A facile synthesis of 1,1-disilylethenes via Me3MgLi-induced monomethylation of dibromodisilylmethanes

Chemistry Letters

Volumn , Issue 10, 2001, Pages 956-957

  Inoue, Atsushi ^a   Kondo, Junichi ^a   Shinokubo, Hiroshi ^a   Oshima, Koichiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0035541243     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2001.956     Document Type: Article

References (28)

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24. 4 and concentrated in vacuo. Washing the residual colorless solid with pentane provided 1-bromo-1,1-bis(methyldiphenylsilyl)ethane (2i, 4.51 g, 9.0 mmol) in 90% yield.
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28. 4 and concentrated in vacuo. Washing the residual colorless solid with cold hexane provided 1,1-bis(methyldiphenylsilyl)ethene (6i, 3.37 g, 8.0 mmol) in 89% yield.