M. Speranza, Angew. Chem. 1999, 111, 838; Angew. Chem. Int. Ed. 1999, 38, 815; See also, H. J. Neusser, H. Krause, Chem. Rev. 1994, 94, 1829, and references therein.
9. A. Latini, D. Toja, A. Giardini-Guidoni, S. Piccirillo, M. Speranza, Angew. Chem. 1999, 111, 838; Angew. Chem. Int. Ed. 1999, 38, 815; See also, H. J. Neusser, H. Krause, Chem. Rev. 1994, 94, 1829, and references therein.
10. A. Latini, D. Toja, A. Giardini-Guidoni, S. Piccirillo, M. Speranza, Angew. Chem. 1999, 111, 838; Angew. Chem. Int. Ed. 1999, 38, 815; See also, H. J. Neusser, H. Krause, Chem. Rev. 1994, 94, 1829, and references therein.
11. N. Ramsey, Molecular Beams, Oxford Clarendon Press, Oxford, 1956.
12. R. E. Smalley, B. L. Ramakrishna, D. H. Levy, L. Wharton, J. Chem. Phys. 1974, 61, 4363.
13. W. C. Wiley, I. H. McLaren, Rev. Sci. Instrum. 1955, 26, 1150.
14. B. Brutschy, Chem. Rev. 1992, 92, 1567.
15. M. Coreno, S. Piccirillo, A. Giardini Guidoni, A. Mele, A. Palleschi, P. Brechignac, P. Parneix, Chem. Phys. Lett. 1995, 236, 580.
16. S. Piccirillo, M. Coreno, A. Giardini-Guidoni, G. Pizzella, M. Snels, R. Teghil, J. Mol. Struct. 1993, 293, 197.
17. T. M. Di Palma, A. Latini, M. Satta, M. Varvesi, A. Giardini Guidoni, Chem. Phys. Lett. 1998, 284, 184.
18. D. Consalvo, A. van der Avoird, S. Piccirillo, M. Coreno, A. Giardini-Guidoni, A. Mele, M. Snels, J. Chem. Phys. 1993, 99, 8398.
19. M. J. Frish, G. W. Trucks, H. B. Schlegel, P. M. W. Gill, B. G. Johnson, M. A. Robb, J. R. Cheeseman, T. A. Keith, G. A. Petersson, J. A. Montgomery, K. Ragavachari, M. A. Al-Laham, V. G. Zakrzewski, J. V. Ortiz, J. B. Foresman, J. Cioslowski, B. B. Stefanov, A. Nanayakkara, M. Challacombe, C. Y. Peng, P. Y. Ayala, W. Chen, M. W. Wong, J. L. Andres, E. S. Repogle, R. Gomperts, R. L. Martin, D. J. Fox, J. S. Binkley, D. J. Defrees, J. Baker, J. J. P. Stewart, M. Head-Gordon, C. Gonzales, J. A. Pople, GAUSSIAN 94, Revision C.2, Gaussian, Pittsburgh, PA, 1995.
20. C. Peng, H. B. Schlegel, Isr. J. Chem. 1993, 33, 449.
21. A. D. Becke, J. Chem. Phys. 1993, 98, 1372, 5648.
22. S. Sun, E. R. Bernstein, J. Am. Chem. Soc. 1996, 118, 5086.
23. S. Li, E. R. Bernstein, J. Chem. Phys. 1992, 97, 7383.
24. 0) characterize the spectrum of many substituted benzenes and are found to be independent of the nature of the substituent; cf. J. B. Hopkins, D. E. Powers, S. Mukamel, R. E. Smalley, J. Chem. Phys. 1980, 72, 5049.
25. -1 more than that of 1-propanol (M. J. Haas, A. G. Harrison, Int. J. Mass Spectrom. Ion Proc. 1993, 124, 115) and that the differential effects of the aromatic substituents on their acidity approximately cancels out (J. E. Bartmess, J. A. Scott, R. T. McIver, Jr., J. Am. Chem. Soc. 1979, 101, 6046, 6056). The proton affinities (PA) of solv are reported in S. G. Lias, J. E. Bartmess, J. F. Liebman, J. L. Holmes, R. D. Levin, W. G. Mallard, J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
26. -1 more than that of 1-propanol (M. J. Haas, A. G. Harrison, Int. J. Mass Spectrom. Ion Proc. 1993, 124, 115) and that the differential effects of the aromatic substituents on their acidity approximately cancels out (J. E. Bartmess, J. A. Scott, R. T. McIver, Jr., J. Am. Chem. Soc. 1979, 101, 6046, 6056). The proton affinities (PA) of solv are reported in S. G. Lias, J. E. Bartmess, J. F. Liebman, J. L. Holmes, R. D. Levin, W. G. Mallard, J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
27. -1 more than that of 1-propanol (M. J. Haas, A. G. Harrison, Int. J. Mass Spectrom. Ion Proc. 1993, 124, 115) and that the differential effects of the aromatic substituents on their acidity approximately cancels out (J. E. Bartmess, J. A. Scott, R. T. McIver, Jr., J. Am. Chem. Soc. 1979, 101, 6046, 6056). The proton affinities (PA) of solv are reported in S. G. Lias, J. E. Bartmess, J. F. Liebman, J. L. Holmes, R. D. Levin, W. G. Mallard, J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
28. -1 more than that of 1-propanol (M. J. Haas, A. G. Harrison, Int. J. Mass Spectrom. Ion Proc. 1993, 124, 115) and that the differential effects of the aromatic substituents on their acidity approximately cancels out (J. E. Bartmess, J. A. Scott, R. T. McIver, Jr., J. Am. Chem. Soc. 1979, 101, 6046, 6056). The proton affinities (PA) of solv are reported in S. G. Lias, J. E. Bartmess, J. F. Liebman, J. L. Holmes, R. D. Levin, W. G. Mallard, J. Phys. Chem. Ref. Data 1988, 17, Suppl. 1.
29. E. R. Bernstein, in Atomic and Molecular Clusters (Ed.: E. R. Bernstein), Elsevier, Amsterdam, 1990.
30. An alternative effect of the steric congestion in [R·5s] may be a change in the nature of the O-H ⋯ O hydrogen bond, wherein 5s acts as the donor and R as the acceptor.
31. 2 molecule (M. Meot-Ner (Mautner), P. Hamlet, E. P. Hunter, F. H. Field, J. Am. Chem. Soc. 1978, 100, 5466).
32. 2 molecule (M. Meot-Ner (Mautner), P. Hamlet, E. P. Hunter, F. H. Field, J. Am. Chem. Soc. 1978, 100, 5466).