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Volumn 44, Issue 22, 2005, Pages 3488-3490

Regio- and stereoselective approach to 1,2-di- and 1,1,2-trisilylethenes by cobalt-mediated reaction of silyl-substituted dibromomethanes with silylmethylmagnesium reagents

Author keywords

Alkenes; Cobalt; Grignard reagents; Silicon; Synthetic methods

Indexed keywords

CATALYST ACTIVITY; COBALT; MATHEMATICAL TRANSFORMATIONS; REACTION KINETICS; STOICHIOMETRY;

EID: 20444364901     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500576     Document Type: Article
Times cited : (26)

References (42)
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    • (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, chap. 2.5
    • c) J. S. Panek in Comprehensive Organic Chemistry, Vol. 1 (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, 1991, chap. 2.5;
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    • Panek, J.S.1
  • 11
    • 0000829913 scopus 로고
    • (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester
    • c) I. Ojima in The Chemistry of Organic Silicon Compounds (Eds.: S. Patai, Z. Rappoport), Wiley, Chichester, 1989, pp. 1479-1526;
    • (1989) The Chemistry of Organic Silicon Compounds , pp. 1479-1526
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  • 13
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    • (Eds.: B. M. Trost, I. Fleming), Pergamon, Oxford, chap. 3.12
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    • f) K. A. Horn, Chem. Rev. 1995, 95, 1317-1350.
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    • 0002718402 scopus 로고    scopus 로고
    • For the cobalt-mediated reaction of dibromocyclopropane with methyl and butyl Grignard reagents, see: Y. Nishii, K. Wakasugi, Y. Tanabe, Synlett 1998, 67-69.
    • (1998) Synlett , pp. 67-69
    • Nishii, Y.1    Wakasugi, K.2    Tanabe, Y.3
  • 37
    • 0002534519 scopus 로고
    • 2] in solution is not clear. For convenience, we use this expression. Several organocobaltate(II) compounds were characterized by X-ray crystallographic analysis: R. S. Hay-Motherwell, G. Wilkinson, B. Hussain, M. B. Hursthouse, Polyhedron 1990, 9, 931-937.
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    • For a review on cobaltate complexes, see: T. Kauffmann, Angew. Chem. 1996, 108, 401-418;
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  • 40
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    • and references therein
    • For examples of halogen-metal exchange between gem-dihaloalkane and ate complexes followed by alkyl migration, see: A. Inoue, J. Kondo, H. Shinokubo, K. Oshima, Chem. Eur. J. 2002, 8, 1730-1740, and references therein.
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    • Inoue, A.1    Kondo, J.2    Shinokubo, H.3    Oshima, K.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.